Development of catalytic materials for decomposition of ADN-based monopropellants

Hydrazine (N2H4), one of the widest used liquid monopropellant is to be replaced by “greener” propellants based on ammonium dinitramide (ADN, NH4+N(NO2)2-), such as LMP-103S and FLP-106 within the framework of the Horizon 2020 Rheform project. While hydrazine can rely on a catalytic technology based...

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Veröffentlicht in:Acta astronautica 2019-05, Vol.158, p.407-415
Hauptverfasser: Maleix, Corentin, Chabernaud, Pierre, Brahmi, Rachid, Beauchet, Romain, Batonneau, Yann, Kappenstein, Charles, Schwentenwein, Martin, Koopmans, Robert-Jan, Schuh, Sebastian, Scharlemann, Carsten
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container_end_page 415
container_issue
container_start_page 407
container_title Acta astronautica
container_volume 158
creator Maleix, Corentin
Chabernaud, Pierre
Brahmi, Rachid
Beauchet, Romain
Batonneau, Yann
Kappenstein, Charles
Schwentenwein, Martin
Koopmans, Robert-Jan
Schuh, Sebastian
Scharlemann, Carsten
description Hydrazine (N2H4), one of the widest used liquid monopropellant is to be replaced by “greener” propellants based on ammonium dinitramide (ADN, NH4+N(NO2)2-), such as LMP-103S and FLP-106 within the framework of the Horizon 2020 Rheform project. While hydrazine can rely on a catalytic technology based on conventional materials such as γ-Al2O3 (due to the adiabatic decomposition temperature of about 900–1000 °C), LMP-103S and FLP-106 require catalyst support materials that can withstand higher temperatures (about 1650 °C and 1900 °C, respectively) and exhibit a sufficient porosity and resistance to sintering. On these terms, among the various candidates for catalyst support, monolith-shaped supports were investigated. •Ammonium DiNitramide (ADN) investigated in the form of two liquid propellants blends, namely FLP-106 and LMP-103S.•Several catalysts shapes investigated: granulated catalysts and monolithic catalysts.•3D printing of complex ceramic structures investigated towards a washcoating process.•Decomposition tests of FLP-106 and LMP-103S after impregnation of potential active metal solutions.•Textural behaviour of the washcoat layer studied after several heat treatments up to 1500 °C for different durations.
doi_str_mv 10.1016/j.actaastro.2019.03.033
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subjects 3D-printed monolith
Aluminum oxide
Ammonium
Ammonium DiNitramide (ADN)
Catalysis
Catalysts
Catalytic ignition
Decomposition
Engineering Sciences
Green propellant
Hydrazines
Monolithic materials
Monopropellants
Nitrogen dioxide
Porosity
Sintering (powder metallurgy)
Transitional aluminas
Washcoating
title Development of catalytic materials for decomposition of ADN-based monopropellants
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