Azobenzene: a Visible‐Light Chemical Actinometer for the Characterization of Fluidic Photosystems

(E)‐Azobenzene is introduced as a suitable chemical actinometer in the visible spectral range (440–540 nm) for photon flux determination of fluidic microphotoreactors or for assessing efficiency of visible light photo‐induced reactions, its evaluation is straightforward without tedious analytics. Ph...

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Veröffentlicht in:Helvetica chimica acta 2021-07, Vol.104 (7), p.n/a
Hauptverfasser: Roseau, Mélanie, De Waele, Vincent, Trivelli, Xavier, Cantrelle, Francois Xavier, Penhoat, Maël, Chausset‐Boissarie, Laëtitia
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container_issue 7
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container_title Helvetica chimica acta
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creator Roseau, Mélanie
De Waele, Vincent
Trivelli, Xavier
Cantrelle, Francois Xavier
Penhoat, Maël
Chausset‐Boissarie, Laëtitia
description (E)‐Azobenzene is introduced as a suitable chemical actinometer in the visible spectral range (440–540 nm) for photon flux determination of fluidic microphotoreactors or for assessing efficiency of visible light photo‐induced reactions, its evaluation is straightforward without tedious analytics. Photoisomerization quantum yields (ΦE→Z) of (E)‐azobenzene were accurately determined upon irradiation at several wavelengths and in different solvents based on well‐known diarylethene.
doi_str_mv 10.1002/hlca.202100071
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source Wiley Online Library Journals Frontfile Complete
subjects Actinometers
actinometry
Azo compounds
azobenzene
Chemical Sciences
Irradiation
microfluidic photoreactor
Organic chemistry
photochemistry
Radiation
visible light
Wavelengths
title Azobenzene: a Visible‐Light Chemical Actinometer for the Characterization of Fluidic Photosystems
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