Development of organic glass using Interpenetrating Polymer Networks with enhanced resistance towards scratches and solvents
[Display omitted] •Materials combining PMMA and PCR39 have been synthesized without exogenous solvent.•Transparent glasses with transmission higher than 95% were obtained.•The presence of PCR39® increases the scratch resistance of PMMA based materials.•The presence of PCR39® improves the solvent res...
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| Veröffentlicht in: | European polymer journal 2015-02, Vol.63, p.132-140 |
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| container_title | European polymer journal |
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| creator | Berrebi, Mickaël Fabre-Francke, Isabelle Lavédrine, Bertrand Fichet, Odile |
| description | [Display omitted]
•Materials combining PMMA and PCR39 have been synthesized without exogenous solvent.•Transparent glasses with transmission higher than 95% were obtained.•The presence of PCR39® increases the scratch resistance of PMMA based materials.•The presence of PCR39® improves the solvent resistance of the PMMA based materials.
Acrylate polymers are one of common organic glass family. However their sensitivity to abrasion is an important drawback. Various alternatives were considered but they are often expensive. In this work, we show that the polymethylmethacrylate (PMMA) glass resistance can be improved by performing materials based on Interpenetrating Polymer Network (IPN) at low cost. A series of transparent IPNs based on an aliphatic polycarbonate and PMMA was synthesized through in situ polymerization process. The formation of two networks in the IPNs was studied by FTIR spectroscopy. Effects of PMMA cross-linking and partner proportions in the IPNs were investigated by dynamic mechanical thermal analysis. Optical properties, solvent and scratch resistances have been also studied. |
| doi_str_mv | 10.1016/j.eurpolymj.2014.12.010 |
| format | Article |
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•Materials combining PMMA and PCR39 have been synthesized without exogenous solvent.•Transparent glasses with transmission higher than 95% were obtained.•The presence of PCR39® increases the scratch resistance of PMMA based materials.•The presence of PCR39® improves the solvent resistance of the PMMA based materials.
Acrylate polymers are one of common organic glass family. However their sensitivity to abrasion is an important drawback. Various alternatives were considered but they are often expensive. In this work, we show that the polymethylmethacrylate (PMMA) glass resistance can be improved by performing materials based on Interpenetrating Polymer Network (IPN) at low cost. A series of transparent IPNs based on an aliphatic polycarbonate and PMMA was synthesized through in situ polymerization process. The formation of two networks in the IPNs was studied by FTIR spectroscopy. Effects of PMMA cross-linking and partner proportions in the IPNs were investigated by dynamic mechanical thermal analysis. Optical properties, solvent and scratch resistances have been also studied.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2014.12.010</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Abrasion ; Abrasion resistance ; Chemical Sciences ; Glass ; Interpenetrating networks ; Interpenetrating Polymer Networks ; Mechanical properties ; Polycarbonates ; Polymerization ; Polymers ; Polymethyl methacrylates ; Polymethylmethacrylate ; Solvents ; Surfaces and interfaces</subject><ispartof>European polymer journal, 2015-02, Vol.63, p.132-140</ispartof><rights>2014 Elsevier Ltd</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c468t-a9f93bd27e1323a5c2182e96ed4fc6e5e74b060f8cd694c908a09939548e5c133</citedby><cites>FETCH-LOGICAL-c468t-a9f93bd27e1323a5c2182e96ed4fc6e5e74b060f8cd694c908a09939548e5c133</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.eurpolymj.2014.12.010$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://cyu.hal.science/hal-02979956$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Berrebi, Mickaël</creatorcontrib><creatorcontrib>Fabre-Francke, Isabelle</creatorcontrib><creatorcontrib>Lavédrine, Bertrand</creatorcontrib><creatorcontrib>Fichet, Odile</creatorcontrib><title>Development of organic glass using Interpenetrating Polymer Networks with enhanced resistance towards scratches and solvents</title><title>European polymer journal</title><description>[Display omitted]
•Materials combining PMMA and PCR39 have been synthesized without exogenous solvent.•Transparent glasses with transmission higher than 95% were obtained.•The presence of PCR39® increases the scratch resistance of PMMA based materials.•The presence of PCR39® improves the solvent resistance of the PMMA based materials.
Acrylate polymers are one of common organic glass family. However their sensitivity to abrasion is an important drawback. Various alternatives were considered but they are often expensive. In this work, we show that the polymethylmethacrylate (PMMA) glass resistance can be improved by performing materials based on Interpenetrating Polymer Network (IPN) at low cost. A series of transparent IPNs based on an aliphatic polycarbonate and PMMA was synthesized through in situ polymerization process. The formation of two networks in the IPNs was studied by FTIR spectroscopy. Effects of PMMA cross-linking and partner proportions in the IPNs were investigated by dynamic mechanical thermal analysis. Optical properties, solvent and scratch resistances have been also studied.</description><subject>Abrasion</subject><subject>Abrasion resistance</subject><subject>Chemical Sciences</subject><subject>Glass</subject><subject>Interpenetrating networks</subject><subject>Interpenetrating Polymer Networks</subject><subject>Mechanical properties</subject><subject>Polycarbonates</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polymethyl methacrylates</subject><subject>Polymethylmethacrylate</subject><subject>Solvents</subject><subject>Surfaces and interfaces</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFUUtv2zAMFoYNWNb1N1TH9WBXsmzJOgbdowWCtof2LKgynShzJFdUEhTYj5-NFL32RIL8HiA_Qi44Kznj8mpbwj6NcXjdbcuK8brkVck4-0QWvFWi4LpuPpMFmzaFYI36Sr4hbhljSkixIP9-wgGGOO4gZBp7GtPaBu_oerCIdI8-rOltyJBGCJCTzfPgYXaDRO8gH2P6i_To84ZC2NjgoKMJ0GOee5rj0aYOKbqJ6jaA1IaOYhwOkx9-J196OyCcv9Uz8vT71-P1TbG6_3N7vVwVrpZtLqzutXjuKgVcVMI2ruJtBVpCV_dOQgOqfmaS9a3rpK6dZq1lWgvd1C00jgtxRi5Puhs7mDH5nU2vJlpvbpYrM89YpZXWjTzwCfvjhB1TfNkDZrPz6GAYbIC4R8OlUrqttVYTVJ2gLkXEBP27NmdmzsZszXs2Zs7G8MpM2UzM5YkJ09UHD8mg8zA_zydw2XTRf6jxH3ZRn0A</recordid><startdate>20150201</startdate><enddate>20150201</enddate><creator>Berrebi, Mickaël</creator><creator>Fabre-Francke, Isabelle</creator><creator>Lavédrine, Bertrand</creator><creator>Fichet, Odile</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope></search><sort><creationdate>20150201</creationdate><title>Development of organic glass using Interpenetrating Polymer Networks with enhanced resistance towards scratches and solvents</title><author>Berrebi, Mickaël ; Fabre-Francke, Isabelle ; Lavédrine, Bertrand ; Fichet, Odile</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c468t-a9f93bd27e1323a5c2182e96ed4fc6e5e74b060f8cd694c908a09939548e5c133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Abrasion</topic><topic>Abrasion resistance</topic><topic>Chemical Sciences</topic><topic>Glass</topic><topic>Interpenetrating networks</topic><topic>Interpenetrating Polymer Networks</topic><topic>Mechanical properties</topic><topic>Polycarbonates</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polymethyl methacrylates</topic><topic>Polymethylmethacrylate</topic><topic>Solvents</topic><topic>Surfaces and interfaces</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Berrebi, Mickaël</creatorcontrib><creatorcontrib>Fabre-Francke, Isabelle</creatorcontrib><creatorcontrib>Lavédrine, Bertrand</creatorcontrib><creatorcontrib>Fichet, Odile</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Berrebi, Mickaël</au><au>Fabre-Francke, Isabelle</au><au>Lavédrine, Bertrand</au><au>Fichet, Odile</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of organic glass using Interpenetrating Polymer Networks with enhanced resistance towards scratches and solvents</atitle><jtitle>European polymer journal</jtitle><date>2015-02-01</date><risdate>2015</risdate><volume>63</volume><spage>132</spage><epage>140</epage><pages>132-140</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><abstract>[Display omitted]
•Materials combining PMMA and PCR39 have been synthesized without exogenous solvent.•Transparent glasses with transmission higher than 95% were obtained.•The presence of PCR39® increases the scratch resistance of PMMA based materials.•The presence of PCR39® improves the solvent resistance of the PMMA based materials.
Acrylate polymers are one of common organic glass family. However their sensitivity to abrasion is an important drawback. Various alternatives were considered but they are often expensive. In this work, we show that the polymethylmethacrylate (PMMA) glass resistance can be improved by performing materials based on Interpenetrating Polymer Network (IPN) at low cost. A series of transparent IPNs based on an aliphatic polycarbonate and PMMA was synthesized through in situ polymerization process. The formation of two networks in the IPNs was studied by FTIR spectroscopy. Effects of PMMA cross-linking and partner proportions in the IPNs were investigated by dynamic mechanical thermal analysis. Optical properties, solvent and scratch resistances have been also studied.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2014.12.010</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Abrasion Abrasion resistance Chemical Sciences Glass Interpenetrating networks Interpenetrating Polymer Networks Mechanical properties Polycarbonates Polymerization Polymers Polymethyl methacrylates Polymethylmethacrylate Solvents Surfaces and interfaces |
| title | Development of organic glass using Interpenetrating Polymer Networks with enhanced resistance towards scratches and solvents |
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