Development of catalytic materials for decomposition of ADN-based monopropellants
Hydrazine (N2H4), one of the widest used liquid monopropellant is to be replaced by “greener” propellants based on ammonium dinitramide (ADN, NH4+N(NO2)2-), such as LMP-103S and FLP-106 within the framework of the Horizon 2020 Rheform project. While hydrazine can rely on a catalytic technology based...
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Veröffentlicht in: | Acta astronautica 2019-05, Vol.158, p.407-415 |
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creator | Maleix, Corentin Chabernaud, Pierre Brahmi, Rachid Beauchet, Romain Batonneau, Yann Kappenstein, Charles Schwentenwein, Martin Koopmans, Robert-Jan Schuh, Sebastian Scharlemann, Carsten |
description | Hydrazine (N2H4), one of the widest used liquid monopropellant is to be replaced by “greener” propellants based on ammonium dinitramide (ADN, NH4+N(NO2)2-), such as LMP-103S and FLP-106 within the framework of the Horizon 2020 Rheform project. While hydrazine can rely on a catalytic technology based on conventional materials such as γ-Al2O3 (due to the adiabatic decomposition temperature of about 900–1000 °C), LMP-103S and FLP-106 require catalyst support materials that can withstand higher temperatures (about 1650 °C and 1900 °C, respectively) and exhibit a sufficient porosity and resistance to sintering. On these terms, among the various candidates for catalyst support, monolith-shaped supports were investigated.
•Ammonium DiNitramide (ADN) investigated in the form of two liquid propellants blends, namely FLP-106 and LMP-103S.•Several catalysts shapes investigated: granulated catalysts and monolithic catalysts.•3D printing of complex ceramic structures investigated towards a washcoating process.•Decomposition tests of FLP-106 and LMP-103S after impregnation of potential active metal solutions.•Textural behaviour of the washcoat layer studied after several heat treatments up to 1500 °C for different durations. |
doi_str_mv | 10.1016/j.actaastro.2019.03.033 |
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•Ammonium DiNitramide (ADN) investigated in the form of two liquid propellants blends, namely FLP-106 and LMP-103S.•Several catalysts shapes investigated: granulated catalysts and monolithic catalysts.•3D printing of complex ceramic structures investigated towards a washcoating process.•Decomposition tests of FLP-106 and LMP-103S after impregnation of potential active metal solutions.•Textural behaviour of the washcoat layer studied after several heat treatments up to 1500 °C for different durations.</description><identifier>ISSN: 0094-5765</identifier><identifier>EISSN: 1879-2030</identifier><identifier>DOI: 10.1016/j.actaastro.2019.03.033</identifier><language>eng</language><publisher>Elmsford: Elsevier Ltd</publisher><subject>3D-printed monolith ; Aluminum oxide ; Ammonium ; Ammonium DiNitramide (ADN) ; Catalysis ; Catalysts ; Catalytic ignition ; Decomposition ; Engineering Sciences ; Green propellant ; Hydrazines ; Monolithic materials ; Monopropellants ; Nitrogen dioxide ; Porosity ; Sintering (powder metallurgy) ; Transitional aluminas ; Washcoating</subject><ispartof>Acta astronautica, 2019-05, Vol.158, p.407-415</ispartof><rights>2019</rights><rights>Copyright Elsevier BV May 2019</rights><rights>Attribution - NonCommercial</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-2a22ce9f98d2159618c2dabd154909024f4a83eb111eee6965b6c81ef586e0e63</citedby><cites>FETCH-LOGICAL-c426t-2a22ce9f98d2159618c2dabd154909024f4a83eb111eee6965b6c81ef586e0e63</cites><orcidid>0000-0002-6858-2532 ; 0000-0002-9437-1579</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0094576519304783$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03486988$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Maleix, Corentin</creatorcontrib><creatorcontrib>Chabernaud, Pierre</creatorcontrib><creatorcontrib>Brahmi, Rachid</creatorcontrib><creatorcontrib>Beauchet, Romain</creatorcontrib><creatorcontrib>Batonneau, Yann</creatorcontrib><creatorcontrib>Kappenstein, Charles</creatorcontrib><creatorcontrib>Schwentenwein, Martin</creatorcontrib><creatorcontrib>Koopmans, Robert-Jan</creatorcontrib><creatorcontrib>Schuh, Sebastian</creatorcontrib><creatorcontrib>Scharlemann, Carsten</creatorcontrib><title>Development of catalytic materials for decomposition of ADN-based monopropellants</title><title>Acta astronautica</title><description>Hydrazine (N2H4), one of the widest used liquid monopropellant is to be replaced by “greener” propellants based on ammonium dinitramide (ADN, NH4+N(NO2)2-), such as LMP-103S and FLP-106 within the framework of the Horizon 2020 Rheform project. While hydrazine can rely on a catalytic technology based on conventional materials such as γ-Al2O3 (due to the adiabatic decomposition temperature of about 900–1000 °C), LMP-103S and FLP-106 require catalyst support materials that can withstand higher temperatures (about 1650 °C and 1900 °C, respectively) and exhibit a sufficient porosity and resistance to sintering. On these terms, among the various candidates for catalyst support, monolith-shaped supports were investigated.
•Ammonium DiNitramide (ADN) investigated in the form of two liquid propellants blends, namely FLP-106 and LMP-103S.•Several catalysts shapes investigated: granulated catalysts and monolithic catalysts.•3D printing of complex ceramic structures investigated towards a washcoating process.•Decomposition tests of FLP-106 and LMP-103S after impregnation of potential active metal solutions.•Textural behaviour of the washcoat layer studied after several heat treatments up to 1500 °C for different durations.</description><subject>3D-printed monolith</subject><subject>Aluminum oxide</subject><subject>Ammonium</subject><subject>Ammonium DiNitramide (ADN)</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic ignition</subject><subject>Decomposition</subject><subject>Engineering Sciences</subject><subject>Green propellant</subject><subject>Hydrazines</subject><subject>Monolithic materials</subject><subject>Monopropellants</subject><subject>Nitrogen dioxide</subject><subject>Porosity</subject><subject>Sintering (powder metallurgy)</subject><subject>Transitional aluminas</subject><subject>Washcoating</subject><issn>0094-5765</issn><issn>1879-2030</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkEFLxDAQhYMouK7-BguePHRN0jZNjmVXXWFRBD2HNJ1iStvUJLuw_94sFa_CwMDwvTczD6FbglcEE_bQrZQOSvng7IpiIlY4i5WdoQXhpUgpzvA5WmAs8rQoWXGJrrzvMMYl5WKB3jdwgN5OA4whsW2iVVD9MRidDCqAM6r3SWtd0oC2w2S9CcaOJ7DavKa18tAkgx3t5OwEfa_G4K_RRRtVcPPbl-jz6fFjvU13b88v62qX6pyykFJFqQbRCt5QUghGuKaNqhtS5AILTPM2VzyDmhACAEywomaaE2gLzgADy5bofvb9Ur2cnBmUO0qrjNxWO3ma4SznTHB-IJG9m9l45_cefJCd3bsxnicpJYwLymgZqXKmtLPeO2j_bAmWp6xlJ_-ylqes445YWVRWsxLiwwcDTnptYNTQGAc6yMaafz1-AOFwi-8</recordid><startdate>20190501</startdate><enddate>20190501</enddate><creator>Maleix, Corentin</creator><creator>Chabernaud, Pierre</creator><creator>Brahmi, Rachid</creator><creator>Beauchet, Romain</creator><creator>Batonneau, Yann</creator><creator>Kappenstein, Charles</creator><creator>Schwentenwein, Martin</creator><creator>Koopmans, Robert-Jan</creator><creator>Schuh, Sebastian</creator><creator>Scharlemann, Carsten</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>7TG</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>KL.</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-6858-2532</orcidid><orcidid>https://orcid.org/0000-0002-9437-1579</orcidid></search><sort><creationdate>20190501</creationdate><title>Development of catalytic materials for decomposition of ADN-based monopropellants</title><author>Maleix, Corentin ; Chabernaud, Pierre ; Brahmi, Rachid ; Beauchet, Romain ; Batonneau, Yann ; Kappenstein, Charles ; Schwentenwein, Martin ; Koopmans, Robert-Jan ; Schuh, Sebastian ; Scharlemann, Carsten</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-2a22ce9f98d2159618c2dabd154909024f4a83eb111eee6965b6c81ef586e0e63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>3D-printed monolith</topic><topic>Aluminum oxide</topic><topic>Ammonium</topic><topic>Ammonium DiNitramide (ADN)</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic ignition</topic><topic>Decomposition</topic><topic>Engineering Sciences</topic><topic>Green propellant</topic><topic>Hydrazines</topic><topic>Monolithic materials</topic><topic>Monopropellants</topic><topic>Nitrogen dioxide</topic><topic>Porosity</topic><topic>Sintering (powder metallurgy)</topic><topic>Transitional aluminas</topic><topic>Washcoating</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maleix, Corentin</creatorcontrib><creatorcontrib>Chabernaud, Pierre</creatorcontrib><creatorcontrib>Brahmi, Rachid</creatorcontrib><creatorcontrib>Beauchet, Romain</creatorcontrib><creatorcontrib>Batonneau, Yann</creatorcontrib><creatorcontrib>Kappenstein, Charles</creatorcontrib><creatorcontrib>Schwentenwein, Martin</creatorcontrib><creatorcontrib>Koopmans, Robert-Jan</creatorcontrib><creatorcontrib>Schuh, Sebastian</creatorcontrib><creatorcontrib>Scharlemann, Carsten</creatorcontrib><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Acta astronautica</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maleix, Corentin</au><au>Chabernaud, Pierre</au><au>Brahmi, Rachid</au><au>Beauchet, Romain</au><au>Batonneau, Yann</au><au>Kappenstein, Charles</au><au>Schwentenwein, Martin</au><au>Koopmans, Robert-Jan</au><au>Schuh, Sebastian</au><au>Scharlemann, Carsten</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of catalytic materials for decomposition of ADN-based monopropellants</atitle><jtitle>Acta astronautica</jtitle><date>2019-05-01</date><risdate>2019</risdate><volume>158</volume><spage>407</spage><epage>415</epage><pages>407-415</pages><issn>0094-5765</issn><eissn>1879-2030</eissn><abstract>Hydrazine (N2H4), one of the widest used liquid monopropellant is to be replaced by “greener” propellants based on ammonium dinitramide (ADN, NH4+N(NO2)2-), such as LMP-103S and FLP-106 within the framework of the Horizon 2020 Rheform project. While hydrazine can rely on a catalytic technology based on conventional materials such as γ-Al2O3 (due to the adiabatic decomposition temperature of about 900–1000 °C), LMP-103S and FLP-106 require catalyst support materials that can withstand higher temperatures (about 1650 °C and 1900 °C, respectively) and exhibit a sufficient porosity and resistance to sintering. On these terms, among the various candidates for catalyst support, monolith-shaped supports were investigated.
•Ammonium DiNitramide (ADN) investigated in the form of two liquid propellants blends, namely FLP-106 and LMP-103S.•Several catalysts shapes investigated: granulated catalysts and monolithic catalysts.•3D printing of complex ceramic structures investigated towards a washcoating process.•Decomposition tests of FLP-106 and LMP-103S after impregnation of potential active metal solutions.•Textural behaviour of the washcoat layer studied after several heat treatments up to 1500 °C for different durations.</abstract><cop>Elmsford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.actaastro.2019.03.033</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-6858-2532</orcidid><orcidid>https://orcid.org/0000-0002-9437-1579</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | 3D-printed monolith Aluminum oxide Ammonium Ammonium DiNitramide (ADN) Catalysis Catalysts Catalytic ignition Decomposition Engineering Sciences Green propellant Hydrazines Monolithic materials Monopropellants Nitrogen dioxide Porosity Sintering (powder metallurgy) Transitional aluminas Washcoating |
title | Development of catalytic materials for decomposition of ADN-based monopropellants |
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