Crystal and magnetic structures, magnetic and ferroelectric properties of strontium ferrite partially substituted with in ions

The influence of temperature factor to crystal structure as well as magnetic and electric properties of strontium hexaferrite partially substituted with diamagnetic indium ions has been investigated. Ferroelectric properties have been found out in SrFe11.9In0.1O19 compound that contradicts to conven...

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Veröffentlicht in:Journal of alloys and compounds 2020-04, Vol.821, p.153412, Article 153412
Hauptverfasser: Turchenko, Vitalii, Kostishyn, V.G., Trukhanov, Sergei, Damay, Francoise, Porcher, Florence, Balasoiu, Maria, Lupu, Nicoleta, Bozzo, Bernar, Fina, Ignasi, Trukhanov, Alex, Waliszewski, Janusz, Recko, Katarzyna, Polosan, Silviu
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container_start_page 153412
container_title Journal of alloys and compounds
container_volume 821
creator Turchenko, Vitalii
Kostishyn, V.G.
Trukhanov, Sergei
Damay, Francoise
Porcher, Florence
Balasoiu, Maria
Lupu, Nicoleta
Bozzo, Bernar
Fina, Ignasi
Trukhanov, Alex
Waliszewski, Janusz
Recko, Katarzyna
Polosan, Silviu
description The influence of temperature factor to crystal structure as well as magnetic and electric properties of strontium hexaferrite partially substituted with diamagnetic indium ions has been investigated. Ferroelectric properties have been found out in SrFe11.9In0.1O19 compound that contradicts to conventional opinion, which describe its crystal structure within the framework of centrosymmetric space group P63/mmc (No. 194). For determination features of the crystal structure, which are responsible for ferroelectric properties of strontium hexaferrite, have been carried out neutron diffraction measurements with high resolution in temperature range from 1.5 to 740 K. The analysis of hexaferrite structure has been executed within the framework both centrosymmetric and non-centrosymmetric space group. Values of coefficients of magneto crystalline anisotropy at 5 and 300 K and influence of ambient temperature to linear size of magnetic regions have been determined from magnetic measurements. •Spontaneous polarization has been found in polycrystalline SrFe11.9In0.1O19 strontium ferrite at room temperature.•Crystal structure of strontium hexaferrite has been refined in the framework of non-centrosymmetric space group.•Existence of spontaneous polarization in M-type hexaferrite has been explained by different distortions of oxygen polyhedra.
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Ferroelectric properties have been found out in SrFe11.9In0.1O19 compound that contradicts to conventional opinion, which describe its crystal structure within the framework of centrosymmetric space group P63/mmc (No. 194). For determination features of the crystal structure, which are responsible for ferroelectric properties of strontium hexaferrite, have been carried out neutron diffraction measurements with high resolution in temperature range from 1.5 to 740 K. The analysis of hexaferrite structure has been executed within the framework both centrosymmetric and non-centrosymmetric space group. Values of coefficients of magneto crystalline anisotropy at 5 and 300 K and influence of ambient temperature to linear size of magnetic regions have been determined from magnetic measurements. •Spontaneous polarization has been found in polycrystalline SrFe11.9In0.1O19 strontium ferrite at room temperature.•Crystal structure of strontium hexaferrite has been refined in the framework of non-centrosymmetric space group.•Existence of spontaneous polarization in M-type hexaferrite has been explained by different distortions of oxygen polyhedra.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2019.153412</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Ambient temperature ; Anisotropy ; Chemical Sciences ; Crystal structure ; Diamagnetism ; Electric properties ; Ferroelectric materials ; Ferroelectricity ; Inorganic chemistry ; Magnetic measurement ; Magnetic properties ; Neutron diffraction ; Spontaneous polarization ; strontium ferrite ; Substitutes</subject><ispartof>Journal of alloys and compounds, 2020-04, Vol.821, p.153412, Article 153412</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright Elsevier BV Apr 15, 2020</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c418t-95f9a3bb1bb477ec76bb725d9a514686dd56d185793a09e89de09cb6ee6323e3</citedby><cites>FETCH-LOGICAL-c418t-95f9a3bb1bb477ec76bb725d9a514686dd56d185793a09e89de09cb6ee6323e3</cites><orcidid>0000-0003-2188-8187 ; 0000-0003-4182-6194 ; 0000-0002-4755-3898 ; 0000-0003-3430-9578 ; 0000-0002-8873-6498 ; 0000-0002-2888-9783</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2019.153412$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02997950$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Turchenko, Vitalii</creatorcontrib><creatorcontrib>Kostishyn, V.G.</creatorcontrib><creatorcontrib>Trukhanov, Sergei</creatorcontrib><creatorcontrib>Damay, Francoise</creatorcontrib><creatorcontrib>Porcher, Florence</creatorcontrib><creatorcontrib>Balasoiu, Maria</creatorcontrib><creatorcontrib>Lupu, Nicoleta</creatorcontrib><creatorcontrib>Bozzo, Bernar</creatorcontrib><creatorcontrib>Fina, Ignasi</creatorcontrib><creatorcontrib>Trukhanov, Alex</creatorcontrib><creatorcontrib>Waliszewski, Janusz</creatorcontrib><creatorcontrib>Recko, Katarzyna</creatorcontrib><creatorcontrib>Polosan, Silviu</creatorcontrib><title>Crystal and magnetic structures, magnetic and ferroelectric properties of strontium ferrite partially substituted with in ions</title><title>Journal of alloys and compounds</title><description>The influence of temperature factor to crystal structure as well as magnetic and electric properties of strontium hexaferrite partially substituted with diamagnetic indium ions has been investigated. 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Ferroelectric properties have been found out in SrFe11.9In0.1O19 compound that contradicts to conventional opinion, which describe its crystal structure within the framework of centrosymmetric space group P63/mmc (No. 194). For determination features of the crystal structure, which are responsible for ferroelectric properties of strontium hexaferrite, have been carried out neutron diffraction measurements with high resolution in temperature range from 1.5 to 740 K. The analysis of hexaferrite structure has been executed within the framework both centrosymmetric and non-centrosymmetric space group. 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subjects Ambient temperature
Anisotropy
Chemical Sciences
Crystal structure
Diamagnetism
Electric properties
Ferroelectric materials
Ferroelectricity
Inorganic chemistry
Magnetic measurement
Magnetic properties
Neutron diffraction
Spontaneous polarization
strontium ferrite
Substitutes
title Crystal and magnetic structures, magnetic and ferroelectric properties of strontium ferrite partially substituted with in ions
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