Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties
In this work, we explored the elaboration of new smart paper by coating fiber-based materials with CNC for possible use in packaging. Particularly, we investigated application of a 100% CNC layer onto a substrate. Mainly due to the cost and limited availability of CNC on a large scale, few studies h...
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Veröffentlicht in: | Journal of materials science 2017-03, Vol.52 (6), p.3048-3061 |
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creator | Gicquel, Erwan Martin, Céline Garrido Yanez, José Bras, Julien |
description | In this work, we explored the elaboration of new smart paper by coating fiber-based materials with CNC for possible use in packaging. Particularly, we investigated application of a 100% CNC layer onto a substrate. Mainly due to the cost and limited availability of CNC on a large scale, few studies have examined these opportunities. Several layers of CNC were deposited onto a paper material using the bar-coating process to improve relevant properties of the paper surface. Surface analyses (atomic force microscopy, scanning electron microscopy, and transmission electron microscopy) were performed to elucidate the CNC network at the paper surface. Structural and mechanical properties of the final materials were evaluated. Results of general interest were obtained about barrier properties. The air barrier and grease resistance improve only with the paper coated with CNC. To complete this research, a small amount of polyethylene glycol was added to reinforce the brittle CNC coating and clearly enhance barrier properties of the paper. |
doi_str_mv | 10.1007/s10853-016-0589-x |
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Particularly, we investigated application of a 100% CNC layer onto a substrate. Mainly due to the cost and limited availability of CNC on a large scale, few studies have examined these opportunities. Several layers of CNC were deposited onto a paper material using the bar-coating process to improve relevant properties of the paper surface. Surface analyses (atomic force microscopy, scanning electron microscopy, and transmission electron microscopy) were performed to elucidate the CNC network at the paper surface. Structural and mechanical properties of the final materials were evaluated. Results of general interest were obtained about barrier properties. The air barrier and grease resistance improve only with the paper coated with CNC. To complete this research, a small amount of polyethylene glycol was added to reinforce the brittle CNC coating and clearly enhance barrier properties of the paper.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-016-0589-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analysis ; Atomic force microscopy ; Cellulose ; Cellulose fibers ; Characterization and Evaluation of Materials ; Chemical engineering ; Chemical Sciences ; Chemistry and Materials Science ; Classical Mechanics ; Coating ; Coatings ; Crystallography and Scattering Methods ; Material chemistry ; Materials Science ; Mechanical properties ; Microscopy ; Nanocrystals ; Original Paper ; Polyethylene glycol ; Polymer Sciences ; Polymers ; Polyols ; Scanning electron microscopy ; Solid Mechanics ; Substrates ; Transmission electron microscopy</subject><ispartof>Journal of materials science, 2017-03, Vol.52 (6), p.3048-3061</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>COPYRIGHT 2017 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2016). All Rights Reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c423t-1ef0579b4f895e8f9f9cdd674035ad0866522219f5861df1d46554f34fefc9753</citedby><cites>FETCH-LOGICAL-c423t-1ef0579b4f895e8f9f9cdd674035ad0866522219f5861df1d46554f34fefc9753</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-016-0589-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-016-0589-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03326830$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Gicquel, Erwan</creatorcontrib><creatorcontrib>Martin, Céline</creatorcontrib><creatorcontrib>Garrido Yanez, José</creatorcontrib><creatorcontrib>Bras, Julien</creatorcontrib><title>Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>In this work, we explored the elaboration of new smart paper by coating fiber-based materials with CNC for possible use in packaging. Particularly, we investigated application of a 100% CNC layer onto a substrate. Mainly due to the cost and limited availability of CNC on a large scale, few studies have examined these opportunities. Several layers of CNC were deposited onto a paper material using the bar-coating process to improve relevant properties of the paper surface. Surface analyses (atomic force microscopy, scanning electron microscopy, and transmission electron microscopy) were performed to elucidate the CNC network at the paper surface. Structural and mechanical properties of the final materials were evaluated. Results of general interest were obtained about barrier properties. The air barrier and grease resistance improve only with the paper coated with CNC. To complete this research, a small amount of polyethylene glycol was added to reinforce the brittle CNC coating and clearly enhance barrier properties of the paper.</description><subject>Analysis</subject><subject>Atomic force microscopy</subject><subject>Cellulose</subject><subject>Cellulose fibers</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical engineering</subject><subject>Chemical Sciences</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Coating</subject><subject>Coatings</subject><subject>Crystallography and Scattering Methods</subject><subject>Material chemistry</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>Microscopy</subject><subject>Nanocrystals</subject><subject>Original Paper</subject><subject>Polyethylene glycol</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Polyols</subject><subject>Scanning electron microscopy</subject><subject>Solid Mechanics</subject><subject>Substrates</subject><subject>Transmission electron microscopy</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kc1qGzEYRYfSQt0kD5CdoKsulOp_NEtj2iZgCLTpWmg0nxyFseRI49R--8qMaegiaCG4nCsduE1zTckNJaT9WijRkmNCFSZSd_jwrllQ2XIsNOHvmwUhjGEmFP3YfCrliRAiW0YXzfMKxnE_pgIo2phcPpbJjgXZgiL8QX1IuLcFBuSSnULcoNEeISOfMgrbXU4vp8yHHvKZ24J7tDE4OyIbB9TbnEMtVHQHeQpQLpsPvv4AV-f7ovn9_dvD6hav73_crZZr7ATjE6bgq2LXC687Cdp3vnPDoFpBuLQD0UpJxhjtvNSKDp4OQkkpPBcevOtayS-aL_O7j3Y0uxy2Nh9NssHcLtfmlBHOmdKcvNDKfp7Zqvm8hzKZp7TPseoZxmSnuFCtrtTNTG3sCCZEn6ZsXT0DbINLEXyo-VK0gipGJXtVOBcqM8Fh2th9Kebu18__WTqzLqdSMvh_zpSY08RmntjUic1pYnOoHTZ3SmXjBvKr9tulv3eoqK8</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Gicquel, Erwan</creator><creator>Martin, Céline</creator><creator>Garrido Yanez, José</creator><creator>Bras, Julien</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><general>Springer Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>1XC</scope></search><sort><creationdate>20170301</creationdate><title>Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties</title><author>Gicquel, Erwan ; Martin, Céline ; Garrido Yanez, José ; Bras, Julien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c423t-1ef0579b4f895e8f9f9cdd674035ad0866522219f5861df1d46554f34fefc9753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Analysis</topic><topic>Atomic force microscopy</topic><topic>Cellulose</topic><topic>Cellulose fibers</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical engineering</topic><topic>Chemical Sciences</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Coating</topic><topic>Coatings</topic><topic>Crystallography and Scattering Methods</topic><topic>Material chemistry</topic><topic>Materials Science</topic><topic>Mechanical properties</topic><topic>Microscopy</topic><topic>Nanocrystals</topic><topic>Original Paper</topic><topic>Polyethylene glycol</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Polyols</topic><topic>Scanning electron microscopy</topic><topic>Solid Mechanics</topic><topic>Substrates</topic><topic>Transmission electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gicquel, Erwan</creatorcontrib><creatorcontrib>Martin, Céline</creatorcontrib><creatorcontrib>Garrido Yanez, José</creatorcontrib><creatorcontrib>Bras, Julien</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gicquel, Erwan</au><au>Martin, Céline</au><au>Garrido Yanez, José</au><au>Bras, Julien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>52</volume><issue>6</issue><spage>3048</spage><epage>3061</epage><pages>3048-3061</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>In this work, we explored the elaboration of new smart paper by coating fiber-based materials with CNC for possible use in packaging. Particularly, we investigated application of a 100% CNC layer onto a substrate. Mainly due to the cost and limited availability of CNC on a large scale, few studies have examined these opportunities. Several layers of CNC were deposited onto a paper material using the bar-coating process to improve relevant properties of the paper surface. Surface analyses (atomic force microscopy, scanning electron microscopy, and transmission electron microscopy) were performed to elucidate the CNC network at the paper surface. Structural and mechanical properties of the final materials were evaluated. Results of general interest were obtained about barrier properties. The air barrier and grease resistance improve only with the paper coated with CNC. To complete this research, a small amount of polyethylene glycol was added to reinforce the brittle CNC coating and clearly enhance barrier properties of the paper.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-016-0589-x</doi><tpages>14</tpages></addata></record> |
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subjects | Analysis Atomic force microscopy Cellulose Cellulose fibers Characterization and Evaluation of Materials Chemical engineering Chemical Sciences Chemistry and Materials Science Classical Mechanics Coating Coatings Crystallography and Scattering Methods Material chemistry Materials Science Mechanical properties Microscopy Nanocrystals Original Paper Polyethylene glycol Polymer Sciences Polymers Polyols Scanning electron microscopy Solid Mechanics Substrates Transmission electron microscopy |
title | Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties |
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