Structural and spectroscopic investigations of nine-coordinate redox active lanthanide complexes with a pincer O,N,O ligand

The lanthanide complexes EuL 3 , GdL 3 , YbL 3 and LuL 3 of the N , N ′-bis(2-hydroxy-di-3,5- tert -butylphenyl)amine were prepared. The X-Ray crystal structures of GdL 3 and LuL 3 demonstrated a nine-coordinate sphere with three ligand molecules under their anionic diamagnetic form (Cat-N-BQ) − . T...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-06, Vol.49 (24), p.8238-8246
Hauptverfasser:	Mouchel Dit Leguerrier, D, Barré, R, Bryden, M, Imbert, D, Philouze, C, Jarjayes, O, Luneau, D, Molloy, J. K, Thomas, F
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Antiferromagnetism Chemical Sciences Coordination chemistry Cristallography Crystal structure Crystallography Diamagnetism Gadolinium Ligands Oxidation
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