Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid

The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied polymer science 2007-07, Vol.105 (1), p.278-281
Hauptverfasser: Maria, Sebastien, Biedroń, Tadeusz, Poli, Rinaldo, Kubisa, Przemysaw
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 281
container_issue 1
container_start_page 278
container_title Journal of applied polymer science
container_volume 105
creator Maria, Sebastien
Biedroń, Tadeusz
Poli, Rinaldo
Kubisa, Przemysaw
description The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007
doi_str_mv 10.1002/app.26046
format Article
fullrecord <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_03194553v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29946034</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</originalsourceid><addsrcrecordid>eNp1kMtuFDEQRVuISAwhC_7AG5BYdGK3H20vhxFMkEaQRaIsrWq3rTG4H7E9hObrcZiQrFhZKp97VHWr6i3B5wTj5gLm-bwRmIkX1Ypg1dZMNPJltSp_pJZK8VfV65S-Y0wIx2JVTes8DShHGJOzEUXovYGA5iksg43-N2Q_jWhyaLB5vwQEJi4BskX3Pu_RULCut-NhQHsIvrcJQUIGMoQl5YT8iGBExeANCv7u4Ps31YmDkOzZ43ta3Xz-dL25rHfftl82611tGG1F7awi0nRKUcEd7xrGOi55y7lrMTe45Y3qsWCyg67c1xOielfukY47iwtDT6sPR2_ZS8_RDxAXPYHXl-udfphhShTjnP4khX1_ZOc43R1synrwydgQYLTTIelGKSYwZc9SE6eUonVPZoL1Q_261K__1l_Yd49SSKVRVxo2Pj0HZMsZJqpwF0fu3ge7_F-o11dX_8z1MeFTtr-eEhB_aNHSluvbr1u93WykvKVMf6R_AHm6otc</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>29946034</pqid></control><display><type>article</type><title>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</title><source>Access via Wiley Online Library</source><creator>Maria, Sebastien ; Biedroń, Tadeusz ; Poli, Rinaldo ; Kubisa, Przemysaw</creator><creatorcontrib>Maria, Sebastien ; Biedroń, Tadeusz ; Poli, Rinaldo ; Kubisa, Przemysaw</creatorcontrib><description>The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.26046</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; atom transfer radical polymerization (ATRP) ; Catalysis ; catalysts ; Chemical Sciences ; Coordination chemistry ; Exact sciences and technology ; ionic liquids ; MALDI ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of applied polymer science, 2007-07, Vol.105 (1), p.278-281</ispartof><rights>Copyright © 2007 Wiley Periodicals, Inc.</rights><rights>2008 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</citedby><cites>FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</cites><orcidid>0000-0002-5220-2515</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.26046$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.26046$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=18754019$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-03194553$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Maria, Sebastien</creatorcontrib><creatorcontrib>Biedroń, Tadeusz</creatorcontrib><creatorcontrib>Poli, Rinaldo</creatorcontrib><creatorcontrib>Kubisa, Przemysaw</creatorcontrib><title>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007</description><subject>Applied sciences</subject><subject>atom transfer radical polymerization (ATRP)</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>Chemical Sciences</subject><subject>Coordination chemistry</subject><subject>Exact sciences and technology</subject><subject>ionic liquids</subject><subject>MALDI</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp1kMtuFDEQRVuISAwhC_7AG5BYdGK3H20vhxFMkEaQRaIsrWq3rTG4H7E9hObrcZiQrFhZKp97VHWr6i3B5wTj5gLm-bwRmIkX1Ypg1dZMNPJltSp_pJZK8VfV65S-Y0wIx2JVTes8DShHGJOzEUXovYGA5iksg43-N2Q_jWhyaLB5vwQEJi4BskX3Pu_RULCut-NhQHsIvrcJQUIGMoQl5YT8iGBExeANCv7u4Ps31YmDkOzZ43ta3Xz-dL25rHfftl82611tGG1F7awi0nRKUcEd7xrGOi55y7lrMTe45Y3qsWCyg67c1xOielfukY47iwtDT6sPR2_ZS8_RDxAXPYHXl-udfphhShTjnP4khX1_ZOc43R1synrwydgQYLTTIelGKSYwZc9SE6eUonVPZoL1Q_261K__1l_Yd49SSKVRVxo2Pj0HZMsZJqpwF0fu3ge7_F-o11dX_8z1MeFTtr-eEhB_aNHSluvbr1u93WykvKVMf6R_AHm6otc</recordid><startdate>20070705</startdate><enddate>20070705</enddate><creator>Maria, Sebastien</creator><creator>Biedroń, Tadeusz</creator><creator>Poli, Rinaldo</creator><creator>Kubisa, Przemysaw</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-5220-2515</orcidid></search><sort><creationdate>20070705</creationdate><title>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</title><author>Maria, Sebastien ; Biedroń, Tadeusz ; Poli, Rinaldo ; Kubisa, Przemysaw</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4376-fe918cb99365f5b244b585755f705c07529d0648bab628d119df5068f5fe0f703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>atom transfer radical polymerization (ATRP)</topic><topic>Catalysis</topic><topic>catalysts</topic><topic>Chemical Sciences</topic><topic>Coordination chemistry</topic><topic>Exact sciences and technology</topic><topic>ionic liquids</topic><topic>MALDI</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maria, Sebastien</creatorcontrib><creatorcontrib>Biedroń, Tadeusz</creatorcontrib><creatorcontrib>Poli, Rinaldo</creatorcontrib><creatorcontrib>Kubisa, Przemysaw</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maria, Sebastien</au><au>Biedroń, Tadeusz</au><au>Poli, Rinaldo</au><au>Kubisa, Przemysaw</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2007-07-05</date><risdate>2007</risdate><volume>105</volume><issue>1</issue><spage>278</spage><epage>281</epage><pages>278-281</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The atom transfer radical polymerization of methyl acrylate in 1‐butyl‐3‐methylimidazolium hexafluorophosphate was studied with a molybdenum halide catalytic system. A combination of a bromine‐containing initiator (ethyl‐2‐bromopropionate) with a chloride‐containing catalyst [MoCl3(PMe3)3/MoCl4(PMe3)3] led to a controlled polymerization, and matrix‐assisted laser desorption/ionization time‐of‐flight analysis of the polymers indicated that the reversibly deactivated macromolecules contained both bromine and chloride end groups. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 278–281, 2007</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.26046</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5220-2515</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0021-8995
ispartof Journal of applied polymer science, 2007-07, Vol.105 (1), p.278-281
issn 0021-8995
1097-4628
language eng
recordid cdi_hal_primary_oai_HAL_hal_03194553v1
source Access via Wiley Online Library
subjects Applied sciences
atom transfer radical polymerization (ATRP)
Catalysis
catalysts
Chemical Sciences
Coordination chemistry
Exact sciences and technology
ionic liquids
MALDI
Organic polymers
Physicochemistry of polymers
Polymerization
Polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Atom transfer radical polymerization of methyl acrylate with molybdenum halides as catalysts in an ionic liquid
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T17%3A21%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Atom%20transfer%20radical%20polymerization%20of%20methyl%20acrylate%20with%20molybdenum%20halides%20as%20catalysts%20in%20an%20ionic%20liquid&rft.jtitle=Journal%20of%20applied%20polymer%20science&rft.au=Maria,%20Sebastien&rft.date=2007-07-05&rft.volume=105&rft.issue=1&rft.spage=278&rft.epage=281&rft.pages=278-281&rft.issn=0021-8995&rft.eissn=1097-4628&rft.coden=JAPNAB&rft_id=info:doi/10.1002/app.26046&rft_dat=%3Cproquest_hal_p%3E29946034%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=29946034&rft_id=info:pmid/&rfr_iscdi=true