Deciphering Competitive Routes for Nickel‐Based Nanoparticle Electrodeposition by an Operando Optical Monitoring
Electrodeposition of earth‐abundant iron group metals such as nickel is difficult to characterize by simple electrochemical analyses since the reduction of their metal salts often competes with inhibiting reactions. This makes the mechanistic interpretation sometimes contradictory, preventing unambi...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2021-07, Vol.60 (31), p.16980-16983 |
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| creator | Godeffroy, Louis Ciocci, Paolo Nsabimana, Anaclet Miranda Vieira, Mathias Noël, Jean‐Marc Combellas, Catherine Lemineur, Jean‐François Kanoufi, Frédéric |
| description | Electrodeposition of earth‐abundant iron group metals such as nickel is difficult to characterize by simple electrochemical analyses since the reduction of their metal salts often competes with inhibiting reactions. This makes the mechanistic interpretation sometimes contradictory, preventing unambiguous predictions about the nature and structure of the electrodeposited material. Herein, the complexity of Ni nanoparticles (NPs) electrodeposition on indium tin oxide (ITO) is unraveled operando and at a single entity NP level by optical microscopy correlated to ex situ SEM imaging. Our correlative approach allows differentiating the dynamics of formation of two different NP populations, metallic Ni and Ni(OH)2 with a |
| doi_str_mv | 10.1002/anie.202106420 |
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The results of electrodeposition can be challenging to predict in the absence of unambiguous electrochemical signature. Operando optical microscopy correlated to ex situ SEM imaging allows probing mechanistic diversity with single nanoparticle resolution. It is illustrated by differentiating, with sub‐25 nm size limit of detection, the electrodeposition of Ni and Ni(OH)2 NPs upon Ni2+ reduction.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202106420</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Analytical chemistry ; Chemical Sciences ; Electrochemistry ; Electrodeposition ; Heavy metals ; Indium tin oxides ; Light microscopy ; Material chemistry ; Nanoparticles ; Nickel ; Optical microscopy ; Reduction (metal working) ; Salts ; single nanoparticle ; Tin</subject><ispartof>Angewandte Chemie International Edition, 2021-07, Vol.60 (31), p.16980-16983</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4240-2705a57576a42de8b84cc233df675332094ea5145dab3dd14b35750b1b39b0443</citedby><cites>FETCH-LOGICAL-c4240-2705a57576a42de8b84cc233df675332094ea5145dab3dd14b35750b1b39b0443</cites><orcidid>0000-0002-8394-4650 ; 0000-0002-9784-2380 ; 0000-0002-5276-1624 ; 0000-0001-8278-7748</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202106420$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202106420$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1416,27915,27916,45565,45566</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03287771$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Godeffroy, Louis</creatorcontrib><creatorcontrib>Ciocci, Paolo</creatorcontrib><creatorcontrib>Nsabimana, Anaclet</creatorcontrib><creatorcontrib>Miranda Vieira, Mathias</creatorcontrib><creatorcontrib>Noël, Jean‐Marc</creatorcontrib><creatorcontrib>Combellas, Catherine</creatorcontrib><creatorcontrib>Lemineur, Jean‐François</creatorcontrib><creatorcontrib>Kanoufi, Frédéric</creatorcontrib><title>Deciphering Competitive Routes for Nickel‐Based Nanoparticle Electrodeposition by an Operando Optical Monitoring</title><title>Angewandte Chemie International Edition</title><description>Electrodeposition of earth‐abundant iron group metals such as nickel is difficult to characterize by simple electrochemical analyses since the reduction of their metal salts often competes with inhibiting reactions. This makes the mechanistic interpretation sometimes contradictory, preventing unambiguous predictions about the nature and structure of the electrodeposited material. Herein, the complexity of Ni nanoparticles (NPs) electrodeposition on indium tin oxide (ITO) is unraveled operando and at a single entity NP level by optical microscopy correlated to ex situ SEM imaging. Our correlative approach allows differentiating the dynamics of formation of two different NP populations, metallic Ni and Ni(OH)2 with a <25 nm limit of detection, their formation being ruled by the competition between Ni2+ and water reduction. At the single NP level this results in a self‐terminated growth, an information which is most often hidden in ensemble averaged measurements.
The results of electrodeposition can be challenging to predict in the absence of unambiguous electrochemical signature. Operando optical microscopy correlated to ex situ SEM imaging allows probing mechanistic diversity with single nanoparticle resolution. It is illustrated by differentiating, with sub‐25 nm size limit of detection, the electrodeposition of Ni and Ni(OH)2 NPs upon Ni2+ reduction.</description><subject>Analytical chemistry</subject><subject>Chemical Sciences</subject><subject>Electrochemistry</subject><subject>Electrodeposition</subject><subject>Heavy metals</subject><subject>Indium tin oxides</subject><subject>Light microscopy</subject><subject>Material chemistry</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Optical microscopy</subject><subject>Reduction (metal working)</subject><subject>Salts</subject><subject>single nanoparticle</subject><subject>Tin</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqF0c1OGzEQB_BVRaVC6LVnS73AYYM_17vHkKaAFBKpas-W1zsppo692JtUufUReMY-CY6CQOLCySPr97fHnqL4QvCYYEwvtLcwppgSXHGKPxTHRFBSMinZUa45Y6WsBflUnKR0n31d4-q4iN_A2P4OovW_0TSsexjsYLeAfoTNAAmtQkQLa_6A-__v8VIn6NBC-9DrOFjjAM0cmCGGDvqQcjB41O6Q9mjZQ9S-C7nIUDt0G7wdwv6a0-LjSrsEn5_XUfHr--zn9LqcL69uppN5aTjluKQSCy2kkJXmtIO6rbkxlLFuVUnBGMUNBy0IF51uWdcR3rKscUta1rSYczYqzg_n3mmn-mjXOu5U0FZdT-Zqv4cZraWUZEuyPTvYPoaHDaRBrW0y4Jz2EDZJUcGa_LFNLTL9-obeh030-SVZCVrnviqZ1figTAwpRVi9dECw2o9L7celXsaVA80h8Nc62L2j1WRxM3vNPgH2oplc</recordid><startdate>20210726</startdate><enddate>20210726</enddate><creator>Godeffroy, Louis</creator><creator>Ciocci, Paolo</creator><creator>Nsabimana, Anaclet</creator><creator>Miranda Vieira, Mathias</creator><creator>Noël, Jean‐Marc</creator><creator>Combellas, Catherine</creator><creator>Lemineur, Jean‐François</creator><creator>Kanoufi, Frédéric</creator><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-8394-4650</orcidid><orcidid>https://orcid.org/0000-0002-9784-2380</orcidid><orcidid>https://orcid.org/0000-0002-5276-1624</orcidid><orcidid>https://orcid.org/0000-0001-8278-7748</orcidid></search><sort><creationdate>20210726</creationdate><title>Deciphering Competitive Routes for Nickel‐Based Nanoparticle Electrodeposition by an Operando Optical Monitoring</title><author>Godeffroy, Louis ; Ciocci, Paolo ; Nsabimana, Anaclet ; Miranda Vieira, Mathias ; Noël, Jean‐Marc ; Combellas, Catherine ; Lemineur, Jean‐François ; Kanoufi, Frédéric</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4240-2705a57576a42de8b84cc233df675332094ea5145dab3dd14b35750b1b39b0443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical chemistry</topic><topic>Chemical Sciences</topic><topic>Electrochemistry</topic><topic>Electrodeposition</topic><topic>Heavy metals</topic><topic>Indium tin oxides</topic><topic>Light microscopy</topic><topic>Material chemistry</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Optical microscopy</topic><topic>Reduction (metal working)</topic><topic>Salts</topic><topic>single nanoparticle</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Godeffroy, Louis</creatorcontrib><creatorcontrib>Ciocci, Paolo</creatorcontrib><creatorcontrib>Nsabimana, Anaclet</creatorcontrib><creatorcontrib>Miranda Vieira, Mathias</creatorcontrib><creatorcontrib>Noël, Jean‐Marc</creatorcontrib><creatorcontrib>Combellas, Catherine</creatorcontrib><creatorcontrib>Lemineur, Jean‐François</creatorcontrib><creatorcontrib>Kanoufi, Frédéric</creatorcontrib><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Godeffroy, Louis</au><au>Ciocci, Paolo</au><au>Nsabimana, Anaclet</au><au>Miranda Vieira, Mathias</au><au>Noël, Jean‐Marc</au><au>Combellas, Catherine</au><au>Lemineur, Jean‐François</au><au>Kanoufi, Frédéric</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Deciphering Competitive Routes for Nickel‐Based Nanoparticle Electrodeposition by an Operando Optical Monitoring</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2021-07-26</date><risdate>2021</risdate><volume>60</volume><issue>31</issue><spage>16980</spage><epage>16983</epage><pages>16980-16983</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Electrodeposition of earth‐abundant iron group metals such as nickel is difficult to characterize by simple electrochemical analyses since the reduction of their metal salts often competes with inhibiting reactions. This makes the mechanistic interpretation sometimes contradictory, preventing unambiguous predictions about the nature and structure of the electrodeposited material. Herein, the complexity of Ni nanoparticles (NPs) electrodeposition on indium tin oxide (ITO) is unraveled operando and at a single entity NP level by optical microscopy correlated to ex situ SEM imaging. Our correlative approach allows differentiating the dynamics of formation of two different NP populations, metallic Ni and Ni(OH)2 with a <25 nm limit of detection, their formation being ruled by the competition between Ni2+ and water reduction. At the single NP level this results in a self‐terminated growth, an information which is most often hidden in ensemble averaged measurements.
The results of electrodeposition can be challenging to predict in the absence of unambiguous electrochemical signature. Operando optical microscopy correlated to ex situ SEM imaging allows probing mechanistic diversity with single nanoparticle resolution. It is illustrated by differentiating, with sub‐25 nm size limit of detection, the electrodeposition of Ni and Ni(OH)2 NPs upon Ni2+ reduction.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.202106420</doi><tpages>4</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-8394-4650</orcidid><orcidid>https://orcid.org/0000-0002-9784-2380</orcidid><orcidid>https://orcid.org/0000-0002-5276-1624</orcidid><orcidid>https://orcid.org/0000-0001-8278-7748</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Analytical chemistry Chemical Sciences Electrochemistry Electrodeposition Heavy metals Indium tin oxides Light microscopy Material chemistry Nanoparticles Nickel Optical microscopy Reduction (metal working) Salts single nanoparticle Tin |
| title | Deciphering Competitive Routes for Nickel‐Based Nanoparticle Electrodeposition by an Operando Optical Monitoring |
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