High-Performance Optical Power Limiting Filters at Telecommunication Wavelengths: When Aza-BODIPY Dyes Bond to Sol–Gel Materials
An optical power limiter (OPL) device can change its optical properties depending on the input light intensity: it is ideally transparent at low incident power and presents a decrease in transmission when the incident intensity increases. This phenomenon can be used for protection of optical sensors...
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| Veröffentlicht in: | Journal of physical chemistry. C 2020-11, Vol.124 (44), p.24344-24350 |
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| container_issue | 44 |
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| container_title | Journal of physical chemistry. C |
| container_volume | 124 |
| creator | David, Sylvain Chateau, Denis Chang, Hao-Jung Karlsson, Linda H Bondar, Mykhailo V Lopes, Cesar Le Guennic, Boris Jacquemin, Denis Berginc, Gérard Maury, Olivier Parola, Stéphane Andraud, Chantal |
| description | An optical power limiter (OPL) device can change its optical properties depending on the input light intensity: it is ideally transparent at low incident power and presents a decrease in transmission when the incident intensity increases. This phenomenon can be used for protection of optical sensors. This paper presents the design of a functionalized aza-BODIPY chromophore, combining good nonlinear two-photon absorption and exited-state absorption in the short-wave infrared range (1300–1600 nm). The aza-BODIPY chromophores also show excellent thermal and photochemical stabilities. Their covalent grafting to a sol–gel matrix leads to the formation of class II sol–gel materials that allows for extraordinary doping concentrations of up to 280 mol·L–1 (40 wt %), which results in highly efficient OPL performances at 1550 nm. |
| doi_str_mv | 10.1021/acs.jpcc.0c08006 |
| format | Article |
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| subjects | C: Plasmonics Optical, Magnetic, and Hybrid Materials Chemical Sciences |
| title | High-Performance Optical Power Limiting Filters at Telecommunication Wavelengths: When Aza-BODIPY Dyes Bond to Sol–Gel Materials |
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