Hydrophobic chemical surface functionalization of hydroxyapatite nanoparticles for naphthalene removal
[Display omitted] Hydrophobic apatite monolith nanoparticles were prepared by grafting of dodecylphosphate (DP) onto hydroxyapatite. A modification in the synthesis was used to develop a hydrophobic surface in order to improve the dispersion and compatibility of organoapatite particles for the sensi...
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| Veröffentlicht in: | Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2020-06, Vol.595, p.124706, Article 124706 |
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| container_title | Colloids and surfaces. A, Physicochemical and engineering aspects |
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| creator | Bouiahya, K. Oulguidoum, A. Laghzizil, A. Shalabi, M. Nunzi, J.M. MASSE, Sylvie |
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Hydrophobic apatite monolith nanoparticles were prepared by grafting of dodecylphosphate (DP) onto hydroxyapatite. A modification in the synthesis was used to develop a hydrophobic surface in order to improve the dispersion and compatibility of organoapatite particles for the sensing and separation of hydrophobic substances. Results indicate that DP grafting onto the apatite is quantitative. Structural analyses of the as-received materials show that the grafting approach did not significantly alter the apatite microstructure, but modifies the hydrophobic character and surface properties of the hybrid material. Conversion of the hydrophilic surface of hydroxyapatite to hydrophobic was carried out to better retain naphthalene as a polynuclear aromatic hydrocarbon model. |
| doi_str_mv | 10.1016/j.colsurfa.2020.124706 |
| format | Article |
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Hydrophobic apatite monolith nanoparticles were prepared by grafting of dodecylphosphate (DP) onto hydroxyapatite. A modification in the synthesis was used to develop a hydrophobic surface in order to improve the dispersion and compatibility of organoapatite particles for the sensing and separation of hydrophobic substances. Results indicate that DP grafting onto the apatite is quantitative. Structural analyses of the as-received materials show that the grafting approach did not significantly alter the apatite microstructure, but modifies the hydrophobic character and surface properties of the hybrid material. Conversion of the hydrophilic surface of hydroxyapatite to hydrophobic was carried out to better retain naphthalene as a polynuclear aromatic hydrocarbon model.</description><identifier>ISSN: 0927-7757</identifier><identifier>EISSN: 1873-4359</identifier><identifier>DOI: 10.1016/j.colsurfa.2020.124706</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Adsorption ; Chemical Sciences ; Hybrid hydroxyapatite ; Hydrophilic/hydrophobic surface ; Material chemistry ; Nanoparticles</subject><ispartof>Colloids and surfaces. A, Physicochemical and engineering aspects, 2020-06, Vol.595, p.124706, Article 124706</ispartof><rights>2020</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c394t-aece55c33dbe7c0ffc6962743cf1bd92cb8ae83b3ed52a1cb441084ab8d3e0f43</citedby><cites>FETCH-LOGICAL-c394t-aece55c33dbe7c0ffc6962743cf1bd92cb8ae83b3ed52a1cb441084ab8d3e0f43</cites><orcidid>0000-0001-5490-4273 ; 0000-0001-9608-0583 ; 0000-0001-9448-7013</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0927775720302995$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://hal.sorbonne-universite.fr/hal-03348487$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Bouiahya, K.</creatorcontrib><creatorcontrib>Oulguidoum, A.</creatorcontrib><creatorcontrib>Laghzizil, A.</creatorcontrib><creatorcontrib>Shalabi, M.</creatorcontrib><creatorcontrib>Nunzi, J.M.</creatorcontrib><creatorcontrib>MASSE, Sylvie</creatorcontrib><title>Hydrophobic chemical surface functionalization of hydroxyapatite nanoparticles for naphthalene removal</title><title>Colloids and surfaces. A, Physicochemical and engineering aspects</title><description>[Display omitted]
Hydrophobic apatite monolith nanoparticles were prepared by grafting of dodecylphosphate (DP) onto hydroxyapatite. A modification in the synthesis was used to develop a hydrophobic surface in order to improve the dispersion and compatibility of organoapatite particles for the sensing and separation of hydrophobic substances. Results indicate that DP grafting onto the apatite is quantitative. Structural analyses of the as-received materials show that the grafting approach did not significantly alter the apatite microstructure, but modifies the hydrophobic character and surface properties of the hybrid material. Conversion of the hydrophilic surface of hydroxyapatite to hydrophobic was carried out to better retain naphthalene as a polynuclear aromatic hydrocarbon model.</description><subject>Adsorption</subject><subject>Chemical Sciences</subject><subject>Hybrid hydroxyapatite</subject><subject>Hydrophilic/hydrophobic surface</subject><subject>Material chemistry</subject><subject>Nanoparticles</subject><issn>0927-7757</issn><issn>1873-4359</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkMFOwzAQRC0EEqXwC8hXDil27MTJjaoCilSJC5wtZ7NWXKVxZKcV5etJKHDltKunmVntEHLL2YIznt9vF-DbuA_WLFKWjjCViuVnZMYLJRIpsvKczFiZqkSpTF2Sqxi3jDGZqXJG7PpYB983vnJAocGdA9PS7zRAavcdDM53pnWfZlqot7SZHB9H049kQNqZzvcmDA5ajNT6MJK-GRrTYoc04M4fTHtNLqxpI978zDl5f3p8W62Tzevzy2q5SUCUckgMAmYZCFFXqIBZC3mZp0oKsLyqyxSqwmAhKoF1lhoOlZScFdJURS2QWSnm5O6UO57XfXA7E47aG6fXy42eGBNCFrJQBz5q85MWgo8xoP0zcKanZvVW_zarp2b1qdnR-HAy4vjJwWHQERx2gLULCIOuvfsv4gv1GIlc</recordid><startdate>20200620</startdate><enddate>20200620</enddate><creator>Bouiahya, K.</creator><creator>Oulguidoum, A.</creator><creator>Laghzizil, A.</creator><creator>Shalabi, M.</creator><creator>Nunzi, J.M.</creator><creator>MASSE, Sylvie</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0001-5490-4273</orcidid><orcidid>https://orcid.org/0000-0001-9608-0583</orcidid><orcidid>https://orcid.org/0000-0001-9448-7013</orcidid></search><sort><creationdate>20200620</creationdate><title>Hydrophobic chemical surface functionalization of hydroxyapatite nanoparticles for naphthalene removal</title><author>Bouiahya, K. ; Oulguidoum, A. ; Laghzizil, A. ; Shalabi, M. ; Nunzi, J.M. ; MASSE, Sylvie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c394t-aece55c33dbe7c0ffc6962743cf1bd92cb8ae83b3ed52a1cb441084ab8d3e0f43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Chemical Sciences</topic><topic>Hybrid hydroxyapatite</topic><topic>Hydrophilic/hydrophobic surface</topic><topic>Material chemistry</topic><topic>Nanoparticles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bouiahya, K.</creatorcontrib><creatorcontrib>Oulguidoum, A.</creatorcontrib><creatorcontrib>Laghzizil, A.</creatorcontrib><creatorcontrib>Shalabi, M.</creatorcontrib><creatorcontrib>Nunzi, J.M.</creatorcontrib><creatorcontrib>MASSE, Sylvie</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Colloids and surfaces. A, Physicochemical and engineering aspects</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bouiahya, K.</au><au>Oulguidoum, A.</au><au>Laghzizil, A.</au><au>Shalabi, M.</au><au>Nunzi, J.M.</au><au>MASSE, Sylvie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrophobic chemical surface functionalization of hydroxyapatite nanoparticles for naphthalene removal</atitle><jtitle>Colloids and surfaces. A, Physicochemical and engineering aspects</jtitle><date>2020-06-20</date><risdate>2020</risdate><volume>595</volume><spage>124706</spage><pages>124706-</pages><artnum>124706</artnum><issn>0927-7757</issn><eissn>1873-4359</eissn><abstract>[Display omitted]
Hydrophobic apatite monolith nanoparticles were prepared by grafting of dodecylphosphate (DP) onto hydroxyapatite. A modification in the synthesis was used to develop a hydrophobic surface in order to improve the dispersion and compatibility of organoapatite particles for the sensing and separation of hydrophobic substances. Results indicate that DP grafting onto the apatite is quantitative. Structural analyses of the as-received materials show that the grafting approach did not significantly alter the apatite microstructure, but modifies the hydrophobic character and surface properties of the hybrid material. Conversion of the hydrophilic surface of hydroxyapatite to hydrophobic was carried out to better retain naphthalene as a polynuclear aromatic hydrocarbon model.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.colsurfa.2020.124706</doi><orcidid>https://orcid.org/0000-0001-5490-4273</orcidid><orcidid>https://orcid.org/0000-0001-9608-0583</orcidid><orcidid>https://orcid.org/0000-0001-9448-7013</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Colloids and surfaces. A, Physicochemical and engineering aspects, 2020-06, Vol.595, p.124706, Article 124706 |
| issn | 0927-7757 1873-4359 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Adsorption Chemical Sciences Hybrid hydroxyapatite Hydrophilic/hydrophobic surface Material chemistry Nanoparticles |
| title | Hydrophobic chemical surface functionalization of hydroxyapatite nanoparticles for naphthalene removal |
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