Stereoselective Synthesis of o-Bromo (or Iodo)aryl P-Chirogenic Phosphines Based on Aryne Chemistry

The efficient synthesis of chiral or achiral tertiary phosphines bearing an o-bromo (or iodo)aryl substituent is described. The key step of this synthesis is based on the reaction of a secondary phosphine borane with the 1,2-dibromo (or diiodo)arene, owing to the formation in situ of an aryne specie...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2012-07, Vol.77 (13), p.5759-5769
Hauptverfasser:	Bayardon, Jérôme, Laureano, Hugo, Diemer, Vincent, Dutartre, Mathieu, Das, Utpal, Rousselin, Yoann, Henry, Jean-Christophe, Colobert, Françoise, Leroux, Frédéric R, Jugé, Sylvain
Format:	Artikel
Sprache:	eng
Schlagworte:	B derivatives Chemical Sciences Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Organic chemistry Organometalloidal and organometallic compounds P derivatives Preparations and properties
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!