Novel Styrylquinolinium Dye Thin Films Deposited by Pulsed Laser Deposition for Nonlinear Optical Applications
The nonlinear optical (NLO) properties of novel styrylquinolinium dye thin films for photonic applications have been studied by the Z-scan, second harmonic generation (SHG), and third harmonic generation (THG) techniques, providing both the second- and third-order nonlinear optical parameters. The s...
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| Veröffentlicht in: | Journal of physical chemistry. C 2012-03, Vol.116 (12), p.7144-7152 |
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| creator | El Ouazzani, H Dabos-Seignon, Sylvie Gindre, D Iliopoulos, K Todorova, M Bakalska, R Penchev, P Sotirov, S Kolev, Ts Serbezov, V Arbaoui, A Bakasse, M Sahraoui, B |
| description | The nonlinear optical (NLO) properties of novel styrylquinolinium dye thin films for photonic applications have been studied by the Z-scan, second harmonic generation (SHG), and third harmonic generation (THG) techniques, providing both the second- and third-order nonlinear optical parameters. The styrylquinolinium dye (E)-1-ethyl-4-(2-(4-hydroxynaphthalen-1-yl)vinyl)quinolinium bromide was synthesized by the Knoevenagel condensation, and its structure and physicochemical properties were determined by 1H NMR, 13C NMR, FTIR, UV–vis spectroscopy, and elemental analysis. Functional thin films were deposited by pulsed laser deposition (PLD) using UV TEA N2 laser onto glass substrates and KCl, NaCl monocrystals at room temperature and vacuum at 10–3 mbar/0.1 Pa. Further characterization of the films and target from native material by FTIR spectroscopy revealed that there was no difference between the deposited films and the initial material. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) measurements have been also performed in order to provide information about the morphology and topology of the thin films. |
| doi_str_mv | 10.1021/jp2118218 |
| format | Article |
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The styrylquinolinium dye (E)-1-ethyl-4-(2-(4-hydroxynaphthalen-1-yl)vinyl)quinolinium bromide was synthesized by the Knoevenagel condensation, and its structure and physicochemical properties were determined by 1H NMR, 13C NMR, FTIR, UV–vis spectroscopy, and elemental analysis. Functional thin films were deposited by pulsed laser deposition (PLD) using UV TEA N2 laser onto glass substrates and KCl, NaCl monocrystals at room temperature and vacuum at 10–3 mbar/0.1 Pa. Further characterization of the films and target from native material by FTIR spectroscopy revealed that there was no difference between the deposited films and the initial material. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) measurements have been also performed in order to provide information about the morphology and topology of the thin films.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp2118218</identifier><language>eng</language><publisher>Columbus, OH: American Chemical Society</publisher><subject>Chemical Sciences ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Fundamental areas of phenomenology (including applications) ; Laser deposition ; Materials science ; Methods of deposition of films and coatings; film growth and epitaxy ; Optical materials ; Optics ; Physics</subject><ispartof>Journal of physical chemistry. 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C</title><addtitle>J. Phys. Chem. C</addtitle><description>The nonlinear optical (NLO) properties of novel styrylquinolinium dye thin films for photonic applications have been studied by the Z-scan, second harmonic generation (SHG), and third harmonic generation (THG) techniques, providing both the second- and third-order nonlinear optical parameters. The styrylquinolinium dye (E)-1-ethyl-4-(2-(4-hydroxynaphthalen-1-yl)vinyl)quinolinium bromide was synthesized by the Knoevenagel condensation, and its structure and physicochemical properties were determined by 1H NMR, 13C NMR, FTIR, UV–vis spectroscopy, and elemental analysis. Functional thin films were deposited by pulsed laser deposition (PLD) using UV TEA N2 laser onto glass substrates and KCl, NaCl monocrystals at room temperature and vacuum at 10–3 mbar/0.1 Pa. Further characterization of the films and target from native material by FTIR spectroscopy revealed that there was no difference between the deposited films and the initial material. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) measurements have been also performed in order to provide information about the morphology and topology of the thin films.</description><subject>Chemical Sciences</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Fundamental areas of phenomenology (including applications)</subject><subject>Laser deposition</subject><subject>Materials science</subject><subject>Methods of deposition of films and coatings; film growth and epitaxy</subject><subject>Optical materials</subject><subject>Optics</subject><subject>Physics</subject><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkM1OwzAQhC0EEqVw4A184cAh4N84PlYtpUhRi0Q5R07iqK5SO9gJUt6eVIX0wmlHu9-MNAvAPUZPGBH8vG8IxgnByQWYYElJJBjnl6Nm4hrchLBHiFOE6QTYtfvWNfxoe9_XX52xrjbWdAe46DXc7oyFS1MfAlzoxgXT6hLmPXzv6jCoVAXt_y7GWVg5D9fODglaebhpWlOoGs6aph7EkQi34KpSg_nud07B5_JlO19F6eb1bT5LI0V50kaSiLxkJC8UiTVKEEKMF4VIKoF1UiaMlDKWuVSqzHklOROViMtS8zhBWHNC6RQ8nnJ3qs4abw7K95lTJlvN0uy4Q5QyFkv0jc9s4V0IXlejAaPs-NRsfOrAPpzYRoWhW-WVLUwYDYQLiRmjZ04VIdu7ztuh7T95P9kegr0</recordid><startdate>20120329</startdate><enddate>20120329</enddate><creator>El Ouazzani, H</creator><creator>Dabos-Seignon, Sylvie</creator><creator>Gindre, D</creator><creator>Iliopoulos, K</creator><creator>Todorova, M</creator><creator>Bakalska, R</creator><creator>Penchev, P</creator><creator>Sotirov, S</creator><creator>Kolev, Ts</creator><creator>Serbezov, V</creator><creator>Arbaoui, A</creator><creator>Bakasse, M</creator><creator>Sahraoui, B</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-7900-6354</orcidid><orcidid>https://orcid.org/0000-0002-3934-2839</orcidid><orcidid>https://orcid.org/0000-0002-2844-4936</orcidid></search><sort><creationdate>20120329</creationdate><title>Novel Styrylquinolinium Dye Thin Films Deposited by Pulsed Laser Deposition for Nonlinear Optical Applications</title><author>El Ouazzani, H ; Dabos-Seignon, Sylvie ; Gindre, D ; Iliopoulos, K ; Todorova, M ; Bakalska, R ; Penchev, P ; Sotirov, S ; Kolev, Ts ; Serbezov, V ; Arbaoui, A ; Bakasse, M ; Sahraoui, B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a358t-927bd42bca26e0800045cc78f71e8d842d969b9aadb5f9547f76dde56801e5233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemical Sciences</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Fundamental areas of phenomenology (including applications)</topic><topic>Laser deposition</topic><topic>Materials science</topic><topic>Methods of deposition of films and coatings; film growth and epitaxy</topic><topic>Optical materials</topic><topic>Optics</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El Ouazzani, H</creatorcontrib><creatorcontrib>Dabos-Seignon, Sylvie</creatorcontrib><creatorcontrib>Gindre, D</creatorcontrib><creatorcontrib>Iliopoulos, K</creatorcontrib><creatorcontrib>Todorova, M</creatorcontrib><creatorcontrib>Bakalska, R</creatorcontrib><creatorcontrib>Penchev, P</creatorcontrib><creatorcontrib>Sotirov, S</creatorcontrib><creatorcontrib>Kolev, Ts</creatorcontrib><creatorcontrib>Serbezov, V</creatorcontrib><creatorcontrib>Arbaoui, A</creatorcontrib><creatorcontrib>Bakasse, M</creatorcontrib><creatorcontrib>Sahraoui, B</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of physical chemistry. 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C</addtitle><date>2012-03-29</date><risdate>2012</risdate><volume>116</volume><issue>12</issue><spage>7144</spage><epage>7152</epage><pages>7144-7152</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>The nonlinear optical (NLO) properties of novel styrylquinolinium dye thin films for photonic applications have been studied by the Z-scan, second harmonic generation (SHG), and third harmonic generation (THG) techniques, providing both the second- and third-order nonlinear optical parameters. The styrylquinolinium dye (E)-1-ethyl-4-(2-(4-hydroxynaphthalen-1-yl)vinyl)quinolinium bromide was synthesized by the Knoevenagel condensation, and its structure and physicochemical properties were determined by 1H NMR, 13C NMR, FTIR, UV–vis spectroscopy, and elemental analysis. Functional thin films were deposited by pulsed laser deposition (PLD) using UV TEA N2 laser onto glass substrates and KCl, NaCl monocrystals at room temperature and vacuum at 10–3 mbar/0.1 Pa. Further characterization of the films and target from native material by FTIR spectroscopy revealed that there was no difference between the deposited films and the initial material. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) measurements have been also performed in order to provide information about the morphology and topology of the thin films.</abstract><cop>Columbus, OH</cop><pub>American Chemical Society</pub><doi>10.1021/jp2118218</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-7900-6354</orcidid><orcidid>https://orcid.org/0000-0002-3934-2839</orcidid><orcidid>https://orcid.org/0000-0002-2844-4936</orcidid><oa>free_for_read</oa></addata></record> |
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| source | American Chemical Society Journals |
| subjects | Chemical Sciences Cross-disciplinary physics: materials science rheology Exact sciences and technology Fundamental areas of phenomenology (including applications) Laser deposition Materials science Methods of deposition of films and coatings film growth and epitaxy Optical materials Optics Physics |
| title | Novel Styrylquinolinium Dye Thin Films Deposited by Pulsed Laser Deposition for Nonlinear Optical Applications |
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