Probing the dynamics of Cu nanoparticle growth inside metal-organic frameworks upon electron beam irradiation
•In situ TEM allows observing the growth of NPs from constituent parts of MOFs.•The dynamic of the growth of NPs can be modeled by JMAK.•Tuning the e-beam parameters allows one to manipulate the NP diameter and rate of growth. Metal-organic frameworks (MOFs) represent a unique platform for fabricati...
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| Veröffentlicht in: | Photonics and nanostructures 2020-09, Vol.41, p.100832, Article 100832 |
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| creator | Mezenov, Yuri A. Bruyere, Stéphanie Kulachenkov, Nikita K. Yankin, Andrei N. Rzhevskiy, Sergey S. Alekseevskiy, Pavel V. Gilemkhanova, Venera D. Bachinin, Semyon V. Dyachuk, Vyacheslav Krasilin, Andrei A. Zollinger, Julien Belmonte, Thierry Nominé, Alexandre Milichko, Valentin A. |
| description | •In situ TEM allows observing the growth of NPs from constituent parts of MOFs.•The dynamic of the growth of NPs can be modeled by JMAK.•Tuning the e-beam parameters allows one to manipulate the NP diameter and rate of growth.
Metal-organic frameworks (MOFs) represent a unique platform for fabrication of nanoparticles (NPs) of diverse composition and crystallinity. The growth of NPs from constituent parts of MOFs is usually initiated by external stimuli such as temperature, light and electron irradiation. Herein, the kinetics and NP growth mechanisms remain unexplored. Here, we utilized electron irradiation to initiate the nucleation and growth of crystalline Cu NPs of tunable size from several nanometers to hundreds of nanometers inside MOF as a precursor. Simultaneously, the process of the NPs growth, captured in real time using transmission electron microscope, demonstrates the evolution of their size, shape and spatial distribution. We also analyze the NP growth by the classical kinetic theory taking into account a phase transformation. Our results contribute to crystal engineering and developing of functional MOF-based nanocomposites. |
| doi_str_mv | 10.1016/j.photonics.2020.100832 |
| format | Article |
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Metal-organic frameworks (MOFs) represent a unique platform for fabrication of nanoparticles (NPs) of diverse composition and crystallinity. The growth of NPs from constituent parts of MOFs is usually initiated by external stimuli such as temperature, light and electron irradiation. Herein, the kinetics and NP growth mechanisms remain unexplored. Here, we utilized electron irradiation to initiate the nucleation and growth of crystalline Cu NPs of tunable size from several nanometers to hundreds of nanometers inside MOF as a precursor. Simultaneously, the process of the NPs growth, captured in real time using transmission electron microscope, demonstrates the evolution of their size, shape and spatial distribution. We also analyze the NP growth by the classical kinetic theory taking into account a phase transformation. Our results contribute to crystal engineering and developing of functional MOF-based nanocomposites.</description><identifier>ISSN: 1569-4410</identifier><identifier>EISSN: 1569-4429</identifier><identifier>DOI: 10.1016/j.photonics.2020.100832</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Chemical Sciences ; Copper ; Crystal growth ; Crystal structure ; Crystallinity ; Electron beams ; Electron irradiation ; Electron microscopy ; Kinetic theory ; Material chemistry ; Metal-organic framework ; Metal-organic frameworks ; Nanocomposites ; Nanoparticles ; Nucleation ; Phase transitions ; Spatial distribution</subject><ispartof>Photonics and nanostructures, 2020-09, Vol.41, p.100832, Article 100832</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier Science Ltd. Sep 2020</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-d2ac3fd55a90072621b15cec81e64fa2aa2103ddfd18a943da3b72b376600e623</citedby><cites>FETCH-LOGICAL-c426t-d2ac3fd55a90072621b15cec81e64fa2aa2103ddfd18a943da3b72b376600e623</cites><orcidid>0000-0001-8061-7382 ; 0000-0001-7160-4520 ; 0000-0002-8572-7676 ; 0000-0001-9460-8727 ; 0000-0002-3938-3024 ; 0000-0003-0612-1260 ; 0000-0002-1101-282X ; 0000-0002-5553-3539 ; 0000-0002-8461-0804</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1569441020301607$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02944938$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Mezenov, Yuri A.</creatorcontrib><creatorcontrib>Bruyere, Stéphanie</creatorcontrib><creatorcontrib>Kulachenkov, Nikita K.</creatorcontrib><creatorcontrib>Yankin, Andrei N.</creatorcontrib><creatorcontrib>Rzhevskiy, Sergey S.</creatorcontrib><creatorcontrib>Alekseevskiy, Pavel V.</creatorcontrib><creatorcontrib>Gilemkhanova, Venera D.</creatorcontrib><creatorcontrib>Bachinin, Semyon V.</creatorcontrib><creatorcontrib>Dyachuk, Vyacheslav</creatorcontrib><creatorcontrib>Krasilin, Andrei A.</creatorcontrib><creatorcontrib>Zollinger, Julien</creatorcontrib><creatorcontrib>Belmonte, Thierry</creatorcontrib><creatorcontrib>Nominé, Alexandre</creatorcontrib><creatorcontrib>Milichko, Valentin A.</creatorcontrib><title>Probing the dynamics of Cu nanoparticle growth inside metal-organic frameworks upon electron beam irradiation</title><title>Photonics and nanostructures</title><description>•In situ TEM allows observing the growth of NPs from constituent parts of MOFs.•The dynamic of the growth of NPs can be modeled by JMAK.•Tuning the e-beam parameters allows one to manipulate the NP diameter and rate of growth.
Metal-organic frameworks (MOFs) represent a unique platform for fabrication of nanoparticles (NPs) of diverse composition and crystallinity. The growth of NPs from constituent parts of MOFs is usually initiated by external stimuli such as temperature, light and electron irradiation. Herein, the kinetics and NP growth mechanisms remain unexplored. Here, we utilized electron irradiation to initiate the nucleation and growth of crystalline Cu NPs of tunable size from several nanometers to hundreds of nanometers inside MOF as a precursor. Simultaneously, the process of the NPs growth, captured in real time using transmission electron microscope, demonstrates the evolution of their size, shape and spatial distribution. We also analyze the NP growth by the classical kinetic theory taking into account a phase transformation. 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Bruyere, Stéphanie ; Kulachenkov, Nikita K. ; Yankin, Andrei N. ; Rzhevskiy, Sergey S. ; Alekseevskiy, Pavel V. ; Gilemkhanova, Venera D. ; Bachinin, Semyon V. ; Dyachuk, Vyacheslav ; Krasilin, Andrei A. ; Zollinger, Julien ; Belmonte, Thierry ; Nominé, Alexandre ; Milichko, Valentin A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-d2ac3fd55a90072621b15cec81e64fa2aa2103ddfd18a943da3b72b376600e623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemical Sciences</topic><topic>Copper</topic><topic>Crystal growth</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Electron beams</topic><topic>Electron irradiation</topic><topic>Electron microscopy</topic><topic>Kinetic theory</topic><topic>Material chemistry</topic><topic>Metal-organic framework</topic><topic>Metal-organic frameworks</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Nucleation</topic><topic>Phase transitions</topic><topic>Spatial distribution</topic><toplevel>online_resources</toplevel><creatorcontrib>Mezenov, Yuri A.</creatorcontrib><creatorcontrib>Bruyere, Stéphanie</creatorcontrib><creatorcontrib>Kulachenkov, Nikita K.</creatorcontrib><creatorcontrib>Yankin, Andrei N.</creatorcontrib><creatorcontrib>Rzhevskiy, Sergey S.</creatorcontrib><creatorcontrib>Alekseevskiy, Pavel V.</creatorcontrib><creatorcontrib>Gilemkhanova, Venera D.</creatorcontrib><creatorcontrib>Bachinin, Semyon V.</creatorcontrib><creatorcontrib>Dyachuk, Vyacheslav</creatorcontrib><creatorcontrib>Krasilin, Andrei A.</creatorcontrib><creatorcontrib>Zollinger, Julien</creatorcontrib><creatorcontrib>Belmonte, Thierry</creatorcontrib><creatorcontrib>Nominé, Alexandre</creatorcontrib><creatorcontrib>Milichko, Valentin A.</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Photonics and nanostructures</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mezenov, Yuri A.</au><au>Bruyere, Stéphanie</au><au>Kulachenkov, Nikita K.</au><au>Yankin, Andrei N.</au><au>Rzhevskiy, Sergey S.</au><au>Alekseevskiy, Pavel V.</au><au>Gilemkhanova, Venera D.</au><au>Bachinin, Semyon V.</au><au>Dyachuk, Vyacheslav</au><au>Krasilin, Andrei A.</au><au>Zollinger, Julien</au><au>Belmonte, Thierry</au><au>Nominé, Alexandre</au><au>Milichko, Valentin A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Probing the dynamics of Cu nanoparticle growth inside metal-organic frameworks upon electron beam irradiation</atitle><jtitle>Photonics and nanostructures</jtitle><date>2020-09</date><risdate>2020</risdate><volume>41</volume><spage>100832</spage><pages>100832-</pages><artnum>100832</artnum><issn>1569-4410</issn><eissn>1569-4429</eissn><abstract>•In situ TEM allows observing the growth of NPs from constituent parts of MOFs.•The dynamic of the growth of NPs can be modeled by JMAK.•Tuning the e-beam parameters allows one to manipulate the NP diameter and rate of growth.
Metal-organic frameworks (MOFs) represent a unique platform for fabrication of nanoparticles (NPs) of diverse composition and crystallinity. The growth of NPs from constituent parts of MOFs is usually initiated by external stimuli such as temperature, light and electron irradiation. Herein, the kinetics and NP growth mechanisms remain unexplored. Here, we utilized electron irradiation to initiate the nucleation and growth of crystalline Cu NPs of tunable size from several nanometers to hundreds of nanometers inside MOF as a precursor. Simultaneously, the process of the NPs growth, captured in real time using transmission electron microscope, demonstrates the evolution of their size, shape and spatial distribution. We also analyze the NP growth by the classical kinetic theory taking into account a phase transformation. Our results contribute to crystal engineering and developing of functional MOF-based nanocomposites.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.photonics.2020.100832</doi><orcidid>https://orcid.org/0000-0001-8061-7382</orcidid><orcidid>https://orcid.org/0000-0001-7160-4520</orcidid><orcidid>https://orcid.org/0000-0002-8572-7676</orcidid><orcidid>https://orcid.org/0000-0001-9460-8727</orcidid><orcidid>https://orcid.org/0000-0002-3938-3024</orcidid><orcidid>https://orcid.org/0000-0003-0612-1260</orcidid><orcidid>https://orcid.org/0000-0002-1101-282X</orcidid><orcidid>https://orcid.org/0000-0002-5553-3539</orcidid><orcidid>https://orcid.org/0000-0002-8461-0804</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Chemical Sciences Copper Crystal growth Crystal structure Crystallinity Electron beams Electron irradiation Electron microscopy Kinetic theory Material chemistry Metal-organic framework Metal-organic frameworks Nanocomposites Nanoparticles Nucleation Phase transitions Spatial distribution |
| title | Probing the dynamics of Cu nanoparticle growth inside metal-organic frameworks upon electron beam irradiation |
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