Luminescent Neutral Platinum Complexes Bearing an Asymmetric N^N^N Ligand for High-Performance Solution-Processed OLEDs

The synthesis and full characterization of new platinum complexes bearing a bulky asymmetric dianionic tridentate ligand is reported. The hindrance of the ligand prevents detrimental intermolecular interactions yielding to highly emitting species in both crystalline state and thin‐film. Such propert...

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Veröffentlicht in:Advanced materials (Weinheim) 2013-01, Vol.25 (3), p.437-442
Hauptverfasser: Cebrián, Cristina, Mauro, Matteo, Kourkoulos, Dimitrios, Mercandelli, Pierluigi, Hertel, Dirk, Meerholz, Klaus, Strassert, Cristian A., De Cola, Luisa
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container_end_page 442
container_issue 3
container_start_page 437
container_title Advanced materials (Weinheim)
container_volume 25
creator Cebrián, Cristina
Mauro, Matteo
Kourkoulos, Dimitrios
Mercandelli, Pierluigi
Hertel, Dirk
Meerholz, Klaus
Strassert, Cristian A.
De Cola, Luisa
description The synthesis and full characterization of new platinum complexes bearing a bulky asymmetric dianionic tridentate ligand is reported. The hindrance of the ligand prevents detrimental intermolecular interactions yielding to highly emitting species in both crystalline state and thin‐film. Such properties prompted their successful use in solution‐processed OLEDs, showing remarkable external quantum efficiency up to 5.6%.
doi_str_mv 10.1002/adma.201202123
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subjects asymmetric
Chemical Sciences
Coordination chemistry
luminescence
Material chemistry
OLED
or physical chemistry
Organic chemistry
Physics
platinum complexes
Theoretical and
tridentate ligand
title Luminescent Neutral Platinum Complexes Bearing an Asymmetric N^N^N Ligand for High-Performance Solution-Processed OLEDs
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