Synthesis and UV-light induced oligomerization of a benzofulvene-based neutral platinum(II) complex

[Display omitted] •Neutral platinum(II) complex 2-PTPC-BF3a was prepared from benzofulvene derivative 2-Pyr-BF3a.•Complex 2-PTPC-BF3a was found to aggregate into an ordered crystalline solid-state without significant spontaneous polymerization.•Crystalline powder of 2-PTPC-BF3a is insensible to UV-l...

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Veröffentlicht in:	European polymer journal 2021-08, Vol.156, p.110597, Article 110597
Hauptverfasser:	Paolino, Marco, Reale, Annalisa, Magrini, Giulia, Razzano, Vincenzo, Saletti, Mario, Giuliani, Germano, Donati, Alessandro, Samperi, Filippo, Scamporrino, Andrea, Canetti, Maurizio, Mauro, Matteo, Villafiorita-Monteleone, Francesca, Fois, Ettore, Botta, Chiara, Cappelli, Andrea
Format:	Artikel
Sprache:	eng
Schlagworte:	Agglomeration AIE Chemical Sciences Chemical synthesis Chloroform Crystal structure Crystallinity Light irradiation Mass spectrometry Neutral platinum(II) complex NMR spectroscopy Oligomerization Oligomers Photopolymerization Platinum Polymerization Polymers Solid state Substrates Topochemical polymerization Ultraviolet radiation π-stacked polymer
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