Metal‐Free Visible‐Light Synthesis of Arylsulfonyl Fluorides: Scope and Mechanism

The first metal‐free procedure for the synthesis of arylsulfonyl fluorides is reported. Under organo‐photoredox conditions, aryl diazonium salts react with a readily available SO2 source (DABSO) to afford the desired product through simple nucleophilic fluorination. The reaction tolerates the presen...

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Veröffentlicht in:	Chemistry : a European journal 2021-06, Vol.27 (34), p.8704-8708
Hauptverfasser:	Louvel, Dan, Chelagha, Aida, Rouillon, Jean, Payard, Pierre‐Adrien, Khrouz, Lhoussain, Monnereau, Cyrille, Tlili, Anis
Format:	Artikel
Sprache:	eng
Schlagworte:	arylsulfonyl fluorides Chemical Sciences Chemistry Fluorescence Fluorides Fluorination fluorine Functional groups mechanistic investigations metal-free synthesis NMR Nuclear magnetic resonance organo-photoredox Reaction mechanisms Salts Spectroscopy Sulfur dioxide Synthesis
Online-Zugang:	Volltext
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