Synthesis, Characterization, and Electrochemical Study of Tetradentate Ruthenium-Schiff Base Complexes: Dioxygen Activation with a Cytochrome P450 Model Using 1- or 2-Methylimidazole as Axial Bases

Salicylaldehyde, 2-hydroxyacetophenone, and 3,5-dichlorosalicylaldehyde react with 1,2-diaminoethane to give three symmetrical Schiff bases H2L1, H2L2, and H2L3, respectively. With Ru(III) ions, these ligands lead to three complexes: Ru(III)ClL1 (1), Ru(III)ClL2 (2), and Ru(III)ClL3 (3). The purity...

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Veröffentlicht in:	Advances in Physical Chemistry 2011-01, Vol.2011 (2011), p.4-14
Hauptverfasser:	Bouet, Gilles, Khelafi, Mostefa, Aggoun, Djouhra, Khan, Mustayeen Ahmad, Ourari, Ali
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences
Online-Zugang:	Volltext
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