Biosourced lauroyl poly(glycerol-succinate) oligoesters modified by copolymerizable solvents: A wasteless and eco-friendly surfactants properties enhancement

Biosourced lauroyl poly(glycerol-succinate) oligoesters modified by copolymerizable solvents: A wasteless and eco-friendly surfactants properties enhancement

Biosourced oligomeric surfactants have been synthesized and characterized as potential alternatives to petrobased surfactants. The polar head was a branched oligoester while the hydrophobic part derived from fatty acid or fatty α-monoglyceride ester. Besides the glycerol (G) and succinic acid (S) un...

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Veröffentlicht in:Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2018-01, Vol.536, p.88-95
Hauptverfasser: Agach, Mickaël, Marinkovic, Sinisa, Estrine, Boris, Nardello-Rataj, Véronique
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Organic chemistry
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container_start_page 88
container_title Colloids and surfaces. A, Physicochemical and engineering aspects
container_volume 536
creator Agach, Mickaël
Marinkovic, Sinisa
Estrine, Boris
Nardello-Rataj, Véronique
description Biosourced oligomeric surfactants have been synthesized and characterized as potential alternatives to petrobased surfactants. The polar head was a branched oligoester while the hydrophobic part derived from fatty acid or fatty α-monoglyceride ester. Besides the glycerol (G) and succinic acid (S) units, the hydrophilic oligoesters were modified by a third comonomer (X) which was introduced as a copolymerizable solvent in order to improve its grafting with the alkyl chain and facilitate the processability. The investigated comonomers were lactic acid, ethylene glycol, propylene glycol, 1,3-propanediol and 1,4-butanediol. Modified lauroyl oligoesters, C12PGSX, with controllable sizes were thus obtained by polycondensation reactions. They were characterized by their acid values, gas chromatography and size exclusion chromatography. Their surface activity, foamability, wetting power, solubilizing capacity and biodegradation were investigated highlighting the interest of these biosourced surfactants in a wide set of applications.
doi_str_mv 10.1016/j.colsurfa.2017.07.033
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Organic chemistry
title Biosourced lauroyl poly(glycerol-succinate) oligoesters modified by copolymerizable solvents: A wasteless and eco-friendly surfactants properties enhancement
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