Structural Studies of dielectric HDPE+ZrO2 polymer nanocomposites: filler concentration dependences
Structural properties of HDPE+ZrO2 polymer nanocomposites thin films of 80-100μm thicknesses were investigated using SANS, XRD, Laser Raman and FTIR spectroscopy. The mass fraction of the filler was 1, 3, 10, and 20%. Results of XRD analysis showed that ZrO2 powder was crystallized both in monoclini...
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| creator | Nabiyev, A A Islamov, A Kh Maharramov, A M Nuriyev, M A Ismayilova, R S Doroshkevic, A S Pawlukojc, A Turchenko, V A Olejniczak, A Rulev, M İ Almasan, V Kuklin, A I |
| description | Structural properties of HDPE+ZrO2 polymer nanocomposites thin films of 80-100μm thicknesses were investigated using SANS, XRD, Laser Raman and FTIR spectroscopy. The mass fraction of the filler was 1, 3, 10, and 20%. Results of XRD analysis showed that ZrO2 powder was crystallized both in monoclinic and in cubic phase under normal conditions. The percentages of monoclinic and cubic phase were found to be 99.8% and 0.2%, respectively. It was found that ZrO2 nanoparticles did not affect the main crystal and chemical structure of HDPE, but the degree of crystallinity of the polymer decreases with increasing concentration of zirconium oxide. SANS experiments showed that at ambient conditions ZrO2 nanoparticles mainly distributed like mono-particles in the polymer matrix at all concentrations of filler.The structure of HDPE+ZrO2 does not changes up to 132°C at 1-3% of filler, excepting changing of the polymer structure at temperatures upper 82°C. At high concentrations of filler 10-20% the aggregation of ZrO2 nanoparticles occurs, forming domains of 2.5μm. The results of Raman and FTIR spectroscopy did not show additional specific chemical bonds between the filler and the polymer matrix. New peaks formation was not observed. These results suggest that core-shell structure does not exist in the polymer nanocomposite system. |
| doi_str_mv | 10.1088/1742-6596/994/1/012011 |
| format | Article |
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The mass fraction of the filler was 1, 3, 10, and 20%. Results of XRD analysis showed that ZrO2 powder was crystallized both in monoclinic and in cubic phase under normal conditions. The percentages of monoclinic and cubic phase were found to be 99.8% and 0.2%, respectively. It was found that ZrO2 nanoparticles did not affect the main crystal and chemical structure of HDPE, but the degree of crystallinity of the polymer decreases with increasing concentration of zirconium oxide. SANS experiments showed that at ambient conditions ZrO2 nanoparticles mainly distributed like mono-particles in the polymer matrix at all concentrations of filler.The structure of HDPE+ZrO2 does not changes up to 132°C at 1-3% of filler, excepting changing of the polymer structure at temperatures upper 82°C. At high concentrations of filler 10-20% the aggregation of ZrO2 nanoparticles occurs, forming domains of 2.5μm. The results of Raman and FTIR spectroscopy did not show additional specific chemical bonds between the filler and the polymer matrix. New peaks formation was not observed. These results suggest that core-shell structure does not exist in the polymer nanocomposite system.</description><identifier>ISSN: 1742-6588</identifier><identifier>EISSN: 1742-6596</identifier><identifier>DOI: 10.1088/1742-6596/994/1/012011</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Chemical bonds ; Chemical Sciences ; Core-shell structure ; Crystal structure ; Crystallization ; Crystals ; Degree of crystallinity ; Fillers ; Fourier transforms ; Infrared spectroscopy ; Monoclinic lattice ; Nanocomposites ; Nanoparticles ; Physics ; Polymer films ; Polymers ; Spectrum analysis ; Thickness ; Thin films ; X-ray diffraction ; Zirconium dioxide ; Zirconium oxides</subject><ispartof>Journal of physics. Conference series, 2018-03, Vol.994 (1), p.012011-1-012011-11</ispartof><rights>Published under licence by IOP Publishing Ltd</rights><rights>2018. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/1742-6596/994/1/012011/pdf$$EPDF$$P50$$Giop$$Hfree_for_read</linktopdf><link.rule.ids>230,314,776,780,881,27901,27902,38845,38867,53815,53842</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02976296$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Nabiyev, A A</creatorcontrib><creatorcontrib>Islamov, A Kh</creatorcontrib><creatorcontrib>Maharramov, A M</creatorcontrib><creatorcontrib>Nuriyev, M A</creatorcontrib><creatorcontrib>Ismayilova, R S</creatorcontrib><creatorcontrib>Doroshkevic, A S</creatorcontrib><creatorcontrib>Pawlukojc, A</creatorcontrib><creatorcontrib>Turchenko, V A</creatorcontrib><creatorcontrib>Olejniczak, A</creatorcontrib><creatorcontrib>Rulev, M İ</creatorcontrib><creatorcontrib>Almasan, V</creatorcontrib><creatorcontrib>Kuklin, A I</creatorcontrib><title>Structural Studies of dielectric HDPE+ZrO2 polymer nanocomposites: filler concentration dependences</title><title>Journal of physics. Conference series</title><addtitle>J. Phys.: Conf. Ser</addtitle><description>Structural properties of HDPE+ZrO2 polymer nanocomposites thin films of 80-100μm thicknesses were investigated using SANS, XRD, Laser Raman and FTIR spectroscopy. The mass fraction of the filler was 1, 3, 10, and 20%. Results of XRD analysis showed that ZrO2 powder was crystallized both in monoclinic and in cubic phase under normal conditions. The percentages of monoclinic and cubic phase were found to be 99.8% and 0.2%, respectively. It was found that ZrO2 nanoparticles did not affect the main crystal and chemical structure of HDPE, but the degree of crystallinity of the polymer decreases with increasing concentration of zirconium oxide. SANS experiments showed that at ambient conditions ZrO2 nanoparticles mainly distributed like mono-particles in the polymer matrix at all concentrations of filler.The structure of HDPE+ZrO2 does not changes up to 132°C at 1-3% of filler, excepting changing of the polymer structure at temperatures upper 82°C. At high concentrations of filler 10-20% the aggregation of ZrO2 nanoparticles occurs, forming domains of 2.5μm. The results of Raman and FTIR spectroscopy did not show additional specific chemical bonds between the filler and the polymer matrix. New peaks formation was not observed. These results suggest that core-shell structure does not exist in the polymer nanocomposite system.</description><subject>Chemical bonds</subject><subject>Chemical Sciences</subject><subject>Core-shell structure</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Crystals</subject><subject>Degree of crystallinity</subject><subject>Fillers</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>Monoclinic lattice</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Physics</subject><subject>Polymer films</subject><subject>Polymers</subject><subject>Spectrum analysis</subject><subject>Thickness</subject><subject>Thin films</subject><subject>X-ray diffraction</subject><subject>Zirconium dioxide</subject><subject>Zirconium oxides</subject><issn>1742-6588</issn><issn>1742-6596</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><sourceid>BENPR</sourceid><recordid>eNpVkF1LwzAUhoMoOKd_QQJeidTmo01b72ROpww2mN54E7J8sI6uqWkq7N-bUtlYbk54z3MOhweAW4weMcrzGGcJiVhasLgokhjHCBOE8RkYHRrnh3-eX4Krtt0iRMPLRkCuvOuk75yo4Mp3qtQttAaGWmnpXSnh7GU5ffh2CwIbW-132sFa1FbaXWPb0uv2CZqyqkIsbS117Z3wpa2h0o2ulQ5Rew0ujKhaffNfx-Drdfo5mUXzxdv75HkebWhCfGTkOleGKSOlwpIohRQ1WjOU4SLJhChShFShFdYGrxPMBNMpk4JmVFJE0oSOwf2wdyMq3rhyJ9yeW1Hy2fOc9xkiRcZIwX5xYO8GtnH2p9Ot51vbuTqcx0maEUxpQtNAkYEqbXMEMOK9eN475b1fHsRzzAfxxzNOhj6Wk9UJxxtl6B_Hf4RZ</recordid><startdate>20180301</startdate><enddate>20180301</enddate><creator>Nabiyev, A A</creator><creator>Islamov, A Kh</creator><creator>Maharramov, A M</creator><creator>Nuriyev, M A</creator><creator>Ismayilova, R S</creator><creator>Doroshkevic, A S</creator><creator>Pawlukojc, A</creator><creator>Turchenko, V A</creator><creator>Olejniczak, A</creator><creator>Rulev, M İ</creator><creator>Almasan, V</creator><creator>Kuklin, A I</creator><general>IOP Publishing</general><general>IOP Science</general><scope>O3W</scope><scope>TSCCA</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>H8D</scope><scope>HCIFZ</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>1XC</scope><scope>VOOES</scope></search><sort><creationdate>20180301</creationdate><title>Structural Studies of dielectric HDPE+ZrO2 polymer nanocomposites: filler concentration dependences</title><author>Nabiyev, A A ; Islamov, A Kh ; Maharramov, A M ; Nuriyev, M A ; Ismayilova, R S ; Doroshkevic, A S ; Pawlukojc, A ; Turchenko, V A ; Olejniczak, A ; Rulev, M İ ; Almasan, V ; Kuklin, A I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-h342t-fcb8df6dfccd1c2dd0d3fee6071947aa9500d9ed1ef1b416a6e56ca373c302543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemical bonds</topic><topic>Chemical Sciences</topic><topic>Core-shell structure</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Crystals</topic><topic>Degree of crystallinity</topic><topic>Fillers</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>Monoclinic lattice</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Physics</topic><topic>Polymer films</topic><topic>Polymers</topic><topic>Spectrum analysis</topic><topic>Thickness</topic><topic>Thin films</topic><topic>X-ray diffraction</topic><topic>Zirconium dioxide</topic><topic>Zirconium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nabiyev, A A</creatorcontrib><creatorcontrib>Islamov, A Kh</creatorcontrib><creatorcontrib>Maharramov, A M</creatorcontrib><creatorcontrib>Nuriyev, M A</creatorcontrib><creatorcontrib>Ismayilova, R S</creatorcontrib><creatorcontrib>Doroshkevic, A S</creatorcontrib><creatorcontrib>Pawlukojc, A</creatorcontrib><creatorcontrib>Turchenko, V A</creatorcontrib><creatorcontrib>Olejniczak, A</creatorcontrib><creatorcontrib>Rulev, M İ</creatorcontrib><creatorcontrib>Almasan, V</creatorcontrib><creatorcontrib>Kuklin, A I</creatorcontrib><collection>IOP Publishing Free Content</collection><collection>IOPscience (Open Access)</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Aerospace Database</collection><collection>SciTech Premium Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of physics. Conference series</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nabiyev, A A</au><au>Islamov, A Kh</au><au>Maharramov, A M</au><au>Nuriyev, M A</au><au>Ismayilova, R S</au><au>Doroshkevic, A S</au><au>Pawlukojc, A</au><au>Turchenko, V A</au><au>Olejniczak, A</au><au>Rulev, M İ</au><au>Almasan, V</au><au>Kuklin, A I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural Studies of dielectric HDPE+ZrO2 polymer nanocomposites: filler concentration dependences</atitle><jtitle>Journal of physics. Conference series</jtitle><addtitle>J. Phys.: Conf. Ser</addtitle><date>2018-03-01</date><risdate>2018</risdate><volume>994</volume><issue>1</issue><spage>012011</spage><epage>1-012011-11</epage><pages>012011-1-012011-11</pages><issn>1742-6588</issn><eissn>1742-6596</eissn><abstract>Structural properties of HDPE+ZrO2 polymer nanocomposites thin films of 80-100μm thicknesses were investigated using SANS, XRD, Laser Raman and FTIR spectroscopy. The mass fraction of the filler was 1, 3, 10, and 20%. Results of XRD analysis showed that ZrO2 powder was crystallized both in monoclinic and in cubic phase under normal conditions. The percentages of monoclinic and cubic phase were found to be 99.8% and 0.2%, respectively. It was found that ZrO2 nanoparticles did not affect the main crystal and chemical structure of HDPE, but the degree of crystallinity of the polymer decreases with increasing concentration of zirconium oxide. SANS experiments showed that at ambient conditions ZrO2 nanoparticles mainly distributed like mono-particles in the polymer matrix at all concentrations of filler.The structure of HDPE+ZrO2 does not changes up to 132°C at 1-3% of filler, excepting changing of the polymer structure at temperatures upper 82°C. At high concentrations of filler 10-20% the aggregation of ZrO2 nanoparticles occurs, forming domains of 2.5μm. The results of Raman and FTIR spectroscopy did not show additional specific chemical bonds between the filler and the polymer matrix. New peaks formation was not observed. These results suggest that core-shell structure does not exist in the polymer nanocomposite system.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><doi>10.1088/1742-6596/994/1/012011</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Chemical bonds Chemical Sciences Core-shell structure Crystal structure Crystallization Crystals Degree of crystallinity Fillers Fourier transforms Infrared spectroscopy Monoclinic lattice Nanocomposites Nanoparticles Physics Polymer films Polymers Spectrum analysis Thickness Thin films X-ray diffraction Zirconium dioxide Zirconium oxides |
| title | Structural Studies of dielectric HDPE+ZrO2 polymer nanocomposites: filler concentration dependences |
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