Polymerization of norbornene with Co(II) complexes
The norbornene polymerization was studied in the presence of 6 pyridine bis(imine) cobalt(II) complexes activated with methylaluminoxane (MAO). Norbornene was also polymerized with CoCl2 associated to MAO. All these catalytic systems generate an addition polymerization of norbornene, yielding fully...
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| Veröffentlicht in: | Macromolecular symposia. 2004-06, Vol.213 (1), p.265-274 |
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| container_title | Macromolecular symposia. |
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| creator | Pelascini, Frédéric Peruch, Frédéric Lutz, Pierre Joseph Wesolek, Marcel Kress, Jacky |
| description | The norbornene polymerization was studied in the presence of 6 pyridine bis(imine) cobalt(II) complexes activated with methylaluminoxane (MAO). Norbornene was also polymerized with CoCl2 associated to MAO. All these catalytic systems generate an addition polymerization of norbornene, yielding fully saturated polymers. It was shown that the polymerization yield and the molar masses are highly dependant on several reaction parameters (monomer concentration, [Al]/[Co] ratio, polymerization temperature and time) and the frame of the ligand. |
| doi_str_mv | 10.1002/masy.200450924 |
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Norbornene was also polymerized with CoCl2 associated to MAO. All these catalytic systems generate an addition polymerization of norbornene, yielding fully saturated polymers. It was shown that the polymerization yield and the molar masses are highly dependant on several reaction parameters (monomer concentration, [Al]/[Co] ratio, polymerization temperature and time) and the frame of the ligand.</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/masy.200450924</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>addition polymerization ; Aluminum ; Catalysis ; catalysts ; Chemical Sciences ; cobalt ; Frames ; Ligands ; Monomers ; norbornene ; Polymerization ; Polymers ; pyridine bis(imine) ; Pyridines</subject><ispartof>Macromolecular symposia., 2004-06, Vol.213 (1), p.265-274</ispartof><rights>Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. 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It was shown that the polymerization yield and the molar masses are highly dependant on several reaction parameters (monomer concentration, [Al]/[Co] ratio, polymerization temperature and time) and the frame of the ligand.</description><subject>addition polymerization</subject><subject>Aluminum</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>Chemical Sciences</subject><subject>cobalt</subject><subject>Frames</subject><subject>Ligands</subject><subject>Monomers</subject><subject>norbornene</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>pyridine bis(imine)</subject><subject>Pyridines</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPwkAUhRujiYhuXXcJi-KdV6ezRFQg4iM-grqZTNtpqLYdnCkC_nohNcSdq3ty831ncTzvFEEPAeCzUrl1DwNQBgLTPa-FGEYBEQD7mwwYB4iEcOgdOfcOAEJw1PLwvSnWpbb5t6pzU_km8ytjY2MrXWl_mdczf2A643HXT0w5L_RKu2PvIFOF0ye_t-09X10-DUbB5G44HvQnQUIJpgGJUMZjEoVcEc0iSCMBEVU0VpwLrHiCUqriNMtCpKIszmLCU6IgpgxHWFBG2l636Z2pQs5tXiq7lkblctSfyO0PCKJUCPaFNmynYefWfC60q2WZu0QXhaq0WTiJcBhyyjjDG7TXoIk1zlmd7boRyO2Qcjuk3A25EUQjLPNCr_-h5U3_8fWvGzRu7mq92rnKfsiQE87k9HYoL96up-f3Lw-Skx8uCITX</recordid><startdate>200406</startdate><enddate>200406</enddate><creator>Pelascini, Frédéric</creator><creator>Peruch, Frédéric</creator><creator>Lutz, Pierre Joseph</creator><creator>Wesolek, Marcel</creator><creator>Kress, Jacky</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-1891-5877</orcidid></search><sort><creationdate>200406</creationdate><title>Polymerization of norbornene with Co(II) complexes</title><author>Pelascini, Frédéric ; Peruch, Frédéric ; Lutz, Pierre Joseph ; Wesolek, Marcel ; Kress, Jacky</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4324-381f7b3867a3e580d89084a4ba7792a7c1d4abdff61a8fbfb37d3a0b452829453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>addition polymerization</topic><topic>Aluminum</topic><topic>Catalysis</topic><topic>catalysts</topic><topic>Chemical Sciences</topic><topic>cobalt</topic><topic>Frames</topic><topic>Ligands</topic><topic>Monomers</topic><topic>norbornene</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>pyridine bis(imine)</topic><topic>Pyridines</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pelascini, Frédéric</creatorcontrib><creatorcontrib>Peruch, Frédéric</creatorcontrib><creatorcontrib>Lutz, Pierre Joseph</creatorcontrib><creatorcontrib>Wesolek, Marcel</creatorcontrib><creatorcontrib>Kress, Jacky</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pelascini, Frédéric</au><au>Peruch, Frédéric</au><au>Lutz, Pierre Joseph</au><au>Wesolek, Marcel</au><au>Kress, Jacky</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymerization of norbornene with Co(II) complexes</atitle><jtitle>Macromolecular symposia.</jtitle><addtitle>Macromol. 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| ispartof | Macromolecular symposia., 2004-06, Vol.213 (1), p.265-274 |
| issn | 1022-1360 1521-3900 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | addition polymerization Aluminum Catalysis catalysts Chemical Sciences cobalt Frames Ligands Monomers norbornene Polymerization Polymers pyridine bis(imine) Pyridines |
| title | Polymerization of norbornene with Co(II) complexes |
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