Photoelectrochemical properties of dyads composed of porphyrin/ruthenium catalyst grafted on metal oxide semiconductors
In the current work, we present the use of two free-base and two zinc-metallated porphyrin-ruthenium(II) polypyridine dyads, along with two reference porphyrin derivatives, as sensitizers in both n- and p-type DSSCs and DSPECs. Two of the dyads contain the well-known Ru(bpy)3 unit (HOOC-DMP-Ru(bpy)3...
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| Veröffentlicht in: | Dyes and pigments 2021-02, Vol.185, p.108908, Article 108908 |
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| creator | Charisiadis, Asterios Glymenaki, Eleni Planchat, Aurélien Margiola, Sofia Lavergne-Bril, Anna-Caroline Nikoloudakis, Emmanouil Nikolaou, Vasilis Charalambidis, Georgios Coutsolelos, Athanassios G. Odobel, Fabrice |
| description | In the current work, we present the use of two free-base and two zinc-metallated porphyrin-ruthenium(II) polypyridine dyads, along with two reference porphyrin derivatives, as sensitizers in both n- and p-type DSSCs and DSPECs. Two of the dyads contain the well-known Ru(bpy)3 unit (HOOC-DMP-Ru(bpy)3 and HOOC-(Zn)DMP-Ru(bpy)3), while in the other two terpyridine-Ru(Cl)-bypiridine was used (HOOC-DMP-tpy-Ru and HOOC-(Zn)DMP-tpy-Ru). In all systems, the amide-bonding motif was utilized for the connection of the counterparts comprising each dyad. Photophysical investigation of the reported systems indicated sufficient electronic interactions for the dyads in their excited states (emission measurements). The photovoltaic measurements revealed that the presence of the ruthenium complex improves the overall performance of the dyads with the most efficient dyad being HOOC-(Zn)DMP-tpy-Ru in both n- and p-type DSSCs. Consequently, HOOC-(Zn)DMP-tpy-Ru was used to fabricate n- and p-DSPECs towards the oxidation of methoxy-benzyl alcohol and the reduction of CO2, respectively. |
| doi_str_mv | 10.1016/j.dyepig.2020.108908 |
| format | Article |
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Two of the dyads contain the well-known Ru(bpy)3 unit (HOOC-DMP-Ru(bpy)3 and HOOC-(Zn)DMP-Ru(bpy)3), while in the other two terpyridine-Ru(Cl)-bypiridine was used (HOOC-DMP-tpy-Ru and HOOC-(Zn)DMP-tpy-Ru). In all systems, the amide-bonding motif was utilized for the connection of the counterparts comprising each dyad. Photophysical investigation of the reported systems indicated sufficient electronic interactions for the dyads in their excited states (emission measurements). The photovoltaic measurements revealed that the presence of the ruthenium complex improves the overall performance of the dyads with the most efficient dyad being HOOC-(Zn)DMP-tpy-Ru in both n- and p-type DSSCs. Consequently, HOOC-(Zn)DMP-tpy-Ru was used to fabricate n- and p-DSPECs towards the oxidation of methoxy-benzyl alcohol and the reduction of CO2, respectively.</description><identifier>ISSN: 0143-7208</identifier><identifier>EISSN: 1873-3743</identifier><identifier>DOI: 10.1016/j.dyepig.2020.108908</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Catalysis ; Chemical Sciences ; Coordination chemistry ; DSSC ; Material chemistry ; NiO ; Organic chemistry ; Porphyrins</subject><ispartof>Dyes and pigments, 2021-02, Vol.185, p.108908, Article 108908</ispartof><rights>2020 Elsevier Ltd</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-59f5a7bfc688a82af2b3c6c363818898222e1bf0fbdbcea574dc2ddb8def54733</citedby><cites>FETCH-LOGICAL-c386t-59f5a7bfc688a82af2b3c6c363818898222e1bf0fbdbcea574dc2ddb8def54733</cites><orcidid>0000-0001-5682-2968 ; 0000-0001-5715-2484 ; 0000-0002-2320-6672 ; 0000-0001-7289-4160 ; 0000-0003-1237-9962 ; 0000-0001-9724-9248</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.dyepig.2020.108908$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03015371$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Charisiadis, Asterios</creatorcontrib><creatorcontrib>Glymenaki, Eleni</creatorcontrib><creatorcontrib>Planchat, Aurélien</creatorcontrib><creatorcontrib>Margiola, Sofia</creatorcontrib><creatorcontrib>Lavergne-Bril, Anna-Caroline</creatorcontrib><creatorcontrib>Nikoloudakis, Emmanouil</creatorcontrib><creatorcontrib>Nikolaou, Vasilis</creatorcontrib><creatorcontrib>Charalambidis, Georgios</creatorcontrib><creatorcontrib>Coutsolelos, Athanassios G.</creatorcontrib><creatorcontrib>Odobel, Fabrice</creatorcontrib><title>Photoelectrochemical properties of dyads composed of porphyrin/ruthenium catalyst grafted on metal oxide semiconductors</title><title>Dyes and pigments</title><description>In the current work, we present the use of two free-base and two zinc-metallated porphyrin-ruthenium(II) polypyridine dyads, along with two reference porphyrin derivatives, as sensitizers in both n- and p-type DSSCs and DSPECs. Two of the dyads contain the well-known Ru(bpy)3 unit (HOOC-DMP-Ru(bpy)3 and HOOC-(Zn)DMP-Ru(bpy)3), while in the other two terpyridine-Ru(Cl)-bypiridine was used (HOOC-DMP-tpy-Ru and HOOC-(Zn)DMP-tpy-Ru). In all systems, the amide-bonding motif was utilized for the connection of the counterparts comprising each dyad. Photophysical investigation of the reported systems indicated sufficient electronic interactions for the dyads in their excited states (emission measurements). The photovoltaic measurements revealed that the presence of the ruthenium complex improves the overall performance of the dyads with the most efficient dyad being HOOC-(Zn)DMP-tpy-Ru in both n- and p-type DSSCs. Consequently, HOOC-(Zn)DMP-tpy-Ru was used to fabricate n- and p-DSPECs towards the oxidation of methoxy-benzyl alcohol and the reduction of CO2, respectively.</description><subject>Catalysis</subject><subject>Chemical Sciences</subject><subject>Coordination chemistry</subject><subject>DSSC</subject><subject>Material chemistry</subject><subject>NiO</subject><subject>Organic chemistry</subject><subject>Porphyrins</subject><issn>0143-7208</issn><issn>1873-3743</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOD7-gYtsXXTMo4_MRhBRRxjQha5DmtzYDG1Tkozaf29LxaWrCx_nHLgfQleUrCmh5c1-bUYY3MeaETYjsSHiCK2oqHjGq5wfoxWhOc8qRsQpOotxTwgRnNEV-nptfPLQgk7B6wY6p1WLh-AHCMlBxN5iMyoTsfbd4COYmQw-DM0YXH8TDqmB3h06rFVS7RgT_gjKpjnX4w4mhv23M4DjvO17c9DJh3iBTqxqI1z-3nP0_vjwdr_Ndi9Pz_d3u0xzUaas2NhCVbXVpRBKMGVZzXWpeckFFWIjGGNAa0tsbWoNqqhyo5kxtTBgi7zi_BxdL7uNauUQXKfCKL1ycnu3kzMjnNCCV_STTtl8yergYwxg_wqUyFm03MtFtJxFy0X0VLtdajD98ekgyKgd9BqMC5NWabz7f-AHREWMxQ</recordid><startdate>202102</startdate><enddate>202102</enddate><creator>Charisiadis, Asterios</creator><creator>Glymenaki, Eleni</creator><creator>Planchat, Aurélien</creator><creator>Margiola, Sofia</creator><creator>Lavergne-Bril, Anna-Caroline</creator><creator>Nikoloudakis, Emmanouil</creator><creator>Nikolaou, Vasilis</creator><creator>Charalambidis, Georgios</creator><creator>Coutsolelos, Athanassios G.</creator><creator>Odobel, Fabrice</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0001-5682-2968</orcidid><orcidid>https://orcid.org/0000-0001-5715-2484</orcidid><orcidid>https://orcid.org/0000-0002-2320-6672</orcidid><orcidid>https://orcid.org/0000-0001-7289-4160</orcidid><orcidid>https://orcid.org/0000-0003-1237-9962</orcidid><orcidid>https://orcid.org/0000-0001-9724-9248</orcidid></search><sort><creationdate>202102</creationdate><title>Photoelectrochemical properties of dyads composed of porphyrin/ruthenium catalyst grafted on metal oxide semiconductors</title><author>Charisiadis, Asterios ; Glymenaki, Eleni ; Planchat, Aurélien ; Margiola, Sofia ; Lavergne-Bril, Anna-Caroline ; Nikoloudakis, Emmanouil ; Nikolaou, Vasilis ; Charalambidis, Georgios ; Coutsolelos, Athanassios G. ; Odobel, Fabrice</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-59f5a7bfc688a82af2b3c6c363818898222e1bf0fbdbcea574dc2ddb8def54733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Catalysis</topic><topic>Chemical Sciences</topic><topic>Coordination chemistry</topic><topic>DSSC</topic><topic>Material chemistry</topic><topic>NiO</topic><topic>Organic chemistry</topic><topic>Porphyrins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Charisiadis, Asterios</creatorcontrib><creatorcontrib>Glymenaki, Eleni</creatorcontrib><creatorcontrib>Planchat, Aurélien</creatorcontrib><creatorcontrib>Margiola, Sofia</creatorcontrib><creatorcontrib>Lavergne-Bril, Anna-Caroline</creatorcontrib><creatorcontrib>Nikoloudakis, Emmanouil</creatorcontrib><creatorcontrib>Nikolaou, Vasilis</creatorcontrib><creatorcontrib>Charalambidis, Georgios</creatorcontrib><creatorcontrib>Coutsolelos, Athanassios G.</creatorcontrib><creatorcontrib>Odobel, Fabrice</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Dyes and pigments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Charisiadis, Asterios</au><au>Glymenaki, Eleni</au><au>Planchat, Aurélien</au><au>Margiola, Sofia</au><au>Lavergne-Bril, Anna-Caroline</au><au>Nikoloudakis, Emmanouil</au><au>Nikolaou, Vasilis</au><au>Charalambidis, Georgios</au><au>Coutsolelos, Athanassios G.</au><au>Odobel, Fabrice</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoelectrochemical properties of dyads composed of porphyrin/ruthenium catalyst grafted on metal oxide semiconductors</atitle><jtitle>Dyes and pigments</jtitle><date>2021-02</date><risdate>2021</risdate><volume>185</volume><spage>108908</spage><pages>108908-</pages><artnum>108908</artnum><issn>0143-7208</issn><eissn>1873-3743</eissn><abstract>In the current work, we present the use of two free-base and two zinc-metallated porphyrin-ruthenium(II) polypyridine dyads, along with two reference porphyrin derivatives, as sensitizers in both n- and p-type DSSCs and DSPECs. Two of the dyads contain the well-known Ru(bpy)3 unit (HOOC-DMP-Ru(bpy)3 and HOOC-(Zn)DMP-Ru(bpy)3), while in the other two terpyridine-Ru(Cl)-bypiridine was used (HOOC-DMP-tpy-Ru and HOOC-(Zn)DMP-tpy-Ru). In all systems, the amide-bonding motif was utilized for the connection of the counterparts comprising each dyad. Photophysical investigation of the reported systems indicated sufficient electronic interactions for the dyads in their excited states (emission measurements). The photovoltaic measurements revealed that the presence of the ruthenium complex improves the overall performance of the dyads with the most efficient dyad being HOOC-(Zn)DMP-tpy-Ru in both n- and p-type DSSCs. 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| subjects | Catalysis Chemical Sciences Coordination chemistry DSSC Material chemistry NiO Organic chemistry Porphyrins |
| title | Photoelectrochemical properties of dyads composed of porphyrin/ruthenium catalyst grafted on metal oxide semiconductors |
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