Second harmonic generation and photochromic grating in polyurethane films containing diazo isoxazole chromophore
The chromophoric intermediate: 2,2′-({4-[( E)-(5-methylisoxazol-3-yl)diazenyl]phenyl}-imino)diethanol was used in polyaddition reaction with di-isocyanate to obtain a new polyurethane polymeric material showing nonlinear optical and photochromic properties. The maximum absorption band of the polymer...
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| Veröffentlicht in: | Optical materials 2008, Vol.30 (12), p.1832-1839 |
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| container_issue | 12 |
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| container_title | Optical materials |
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| creator | Marański, Krzysztof Kucharski, Stanisław Ortyl, Ewelina Nunzi, Jean-Michel Ahmadi-Kandjani, Sohrab Dabos-Seignon, Sylvie Chan, Siu-Wai Barille, Regis |
| description | The chromophoric intermediate: 2,2′-({4-[(
E)-(5-methylisoxazol-3-yl)diazenyl]phenyl}-imino)diethanol was used in polyaddition reaction with di-isocyanate to obtain a new polyurethane polymeric material showing nonlinear optical and photochromic properties. The maximum absorption band of the polymer film was at 418
nm. The illumination of the film with crossed beams of the 488
nm Ar
+ laser yielded surface relief grating of regular structure. Measurement of the frequency doubling signal with 1064
nm laser indicated the polymer as interesting material for photooptical applications. The measured nonlinear optical coefficient,
d
33, reached 90.2
pm/V. |
| doi_str_mv | 10.1016/j.optmat.2007.11.030 |
| format | Article |
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E)-(5-methylisoxazol-3-yl)diazenyl]phenyl}-imino)diethanol was used in polyaddition reaction with di-isocyanate to obtain a new polyurethane polymeric material showing nonlinear optical and photochromic properties. The maximum absorption band of the polymer film was at 418
nm. The illumination of the film with crossed beams of the 488
nm Ar
+ laser yielded surface relief grating of regular structure. Measurement of the frequency doubling signal with 1064
nm laser indicated the polymer as interesting material for photooptical applications. The measured nonlinear optical coefficient,
d
33, reached 90.2
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E)-(5-methylisoxazol-3-yl)diazenyl]phenyl}-imino)diethanol was used in polyaddition reaction with di-isocyanate to obtain a new polyurethane polymeric material showing nonlinear optical and photochromic properties. The maximum absorption band of the polymer film was at 418
nm. The illumination of the film with crossed beams of the 488
nm Ar
+ laser yielded surface relief grating of regular structure. Measurement of the frequency doubling signal with 1064
nm laser indicated the polymer as interesting material for photooptical applications. The measured nonlinear optical coefficient,
d
33, reached 90.2
pm/V.</description><subject>Diffraction grating</subject><subject>Exact sciences and technology</subject><subject>Frequency conversion ; harmonic generation, including high-order harmonic generation</subject><subject>Fundamental areas of phenomenology (including applications)</subject><subject>Holographic recording materials; optical storage media</subject><subject>Life Sciences</subject><subject>Nonlinear optics</subject><subject>Optical materials</subject><subject>Optics</subject><subject>Physics</subject><subject>Polymers and organics</subject><subject>Polyurethane polymer</subject><subject>Second harmonic generation</subject><issn>0925-3467</issn><issn>1873-1252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kEFr3TAQhEVpIK9p_kEOuvTQg52VZEv2pRBC0wQe9NDcxUaWYj1syUhuaPrrK9clx54WZr-ZZYeQKwY1AyavT3Vc1hnXmgOomrEaBLwjB9YpUTHe8vfkAD1vK9FIdU4-5HwCAN5KeSDLD2tiGOiIaY7BG_psg024-hgoFn0Z4xrNmOK87bZFeKY-0CVOrz-TXUcMljo_zZmWnBV92IDB4-9IfY6_ypws_RsQS1ayH8mZwynby3_zgjzefX28va-O37893N4cKyMUrNUAKBVXkquOC6Watm0FSsdNz3rneuVQ9s3ApcPODk3fNa594rIT5kmUDkBckM977IiTXpKfMb3qiF7f3xz1poFoODQgX1hhm501KeacrHszMNBbwfqk94L1VrBmrLi3E59224LZ4OQSBuPzm5dDK7nkfeG-7Jwt7754m3Q23gZjB5-sWfUQ_f8P_QGpTZS4</recordid><startdate>2008</startdate><enddate>2008</enddate><creator>Marański, Krzysztof</creator><creator>Kucharski, Stanisław</creator><creator>Ortyl, Ewelina</creator><creator>Nunzi, Jean-Michel</creator><creator>Ahmadi-Kandjani, Sohrab</creator><creator>Dabos-Seignon, Sylvie</creator><creator>Chan, Siu-Wai</creator><creator>Barille, Regis</creator><general>Elsevier B.V</general><general>Elsevier Science</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-7900-6354</orcidid><orcidid>https://orcid.org/0000-0001-8792-5118</orcidid><orcidid>https://orcid.org/0000-0001-5490-4273</orcidid></search><sort><creationdate>2008</creationdate><title>Second harmonic generation and photochromic grating in polyurethane films containing diazo isoxazole chromophore</title><author>Marański, Krzysztof ; Kucharski, Stanisław ; Ortyl, Ewelina ; Nunzi, Jean-Michel ; Ahmadi-Kandjani, Sohrab ; Dabos-Seignon, Sylvie ; Chan, Siu-Wai ; Barille, Regis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-d0a67276278237745553a6f2c919ff97fa694d26fa8ed4984f5b2683cb300703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Diffraction grating</topic><topic>Exact sciences and technology</topic><topic>Frequency conversion ; harmonic generation, including high-order harmonic generation</topic><topic>Fundamental areas of phenomenology (including applications)</topic><topic>Holographic recording materials; optical storage media</topic><topic>Life Sciences</topic><topic>Nonlinear optics</topic><topic>Optical materials</topic><topic>Optics</topic><topic>Physics</topic><topic>Polymers and organics</topic><topic>Polyurethane polymer</topic><topic>Second harmonic generation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Marański, Krzysztof</creatorcontrib><creatorcontrib>Kucharski, Stanisław</creatorcontrib><creatorcontrib>Ortyl, Ewelina</creatorcontrib><creatorcontrib>Nunzi, Jean-Michel</creatorcontrib><creatorcontrib>Ahmadi-Kandjani, Sohrab</creatorcontrib><creatorcontrib>Dabos-Seignon, Sylvie</creatorcontrib><creatorcontrib>Chan, Siu-Wai</creatorcontrib><creatorcontrib>Barille, Regis</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Optical materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Marański, Krzysztof</au><au>Kucharski, Stanisław</au><au>Ortyl, Ewelina</au><au>Nunzi, Jean-Michel</au><au>Ahmadi-Kandjani, Sohrab</au><au>Dabos-Seignon, Sylvie</au><au>Chan, Siu-Wai</au><au>Barille, Regis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Second harmonic generation and photochromic grating in polyurethane films containing diazo isoxazole chromophore</atitle><jtitle>Optical materials</jtitle><date>2008</date><risdate>2008</risdate><volume>30</volume><issue>12</issue><spage>1832</spage><epage>1839</epage><pages>1832-1839</pages><issn>0925-3467</issn><eissn>1873-1252</eissn><abstract>The chromophoric intermediate: 2,2′-({4-[(
E)-(5-methylisoxazol-3-yl)diazenyl]phenyl}-imino)diethanol was used in polyaddition reaction with di-isocyanate to obtain a new polyurethane polymeric material showing nonlinear optical and photochromic properties. The maximum absorption band of the polymer film was at 418
nm. The illumination of the film with crossed beams of the 488
nm Ar
+ laser yielded surface relief grating of regular structure. Measurement of the frequency doubling signal with 1064
nm laser indicated the polymer as interesting material for photooptical applications. The measured nonlinear optical coefficient,
d
33, reached 90.2
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| fulltext | fulltext |
| identifier | ISSN: 0925-3467 |
| ispartof | Optical materials, 2008, Vol.30 (12), p.1832-1839 |
| issn | 0925-3467 1873-1252 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_03420406v1 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Diffraction grating Exact sciences and technology Frequency conversion harmonic generation, including high-order harmonic generation Fundamental areas of phenomenology (including applications) Holographic recording materials optical storage media Life Sciences Nonlinear optics Optical materials Optics Physics Polymers and organics Polyurethane polymer Second harmonic generation |
| title | Second harmonic generation and photochromic grating in polyurethane films containing diazo isoxazole chromophore |
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