Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition

Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition

II–VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition meth...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Crystal growth & design 2017-12, Vol.17 (12), p.6303-6310
Hauptverfasser: Guia, Lluís M, Sallet, Vincent, Hassani, Said, Martínez-Tomás, M. Carmen, Muñoz-Sanjosé, Vicente
Format: Artikel
Sprache:eng
Schlagworte:
Physics
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 6310
container_issue 12
container_start_page 6303
container_title Crystal growth & design
container_volume 17
creator Guia, Lluís M
Sallet, Vincent
Hassani, Said
Martínez-Tomás, M. Carmen
Muñoz-Sanjosé, Vicente
description II–VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal–organic precursors content, a change from Mg1–x Cd x O (Mg-rich phase) to Cd1–x Mg x O (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron microscopy, a structural and morphological study of the samples has been carried out. In addition, the composition of the alloy has been measured by using energy dispersive X-ray analysis, and the behavior of the lattice parameter as a function of Cd content has been studied.
doi_str_mv 10.1021/acs.cgd.7b00989
format Article
fullrecord <record><control><sourceid>acs_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02972562v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b710570638</sourcerecordid><originalsourceid>FETCH-LOGICAL-a418t-b610f2a38db5112e7c24edf7735d0da9819056bce4b7473486c9401a2a84500a3</originalsourceid><addsrcrecordid>eNp1kM1OwzAQhCMEEqVw5uorQmlt58fOsQq0RWpVJArXyHGcxFUSR7YL6lvwyDht4cZpV7PfjLTjefcIThDEaMq4mfCqmJAcwoQmF94IRZj6JILR5e8e0uDauzFmByEkcRCMvO_nshTcAlWChVZftgZb0fZCM7vXAqgO2FqAN6v33AmsAawrwFrpvlaNqiR3yqtWjrdSmCFkXaXFBmxr2YG5bFpzTO1AfgBrYR290RXrJAdpLdqj_YP1SoMn0SsjrVTdrXdVssaIu_Mce-_z52269FebxUs6W_ksRNT6eYxgiVlAizxCCAvCcSiKkpAgKmDBEooSGMU5F2FOQhKENOZJCBHDjIYRhCwYew-n3Jo1Wa9ly_QhU0xmy9kqGzSIE4KjGH8ix05PLNfKGC3KPwOC2VB-5srPXPnZuXzneDw5hsNO7XXnfvmX_gH4Bog6</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition</title><source>American Chemical Society Journals</source><creator>Guia, Lluís M ; Sallet, Vincent ; Hassani, Said ; Martínez-Tomás, M. Carmen ; Muñoz-Sanjosé, Vicente</creator><creatorcontrib>Guia, Lluís M ; Sallet, Vincent ; Hassani, Said ; Martínez-Tomás, M. Carmen ; Muñoz-Sanjosé, Vicente</creatorcontrib><description>II–VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal–organic precursors content, a change from Mg1–x Cd x O (Mg-rich phase) to Cd1–x Mg x O (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron microscopy, a structural and morphological study of the samples has been carried out. In addition, the composition of the alloy has been measured by using energy dispersive X-ray analysis, and the behavior of the lattice parameter as a function of Cd content has been studied.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/acs.cgd.7b00989</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Physics</subject><ispartof>Crystal growth &amp; design, 2017-12, Vol.17 (12), p.6303-6310</ispartof><rights>Copyright © 2017 American Chemical Society</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a418t-b610f2a38db5112e7c24edf7735d0da9819056bce4b7473486c9401a2a84500a3</citedby><cites>FETCH-LOGICAL-a418t-b610f2a38db5112e7c24edf7735d0da9819056bce4b7473486c9401a2a84500a3</cites><orcidid>0000-0002-4404-4385 ; 0000-0003-0949-8397</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.cgd.7b00989$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.cgd.7b00989$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02972562$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Guia, Lluís M</creatorcontrib><creatorcontrib>Sallet, Vincent</creatorcontrib><creatorcontrib>Hassani, Said</creatorcontrib><creatorcontrib>Martínez-Tomás, M. Carmen</creatorcontrib><creatorcontrib>Muñoz-Sanjosé, Vicente</creatorcontrib><title>Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition</title><title>Crystal growth &amp; design</title><addtitle>Cryst. Growth Des</addtitle><description>II–VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal–organic precursors content, a change from Mg1–x Cd x O (Mg-rich phase) to Cd1–x Mg x O (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron microscopy, a structural and morphological study of the samples has been carried out. In addition, the composition of the alloy has been measured by using energy dispersive X-ray analysis, and the behavior of the lattice parameter as a function of Cd content has been studied.</description><subject>Physics</subject><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kM1OwzAQhCMEEqVw5uorQmlt58fOsQq0RWpVJArXyHGcxFUSR7YL6lvwyDht4cZpV7PfjLTjefcIThDEaMq4mfCqmJAcwoQmF94IRZj6JILR5e8e0uDauzFmByEkcRCMvO_nshTcAlWChVZftgZb0fZCM7vXAqgO2FqAN6v33AmsAawrwFrpvlaNqiR3yqtWjrdSmCFkXaXFBmxr2YG5bFpzTO1AfgBrYR290RXrJAdpLdqj_YP1SoMn0SsjrVTdrXdVssaIu_Mce-_z52269FebxUs6W_ksRNT6eYxgiVlAizxCCAvCcSiKkpAgKmDBEooSGMU5F2FOQhKENOZJCBHDjIYRhCwYew-n3Jo1Wa9ly_QhU0xmy9kqGzSIE4KjGH8ix05PLNfKGC3KPwOC2VB-5srPXPnZuXzneDw5hsNO7XXnfvmX_gH4Bog6</recordid><startdate>20171206</startdate><enddate>20171206</enddate><creator>Guia, Lluís M</creator><creator>Sallet, Vincent</creator><creator>Hassani, Said</creator><creator>Martínez-Tomás, M. Carmen</creator><creator>Muñoz-Sanjosé, Vicente</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-4404-4385</orcidid><orcidid>https://orcid.org/0000-0003-0949-8397</orcidid></search><sort><creationdate>20171206</creationdate><title>Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition</title><author>Guia, Lluís M ; Sallet, Vincent ; Hassani, Said ; Martínez-Tomás, M. Carmen ; Muñoz-Sanjosé, Vicente</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a418t-b610f2a38db5112e7c24edf7735d0da9819056bce4b7473486c9401a2a84500a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guia, Lluís M</creatorcontrib><creatorcontrib>Sallet, Vincent</creatorcontrib><creatorcontrib>Hassani, Said</creatorcontrib><creatorcontrib>Martínez-Tomás, M. Carmen</creatorcontrib><creatorcontrib>Muñoz-Sanjosé, Vicente</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Crystal growth &amp; design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guia, Lluís M</au><au>Sallet, Vincent</au><au>Hassani, Said</au><au>Martínez-Tomás, M. Carmen</au><au>Muñoz-Sanjosé, Vicente</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition</atitle><jtitle>Crystal growth &amp; design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2017-12-06</date><risdate>2017</risdate><volume>17</volume><issue>12</issue><spage>6303</spage><epage>6310</epage><pages>6303-6310</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>II–VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal–organic precursors content, a change from Mg1–x Cd x O (Mg-rich phase) to Cd1–x Mg x O (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron microscopy, a structural and morphological study of the samples has been carried out. In addition, the composition of the alloy has been measured by using energy dispersive X-ray analysis, and the behavior of the lattice parameter as a function of Cd content has been studied.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.cgd.7b00989</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-4404-4385</orcidid><orcidid>https://orcid.org/0000-0003-0949-8397</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1528-7483
ispartof Crystal growth & design, 2017-12, Vol.17 (12), p.6303-6310
issn 1528-7483
1528-7505
language eng
recordid cdi_hal_primary_oai_HAL_hal_02972562v1
source American Chemical Society Journals
subjects Physics
title Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T22%3A07%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effect%20of%20Growth%20Temperature%20on%20the%20Structural%20and%20Morphological%20Properties%20of%20MgCdO%20Thin%20Films%20Grown%20by%20Metal%20Organic%20Chemical%20Vapor%20Deposition&rft.jtitle=Crystal%20growth%20&%20design&rft.au=Guia,%20Llui%CC%81s%20M&rft.date=2017-12-06&rft.volume=17&rft.issue=12&rft.spage=6303&rft.epage=6310&rft.pages=6303-6310&rft.issn=1528-7483&rft.eissn=1528-7505&rft_id=info:doi/10.1021/acs.cgd.7b00989&rft_dat=%3Cacs_hal_p%3Eb710570638%3C/acs_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true