Rotaxanating Metallo-supramolecular Nano-cylinder Helicates to Switch DNA Junction Binding

A class of rotaxane is created, not by encapsulating a conventional linear thread, but rather by wrapping a large cucurbit[10]­uril macrocycle about a three-dimensional, cylindrical, nanosized, self-assembled supramolecular helicate as the axle. The resulting pseudo-rotaxane is readily converted int...

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Veröffentlicht in:	Journal of the American Chemical Society 2020-12, Vol.142 (49), p.20651-20660
Hauptverfasser:	Hooper, Catherine A. J, Cardo, Lucia, Craig, James S, Melidis, Lazaros, Garai, Aditya, Egan, Ross T, Sadovnikova, Viktoriia, Burkert, Florian, Male, Louise, Hodges, Nikolas J, Browning, Douglas F, Rosas, Roselyne, Liu, Fengbo, Rocha, Fillipe V, Lima, Mauro A, Liu, Simin, Bardelang, David, Hannon, Michael J
Format:	Artikel
Sprache:	eng
Schlagworte:	Bridged-Ring Compounds - chemistry Chemical Sciences Coordination Complexes - chemistry DNA - chemistry Imidazoles - chemistry Ligands Metals - chemistry Nanostructures - chemistry Rotaxanes - chemistry
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