Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds
One and two: The C2 compound pinBOCH2OCHO (see scheme; HBpin=pinacolborane) and several C1 compounds have been obtained from the borane‐mediated reduction of CO2 under mild conditions with the catalyst precursor [RuH2(H2)2(PCy3)2]. Mechanistic investigation highlights the role of a series of new car...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-02, Vol.51 (7), p.1671-1674 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Bontemps, Sébastien Vendier, Laure Sabo-Etienne, Sylviane |
| description | One and two: The C2 compound pinBOCH2OCHO (see scheme; HBpin=pinacolborane) and several C1 compounds have been obtained from the borane‐mediated reduction of CO2 under mild conditions with the catalyst precursor [RuH2(H2)2(PCy3)2]. Mechanistic investigation highlights the role of a series of new carbonyl ruthenium complexes that were characterized by multinuclear NMR spectroscopy, IR spectroscopy, and X‐ray diffraction studies. |
| doi_str_mv | 10.1002/anie.201107352 |
| format | Article |
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Mechanistic investigation highlights the role of a series of new carbonyl ruthenium complexes that were characterized by multinuclear NMR spectroscopy, IR spectroscopy, and X‐ray diffraction studies.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201107352</identifier><identifier>PMID: 22241554</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Boranes ; Boranes - chemistry ; Carbon dioxide ; Carbon Dioxide - chemistry ; Carbonyl compounds ; Carbonyls ; catalysis ; Chemical Sciences ; Coordination chemistry ; Crystallography, X-Ray ; hydride ligands ; Infrared spectroscopy ; Magnetic resonance spectroscopy ; Models, Molecular ; Molecular Structure ; NMR spectroscopy ; Organometallic Compounds - chemistry ; Oxidation-Reduction ; Ruthenium ; Ruthenium - chemistry ; Ruthenium compounds ; X-ray diffraction</subject><ispartof>Angewandte Chemie International Edition, 2012-02, Vol.51 (7), p.1671-1674</ispartof><rights>Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. 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Chem. Int. Ed</addtitle><description>One and two: The C2 compound pinBOCH2OCHO (see scheme; HBpin=pinacolborane) and several C1 compounds have been obtained from the borane‐mediated reduction of CO2 under mild conditions with the catalyst precursor [RuH2(H2)2(PCy3)2]. Mechanistic investigation highlights the role of a series of new carbonyl ruthenium complexes that were characterized by multinuclear NMR spectroscopy, IR spectroscopy, and X‐ray diffraction studies.</description><subject>Boranes</subject><subject>Boranes - chemistry</subject><subject>Carbon dioxide</subject><subject>Carbon Dioxide - chemistry</subject><subject>Carbonyl compounds</subject><subject>Carbonyls</subject><subject>catalysis</subject><subject>Chemical Sciences</subject><subject>Coordination chemistry</subject><subject>Crystallography, X-Ray</subject><subject>hydride ligands</subject><subject>Infrared spectroscopy</subject><subject>Magnetic resonance spectroscopy</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>NMR spectroscopy</subject><subject>Organometallic Compounds - chemistry</subject><subject>Oxidation-Reduction</subject><subject>Ruthenium</subject><subject>Ruthenium - chemistry</subject><subject>Ruthenium compounds</subject><subject>X-ray diffraction</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kc1v1DAQxS0EoqVw5YgicUAc0nrG8Ue4LaHtttoWqQL1aNmxV-uSxEs-oP3v8bIlhx442X7ze_aMHyFvgR4DpXhiuuCPkQJQyTg-I4fAEXImJXue9gVjuVQcDsirYbhLvFJUvCQHiFgA58Uhuf0ce9P5_Mq7YEbvssr0NnbZlxDvg_PZjXdTPYakmDG7mcaN78LUfsrOYt-av3pcZxVkpktWzKrYbuPUueE1ebE2zeDfPK5H5PvZ6bdqma--nl9Ui1W-YarA3K0VZcxaURZOFt6ZWrlape6tERKlLQVVprbSOuSyRmCSYS3BG0EtMOPYEfm4v3djGr3tQ2v6Bx1N0MvFSu80iiUtC5C_ILEf9uy2jz8nP4y6DUPtmyZ9QJwGXSJlQmCJiXz_hLyLU9-lQTQDhlSVAv5LAQchaYFCJurdIzXZ1ru5yX8ZJKDcA79D4x_mOlC9S1jvEtZzwnpxfXE6n5I333vDMPr72Wv6Hzo9Lbm-vT7XcMmvFIilvmR_AAzRpF4</recordid><startdate>20120213</startdate><enddate>20120213</enddate><creator>Bontemps, Sébastien</creator><creator>Vendier, Laure</creator><creator>Sabo-Etienne, Sylviane</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-7111-9258</orcidid><orcidid>https://orcid.org/0000-0002-4950-9452</orcidid></search><sort><creationdate>20120213</creationdate><title>Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds</title><author>Bontemps, Sébastien ; Vendier, Laure ; Sabo-Etienne, Sylviane</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-h3842-df8033bb694d74edac8dc8773ba6727b9608acb7bd257c213732c71ea60b13ad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Boranes</topic><topic>Boranes - chemistry</topic><topic>Carbon dioxide</topic><topic>Carbon Dioxide - chemistry</topic><topic>Carbonyl compounds</topic><topic>Carbonyls</topic><topic>catalysis</topic><topic>Chemical Sciences</topic><topic>Coordination chemistry</topic><topic>Crystallography, X-Ray</topic><topic>hydride ligands</topic><topic>Infrared spectroscopy</topic><topic>Magnetic resonance spectroscopy</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>NMR spectroscopy</topic><topic>Organometallic Compounds - chemistry</topic><topic>Oxidation-Reduction</topic><topic>Ruthenium</topic><topic>Ruthenium - chemistry</topic><topic>Ruthenium compounds</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bontemps, Sébastien</creatorcontrib><creatorcontrib>Vendier, Laure</creatorcontrib><creatorcontrib>Sabo-Etienne, Sylviane</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bontemps, Sébastien</au><au>Vendier, Laure</au><au>Sabo-Etienne, Sylviane</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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| ispartof | Angewandte Chemie International Edition, 2012-02, Vol.51 (7), p.1671-1674 |
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| source | Wiley-Blackwell Journals; MEDLINE |
| subjects | Boranes Boranes - chemistry Carbon dioxide Carbon Dioxide - chemistry Carbonyl compounds Carbonyls catalysis Chemical Sciences Coordination chemistry Crystallography, X-Ray hydride ligands Infrared spectroscopy Magnetic resonance spectroscopy Models, Molecular Molecular Structure NMR spectroscopy Organometallic Compounds - chemistry Oxidation-Reduction Ruthenium Ruthenium - chemistry Ruthenium compounds X-ray diffraction |
| title | Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds |
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