Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid
The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3...
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Veröffentlicht in: | Journal of applied polymer science 2007-07, Vol.105 (1), p.278-281 |
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creator | Maria, Sebastien Biedroń, Tadeusz Poli, Rinaldo Kubisa, Przemysaw |
description | The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007 |
doi_str_mv | 10.1002/app.26046 |
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A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.26046</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; atom transfer radical polymerization (ATRP) ; Catalysis ; catalysts ; Chemical Sciences ; Coordination chemistry ; Exact sciences and technology ; ionic liquids ; MALDI ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of applied polymer science, 2007-07, Vol.105 (1), p.278-281</ispartof><rights>Copyright © 2007 Wiley Periodicals, Inc.</rights><rights>2008 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</citedby><cites>FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</cites><orcidid>0000-0002-5220-2515</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.26046$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.26046$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18754019$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-03194553$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Maria, Sebastien</creatorcontrib><creatorcontrib>Biedroń, Tadeusz</creatorcontrib><creatorcontrib>Poli, Rinaldo</creatorcontrib><creatorcontrib>Kubisa, Przemysaw</creatorcontrib><title>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007</description><subject>Applied sciences</subject><subject>atom transfer radical polymerization (ATRP)</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>Chemical Sciences</subject><subject>Coordination chemistry</subject><subject>Exact sciences and technology</subject><subject>ionic liquids</subject><subject>MALDI</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp1kMtuFDEQRVuISAwhC_7AG5BYdGK3H20vhxFMkEaQRaIsrWq3rTG4H7E9hObrcZiQrFhZKp97VHWr6i3B5wTj5gLm-bwRmIkX1Ypg1dZMNPJltSp_pJZK8VfV65S-Y0wIx2JVTes8DShHGJOzEUXovYGA5iksg43-N2Q_jWhyaLB5vwQEJi4BskX3Pu_RULCut-NhQHsIvrcJQUIGMoQl5YT8iGBExeANCv7u4Ps31YmDkOzZ43ta3Xz-dL25rHfftl82611tGG1F7awi0nRKUcEd7xrGOi55y7lrMTe45Y3qsWCyg67c1xOielfukY47iwtDT6sPR2_ZS8_RDxAXPYHXl-udfphhShTjnP4khX1_ZOc43R1synrwydgQYLTTIelGKSYwZc9SE6eUonVPZoL1Q_261K__1l_Yd49SSKVRVxo2Pj0HZMsZJqpwF0fu3ge7_F-o11dX_8z1MeFTtr-eEhB_aNHSluvbr1u93WykvKVMf6R_AHm6otc</recordid><startdate>20070705</startdate><enddate>20070705</enddate><creator>Maria, Sebastien</creator><creator>Biedroń, Tadeusz</creator><creator>Poli, Rinaldo</creator><creator>Kubisa, Przemysaw</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-5220-2515</orcidid></search><sort><creationdate>20070705</creationdate><title>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</title><author>Maria, Sebastien ; Biedroń, Tadeusz ; Poli, Rinaldo ; Kubisa, Przemysaw</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>atom transfer radical polymerization (ATRP)</topic><topic>Catalysis</topic><topic>catalysts</topic><topic>Chemical Sciences</topic><topic>Coordination chemistry</topic><topic>Exact sciences and technology</topic><topic>ionic liquids</topic><topic>MALDI</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maria, Sebastien</creatorcontrib><creatorcontrib>Biedroń, Tadeusz</creatorcontrib><creatorcontrib>Poli, Rinaldo</creatorcontrib><creatorcontrib>Kubisa, Przemysaw</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maria, Sebastien</au><au>Biedroń, Tadeusz</au><au>Poli, Rinaldo</au><au>Kubisa, Przemysaw</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2007-07-05</date><risdate>2007</risdate><volume>105</volume><issue>1</issue><spage>278</spage><epage>281</epage><pages>278-281</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.26046</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5220-2515</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Applied sciences atom transfer radical polymerization (ATRP) Catalysis catalysts Chemical Sciences Coordination chemistry Exact sciences and technology ionic liquids MALDI Organic polymers Physicochemistry of polymers Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
title | Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid |
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