A Model for Double Asymmetric Induction in the Stereocontrolled Reduction of Glycosyl α-Ketoesters with Oxazaborolidines

Experimental diastereoselectivities for the stereocontrolled reduction of glycosyl α-ketoesters into the corresponding α-hydroxyesters have recently been reported with unexpected results. The process is catalyzed by a chiral oxazaborolidine derivative (the so-called CBS catalyst) and represents the...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-06, Vol.126 (22), p.6996-7008
Hauptverfasser:	Harb, W, Ruiz-López, M. F, Coutrot, F, Grison, C, Coutrot, P
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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