Solid State Chemistry of Ten-Fold Coordinate Thorium(IV) Complexes with Oxalates in the Presence of Ammonium and Hydrazinium Ions

Double and triple thorium oxalates have been synthesized by successive evaporation of a solution of thorium nitrate, ammonium, or hydrazinium oxalate and hydrogen peroxide. Compounds M6Ca2Th2(C2O4)9­·nH2O (M = NH4 +, N2H5 +) (1) were first accidentally obtained due to the unexpected presence of calc...

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Veröffentlicht in:	Crystal growth & design 2018-08, Vol.18 (8), p.4593-4601
Hauptverfasser:	Blanchard, Florent, Rivenet, Murielle, Vigier, Nicolas, Hablot, Isabelle, Grandjean, Stéphane, Abraham, Francis
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Material chemistry
Online-Zugang:	Volltext
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