Access to Functionalized 3,5‐Disubstituted 1,2‐Dioxolanes under Mild Conditions through Indium(III) Chloride/Trimethylsilyl Chloride or Scandium(III) Triflate Catalysis

Herein we report the use of catalytic amount of scandium(III) triflate or indium(III) chloride (with trimethylsilyl chloride) for the functionalization of endoperoxyacetals through Sakurai or Mukaiyama reactions. These catalysts allow milder and more practical conditions than those previously report...

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Veröffentlicht in:	Advanced synthesis & catalysis 2020-03, Vol.362 (5), p.1190-1194
Hauptverfasser:	Pinet, Alexis, Figadère, Bruno, Ferrié, Laurent
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetal Catalysis Chemical Sciences Chloride Chlorides Indium Organic chemistry Peroxides Peroxycarbenium Rare-earths Scandium
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container_title	Advanced synthesis & catalysis
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creator	Pinet, Alexis Figadère, Bruno Ferrié, Laurent
description	Herein we report the use of catalytic amount of scandium(III) triflate or indium(III) chloride (with trimethylsilyl chloride) for the functionalization of endoperoxyacetals through Sakurai or Mukaiyama reactions. These catalysts allow milder and more practical conditions than those previously reported with improvements in scope and reproducibility. This method allows a full catalytic sequence from cyclopropanols to produce desired functionalized 1,2‐dioxolanes.
doi_str_mv	10.1002/adsc.201901145
format	Article
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subjects	Acetal Catalysis Chemical Sciences Chloride Chlorides Indium Organic chemistry Peroxides Peroxycarbenium Rare-earths Scandium
title	Access to Functionalized 3,5‐Disubstituted 1,2‐Dioxolanes under Mild Conditions through Indium(III) Chloride/Trimethylsilyl Chloride or Scandium(III) Triflate Catalysis
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