Moisture sorption behaviour of jatropha seed ( Jatropha curcas) as a source of vegetable oil for biodiesel production
This research studied the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. Two sets of sorption-isotherm experiment were pe...
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description | This research studied the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. Two sets of sorption-isotherm experiment were performed to describe the relationship between EMC and FFA content with water activity, for both fresh and dried seeds. The seeds were conditioned in series of saturated salts having certain water activity and stored at different temperatures (20, 30, 40 °C). The nested experimental design and ANOVA (F-test at
p = 0.05) were applied to study the effects of temperature and water activity on the EMC of jatropha seed.
EMC increased generally with the increase in water activity and with the decrease in temperature at either desorption or adsorption. The EMC was significantly affected by water activity, but the temperature did not significantly affect the EMC. The hysteresis effect was more pronounced at lower temperatures. The FFA content of seed was relatively constant at low water activity (a
w |
doi_str_mv | 10.1016/j.biombioe.2011.10.026 |
format | Article |
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p = 0.05) were applied to study the effects of temperature and water activity on the EMC of jatropha seed.
EMC increased generally with the increase in water activity and with the decrease in temperature at either desorption or adsorption. The EMC was significantly affected by water activity, but the temperature did not significantly affect the EMC. The hysteresis effect was more pronounced at lower temperatures. The FFA content of seed was relatively constant at low water activity (a
w < 0.8), but it was high at higher water activity.
The moisture sorption behaviour of jatropha seed revealed that like most product, it exhibited the sigmoid pattern. The BET, GAB, Harkins-Jura, Halsey and Henderson models were recommended as adequate models in predicting the amount of moisture adsorbed or desorbed at known humidity. The relationship between EMC and FFA content of jatropha seed showed that the polynomial equation was the best fitting for either fresh or dried seed.
► We study the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. ► We examine the influences of temperature and water activity on the EMC of jatropha seed. ► Increasing water activity will increase the EMC of jatropha seed. ► We recommend the BET, GAB, Harkins-Jura, Halsey and Henderson models as adequate models in predicting the amount of moisture adsorbed or desorbed at known humidity. ► The polynomial equation is the best fitting for the relationship between EMC and FFA content of jatropha seed.</description><identifier>ISSN: 0961-9534</identifier><identifier>EISSN: 1873-2909</identifier><identifier>DOI: 10.1016/j.biombioe.2011.10.026</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Adsorption ; Agronomy. Soil science and plant productions ; analysis of variance ; Biodiesel ; Biological and medical sciences ; Chemical and Process Engineering ; desorption ; Economic plant physiology ; Engineering Sciences ; Equilibrium moisture content ; experimental design ; Food engineering ; free fatty acids ; Fundamental and applied biological sciences. Psychology ; Generalities and techniques ; humidity ; hysteresis ; Jatropha curcas ; Jatropha seed ; Life Sciences ; salts ; seeds ; Sorption isotherm ; vegetable oil ; Water activity ; water content ; water temperature</subject><ispartof>Biomass & bioenergy, 2012, Vol.36, p.226-233</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c432t-bab176de90a523776b40a0f64e363585c9f1c2b8bd8dbf80ef7fb1e3c4c549543</citedby><cites>FETCH-LOGICAL-c432t-bab176de90a523776b40a0f64e363585c9f1c2b8bd8dbf80ef7fb1e3c4c549543</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.biombioe.2011.10.026$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,4024,27923,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25455434$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.inrae.fr/hal-02645226$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Kartika, I. Amalia</creatorcontrib><creatorcontrib>Yuliani, S.</creatorcontrib><creatorcontrib>Kailaku, S.I.</creatorcontrib><creatorcontrib>Rigal, L.</creatorcontrib><title>Moisture sorption behaviour of jatropha seed ( Jatropha curcas) as a source of vegetable oil for biodiesel production</title><title>Biomass & bioenergy</title><description>This research studied the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. Two sets of sorption-isotherm experiment were performed to describe the relationship between EMC and FFA content with water activity, for both fresh and dried seeds. The seeds were conditioned in series of saturated salts having certain water activity and stored at different temperatures (20, 30, 40 °C). The nested experimental design and ANOVA (F-test at
p = 0.05) were applied to study the effects of temperature and water activity on the EMC of jatropha seed.
EMC increased generally with the increase in water activity and with the decrease in temperature at either desorption or adsorption. The EMC was significantly affected by water activity, but the temperature did not significantly affect the EMC. The hysteresis effect was more pronounced at lower temperatures. The FFA content of seed was relatively constant at low water activity (a
w < 0.8), but it was high at higher water activity.
The moisture sorption behaviour of jatropha seed revealed that like most product, it exhibited the sigmoid pattern. The BET, GAB, Harkins-Jura, Halsey and Henderson models were recommended as adequate models in predicting the amount of moisture adsorbed or desorbed at known humidity. The relationship between EMC and FFA content of jatropha seed showed that the polynomial equation was the best fitting for either fresh or dried seed.
► We study the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. ► We examine the influences of temperature and water activity on the EMC of jatropha seed. ► Increasing water activity will increase the EMC of jatropha seed. ► We recommend the BET, GAB, Harkins-Jura, Halsey and Henderson models as adequate models in predicting the amount of moisture adsorbed or desorbed at known humidity. ► The polynomial equation is the best fitting for the relationship between EMC and FFA content of jatropha seed.</description><subject>Adsorption</subject><subject>Agronomy. Soil science and plant productions</subject><subject>analysis of variance</subject><subject>Biodiesel</subject><subject>Biological and medical sciences</subject><subject>Chemical and Process Engineering</subject><subject>desorption</subject><subject>Economic plant physiology</subject><subject>Engineering Sciences</subject><subject>Equilibrium moisture content</subject><subject>experimental design</subject><subject>Food engineering</subject><subject>free fatty acids</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Generalities and techniques</subject><subject>humidity</subject><subject>hysteresis</subject><subject>Jatropha curcas</subject><subject>Jatropha seed</subject><subject>Life Sciences</subject><subject>salts</subject><subject>seeds</subject><subject>Sorption isotherm</subject><subject>vegetable oil</subject><subject>Water activity</subject><subject>water content</subject><subject>water temperature</subject><issn>0961-9534</issn><issn>1873-2909</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkcFu1DAQhiMEEkvhFcAXRHvYZezYTnKjqoCCFnGAnq2xM-56lV0vdrISb4-jtL1ysKyZ-Wbm1_xV9ZbDhgPXH_cbG-KhPNoI4LwkNyD0s2rF26Zeiw6659UKOs3Xnarly-pVznsALkHyVTX9iCGPUyKWYzqNIR6ZpR2eQ5wSi57tcUzxtEOWiXp2yb4_xm5KDvMVw8xKsdCOZv5M9zSiHUoQBuZjYkVYHyjTwE4p9pObd7yuXngcMr15-C-quy-ff9_crrc_v367ud6unazFuLZoeaN76gCVqJtGWwkIXkuqda1a5TrPnbCt7dve-hbIN95yqp10SnZK1hfV1TJ3h4M5pXDA9NdEDOb2emvmXDmUVELoMy_sh4UtMv9MlEdzCNnRMOCR4pRNJ6DpoFF1IfVCuhRzTuSfRnMwsyVmbx4tMbMlc75sKo3vH1Zgdjj4hEcX8lO3UFIV0bPsdwvnMRq8T4W5-yVmywCkbmEmPi0EleudAyWTXaCjoz4kcqPpY_ifmH9sta8G</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>Kartika, I. Amalia</creator><creator>Yuliani, S.</creator><creator>Kailaku, S.I.</creator><creator>Rigal, L.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7U6</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>1XC</scope></search><sort><creationdate>2012</creationdate><title>Moisture sorption behaviour of jatropha seed ( Jatropha curcas) as a source of vegetable oil for biodiesel production</title><author>Kartika, I. Amalia ; Yuliani, S. ; Kailaku, S.I. ; Rigal, L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c432t-bab176de90a523776b40a0f64e363585c9f1c2b8bd8dbf80ef7fb1e3c4c549543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Adsorption</topic><topic>Agronomy. Soil science and plant productions</topic><topic>analysis of variance</topic><topic>Biodiesel</topic><topic>Biological and medical sciences</topic><topic>Chemical and Process Engineering</topic><topic>desorption</topic><topic>Economic plant physiology</topic><topic>Engineering Sciences</topic><topic>Equilibrium moisture content</topic><topic>experimental design</topic><topic>Food engineering</topic><topic>free fatty acids</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Generalities and techniques</topic><topic>humidity</topic><topic>hysteresis</topic><topic>Jatropha curcas</topic><topic>Jatropha seed</topic><topic>Life Sciences</topic><topic>salts</topic><topic>seeds</topic><topic>Sorption isotherm</topic><topic>vegetable oil</topic><topic>Water activity</topic><topic>water content</topic><topic>water temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kartika, I. Amalia</creatorcontrib><creatorcontrib>Yuliani, S.</creatorcontrib><creatorcontrib>Kailaku, S.I.</creatorcontrib><creatorcontrib>Rigal, L.</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Biomass & bioenergy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kartika, I. Amalia</au><au>Yuliani, S.</au><au>Kailaku, S.I.</au><au>Rigal, L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Moisture sorption behaviour of jatropha seed ( Jatropha curcas) as a source of vegetable oil for biodiesel production</atitle><jtitle>Biomass & bioenergy</jtitle><date>2012</date><risdate>2012</risdate><volume>36</volume><spage>226</spage><epage>233</epage><pages>226-233</pages><issn>0961-9534</issn><eissn>1873-2909</eissn><abstract>This research studied the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. Two sets of sorption-isotherm experiment were performed to describe the relationship between EMC and FFA content with water activity, for both fresh and dried seeds. The seeds were conditioned in series of saturated salts having certain water activity and stored at different temperatures (20, 30, 40 °C). The nested experimental design and ANOVA (F-test at
p = 0.05) were applied to study the effects of temperature and water activity on the EMC of jatropha seed.
EMC increased generally with the increase in water activity and with the decrease in temperature at either desorption or adsorption. The EMC was significantly affected by water activity, but the temperature did not significantly affect the EMC. The hysteresis effect was more pronounced at lower temperatures. The FFA content of seed was relatively constant at low water activity (a
w < 0.8), but it was high at higher water activity.
The moisture sorption behaviour of jatropha seed revealed that like most product, it exhibited the sigmoid pattern. The BET, GAB, Harkins-Jura, Halsey and Henderson models were recommended as adequate models in predicting the amount of moisture adsorbed or desorbed at known humidity. The relationship between EMC and FFA content of jatropha seed showed that the polynomial equation was the best fitting for either fresh or dried seed.
► We study the moisture sorption behaviour of jatropha seed allowing the development of a model correlating the equilibrium moisture content (EMC) and the free fatty acids (FFA) content as a function of water activity and EMC, respectively. ► We examine the influences of temperature and water activity on the EMC of jatropha seed. ► Increasing water activity will increase the EMC of jatropha seed. ► We recommend the BET, GAB, Harkins-Jura, Halsey and Henderson models as adequate models in predicting the amount of moisture adsorbed or desorbed at known humidity. ► The polynomial equation is the best fitting for the relationship between EMC and FFA content of jatropha seed.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.biombioe.2011.10.026</doi><tpages>8</tpages></addata></record> |
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subjects | Adsorption Agronomy. Soil science and plant productions analysis of variance Biodiesel Biological and medical sciences Chemical and Process Engineering desorption Economic plant physiology Engineering Sciences Equilibrium moisture content experimental design Food engineering free fatty acids Fundamental and applied biological sciences. Psychology Generalities and techniques humidity hysteresis Jatropha curcas Jatropha seed Life Sciences salts seeds Sorption isotherm vegetable oil Water activity water content water temperature |
title | Moisture sorption behaviour of jatropha seed ( Jatropha curcas) as a source of vegetable oil for biodiesel production |
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