Comparison of internal energy distributions generated by supercritical fluid chromatography versus liquid chromatography hyphenated with electrospray high resolution mass spectrometry

•Influence of chromatographic parameters on the internal energy distribution.•MS instrumental parameters were studied in parallel for SFC and LC.•SFC-ESI-MS led to higher internal energies for thermometer ions than LC-ESI-MS. The internal energy distributions of thermometer ions dissolved in supercr...

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