High mass and spatial resolution mass spectrometry imaging of Nicolas Poussin painting cross section by cluster TOF-SIMS

Time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) imaging using cluster primary ion beams is used for the identification of the pigments in the painting of Rebecca and Eliezer at the Well by Nicolas Poussin. The combination of the high mass resolution of the technique with a sub‐micrometer s...

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Veröffentlicht in:Journal of mass spectrometry. 2016-12, Vol.51 (12), p.1196-1210
Hauptverfasser: Noun, Manale, Van Elslande, Elsa, Touboul, David, Glanville, Helen, Bucklow, Spike, Walter, Philippe, Brunelle, Alain
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container_end_page 1210
container_issue 12
container_start_page 1196
container_title Journal of mass spectrometry.
container_volume 51
creator Noun, Manale
Van Elslande, Elsa
Touboul, David
Glanville, Helen
Bucklow, Spike
Walter, Philippe
Brunelle, Alain
description Time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) imaging using cluster primary ion beams is used for the identification of the pigments in the painting of Rebecca and Eliezer at the Well by Nicolas Poussin. The combination of the high mass resolution of the technique with a sub‐micrometer spatial resolution offered by a delayed extraction of the secondary ions, together with the possibility to simultaneously identifying both minerals and organics, has proved to be the method of choice for the study of the stratigraphy of a paint cross section. The chemical compositions of small grains are shown with the help of a thorough processing of the data, with images of specific ions, mass spectra extracted from small regions of interest, and profiles drawn along the different painting layers. Copyright © 2016 John Wiley & Sons, Ltd.
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source Wiley Online Library Journals Frontfile Complete
subjects Analytical chemistry
Chemical Sciences
Clusters
Cross sections
cultural heritage
Imaging
Mass spectrometry
Mass spectroscopy
Nicolas Poussin
organic matters (oils and proteins)
pigments
Spatial resolution
Stratigraphy
TOF-SIMS imaging
title High mass and spatial resolution mass spectrometry imaging of Nicolas Poussin painting cross section by cluster TOF-SIMS
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