Strained and Reactive Donor/Acceptor‐Supported Metallasilanone
A novel stable donor/acceptor‐supported MnI‐metallasilanone 3 was synthesized. The intramolecular silanone‐MnI interaction induces a highly strained three‐membered cyclic structure, leading to an exceptionally high reactivity of 3 as a donor/acceptor complex of silanone. Indeed, metallasilanone 3 re...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2021-08, Vol.60 (34), p.18489-18493 |
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| creator | Takahashi, Shintaro Ramos‐Enríquez, Manuel A. Bellan, Ekaterina Baceiredo, Antoine Saffon‐Merceron, Nathalie Nakata, Norio Hashizume, Daisuke Branchadell, Vicenç Kato, Tsuyoshi |
| description | A novel stable donor/acceptor‐supported MnI‐metallasilanone 3 was synthesized. The intramolecular silanone‐MnI interaction induces a highly strained three‐membered cyclic structure, leading to an exceptionally high reactivity of 3 as a donor/acceptor complex of silanone. Indeed, metallasilanone 3 readily reacts with various small molecules such as H2 or ethylene gas in mild conditions.
A new stable donor/acceptor‐supported MnI‐metallasilanone was synthesized. This silanone complex is highly strained because of its incorporation in a small cyclic structure formed by the intramolecular silanone‐MnI interaction. Thanks to the high ring strain, the interaction Si=O→Mn is labile, leading to an exceptionally high reactivity with various small molecules such as H2 or ethylene gas in mild conditions. |
| doi_str_mv | 10.1002/anie.202105526 |
| format | Article |
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A new stable donor/acceptor‐supported MnI‐metallasilanone was synthesized. This silanone complex is highly strained because of its incorporation in a small cyclic structure formed by the intramolecular silanone‐MnI interaction. Thanks to the high ring strain, the interaction Si=O→Mn is labile, leading to an exceptionally high reactivity with various small molecules such as H2 or ethylene gas in mild conditions.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202105526</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Chemical Sciences ; Coordination compounds ; donor-acceptor systems ; Lewis pair ; manganese complex ; metallacycles ; stable silanone</subject><ispartof>Angewandte Chemie International Edition, 2021-08, Vol.60 (34), p.18489-18493</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4906-be962a34ad1c273a1b5bad7e577e675fa055b4ae4836cec74acaa2829349ce863</citedby><cites>FETCH-LOGICAL-c4906-be962a34ad1c273a1b5bad7e577e675fa055b4ae4836cec74acaa2829349ce863</cites><orcidid>0000-0001-9003-4455 ; 0000-0002-5288-6021 ; 0000-0003-3480-1669 ; 0000-0002-0301-4163 ; 0000-0002-6428-9697</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202105526$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202105526$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03407088$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Takahashi, Shintaro</creatorcontrib><creatorcontrib>Ramos‐Enríquez, Manuel A.</creatorcontrib><creatorcontrib>Bellan, Ekaterina</creatorcontrib><creatorcontrib>Baceiredo, Antoine</creatorcontrib><creatorcontrib>Saffon‐Merceron, Nathalie</creatorcontrib><creatorcontrib>Nakata, Norio</creatorcontrib><creatorcontrib>Hashizume, Daisuke</creatorcontrib><creatorcontrib>Branchadell, Vicenç</creatorcontrib><creatorcontrib>Kato, Tsuyoshi</creatorcontrib><title>Strained and Reactive Donor/Acceptor‐Supported Metallasilanone</title><title>Angewandte Chemie International Edition</title><description>A novel stable donor/acceptor‐supported MnI‐metallasilanone 3 was synthesized. The intramolecular silanone‐MnI interaction induces a highly strained three‐membered cyclic structure, leading to an exceptionally high reactivity of 3 as a donor/acceptor complex of silanone. Indeed, metallasilanone 3 readily reacts with various small molecules such as H2 or ethylene gas in mild conditions.
A new stable donor/acceptor‐supported MnI‐metallasilanone was synthesized. This silanone complex is highly strained because of its incorporation in a small cyclic structure formed by the intramolecular silanone‐MnI interaction. Thanks to the high ring strain, the interaction Si=O→Mn is labile, leading to an exceptionally high reactivity with various small molecules such as H2 or ethylene gas in mild conditions.</description><subject>Chemical Sciences</subject><subject>Coordination compounds</subject><subject>donor-acceptor systems</subject><subject>Lewis pair</subject><subject>manganese complex</subject><subject>metallacycles</subject><subject>stable silanone</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqF0MtKxDAUBuAiCuro1vWAG110zLVJdw7eYVRwdB1O0zPYoTY1aUfc-Qg-o09ihpER3LhKCN8f_nOS5ICSESWEnUBT4YgRRomULNtIdqhkNOVK8c14F5ynSku6neyGMI9ea5LtJKfTzkPVYDmEphw-INiuWuDw3DXOn4ytxbZz_uvjc9q3rfNddLfYQV1DqGpoXIN7ydYM6oD7P-cgebq8eDy7Tif3Vzdn40lqRU6ytMA8Y8AFlNQyxYEWsoBSoVQKMyVnEEsXAlBonlm0SoAFYJrlXOQWdcYHyfHq32eoTeurF_DvxkFlrscTs3wjXBBFtF7QaI9WtvXutcfQmZcqWIytG3R9MEwKITIm5JIe_qFz1_smThKVzLkWgpOoRitlvQvB42zdgBKzXL5ZLt-slx8D-SrwVtX4_o8247ubi9_sN2nuh_c</recordid><startdate>20210816</startdate><enddate>20210816</enddate><creator>Takahashi, Shintaro</creator><creator>Ramos‐Enríquez, Manuel A.</creator><creator>Bellan, Ekaterina</creator><creator>Baceiredo, Antoine</creator><creator>Saffon‐Merceron, Nathalie</creator><creator>Nakata, Norio</creator><creator>Hashizume, Daisuke</creator><creator>Branchadell, Vicenç</creator><creator>Kato, Tsuyoshi</creator><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-9003-4455</orcidid><orcidid>https://orcid.org/0000-0002-5288-6021</orcidid><orcidid>https://orcid.org/0000-0003-3480-1669</orcidid><orcidid>https://orcid.org/0000-0002-0301-4163</orcidid><orcidid>https://orcid.org/0000-0002-6428-9697</orcidid></search><sort><creationdate>20210816</creationdate><title>Strained and Reactive Donor/Acceptor‐Supported Metallasilanone</title><author>Takahashi, Shintaro ; Ramos‐Enríquez, Manuel A. ; Bellan, Ekaterina ; Baceiredo, Antoine ; Saffon‐Merceron, Nathalie ; Nakata, Norio ; Hashizume, Daisuke ; Branchadell, Vicenç ; Kato, Tsuyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4906-be962a34ad1c273a1b5bad7e577e675fa055b4ae4836cec74acaa2829349ce863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical Sciences</topic><topic>Coordination compounds</topic><topic>donor-acceptor systems</topic><topic>Lewis pair</topic><topic>manganese complex</topic><topic>metallacycles</topic><topic>stable silanone</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Takahashi, Shintaro</creatorcontrib><creatorcontrib>Ramos‐Enríquez, Manuel A.</creatorcontrib><creatorcontrib>Bellan, Ekaterina</creatorcontrib><creatorcontrib>Baceiredo, Antoine</creatorcontrib><creatorcontrib>Saffon‐Merceron, Nathalie</creatorcontrib><creatorcontrib>Nakata, Norio</creatorcontrib><creatorcontrib>Hashizume, Daisuke</creatorcontrib><creatorcontrib>Branchadell, Vicenç</creatorcontrib><creatorcontrib>Kato, Tsuyoshi</creatorcontrib><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Takahashi, Shintaro</au><au>Ramos‐Enríquez, Manuel A.</au><au>Bellan, Ekaterina</au><au>Baceiredo, Antoine</au><au>Saffon‐Merceron, Nathalie</au><au>Nakata, Norio</au><au>Hashizume, Daisuke</au><au>Branchadell, Vicenç</au><au>Kato, Tsuyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Strained and Reactive Donor/Acceptor‐Supported Metallasilanone</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2021-08-16</date><risdate>2021</risdate><volume>60</volume><issue>34</issue><spage>18489</spage><epage>18493</epage><pages>18489-18493</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>A novel stable donor/acceptor‐supported MnI‐metallasilanone 3 was synthesized. The intramolecular silanone‐MnI interaction induces a highly strained three‐membered cyclic structure, leading to an exceptionally high reactivity of 3 as a donor/acceptor complex of silanone. Indeed, metallasilanone 3 readily reacts with various small molecules such as H2 or ethylene gas in mild conditions.
A new stable donor/acceptor‐supported MnI‐metallasilanone was synthesized. This silanone complex is highly strained because of its incorporation in a small cyclic structure formed by the intramolecular silanone‐MnI interaction. Thanks to the high ring strain, the interaction Si=O→Mn is labile, leading to an exceptionally high reactivity with various small molecules such as H2 or ethylene gas in mild conditions.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.202105526</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0001-9003-4455</orcidid><orcidid>https://orcid.org/0000-0002-5288-6021</orcidid><orcidid>https://orcid.org/0000-0003-3480-1669</orcidid><orcidid>https://orcid.org/0000-0002-0301-4163</orcidid><orcidid>https://orcid.org/0000-0002-6428-9697</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Chemical Sciences Coordination compounds donor-acceptor systems Lewis pair manganese complex metallacycles stable silanone |
| title | Strained and Reactive Donor/Acceptor‐Supported Metallasilanone |
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