Influence of Conversion Material Morphology on Electrochemistry Studied with Operando X-Ray Tomography and Diffraction
X‐ray diffraction and X‐ray tomography are performed on intermetallic particles undergoing lithiation in a porous electrode. Differences between ensemble phase evolution and that at a single‐particle level are explored. It is found that all particles evidence core–shell lithiation; however, particle...
Gespeichert in:
| Veröffentlicht in: | Advanced materials (Weinheim) 2015-03, Vol.27 (10), p.1676-1681 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1681 |
|---|---|
| container_issue | 10 |
| container_start_page | 1676 |
| container_title | Advanced materials (Weinheim) |
| container_volume | 27 |
| creator | Villevieille, Claire Ebner, Martin Gómez-Cámer, Juan Luis Marone, Federica Novák, Petr Wood, Vanessa |
| description | X‐ray diffraction and X‐ray tomography are performed on intermetallic particles undergoing lithiation in a porous electrode. Differences between ensemble phase evolution and that at a single‐particle level are explored. It is found that all particles evidence core–shell lithiation; however, particles with internal porosity are more mechanically robust and exhibit less fracture. |
| doi_str_mv | 10.1002/adma.201403792 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02619032v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1677948244</sourcerecordid><originalsourceid>FETCH-LOGICAL-c5482-fc97fbb6a392630186bfcab2f95d9aa3c3af299a5dfd2e6fdbf280d6a5631b363</originalsourceid><addsrcrecordid>eNqNkc9v0zAcxSMEYmVw5YgscRmHFP-InfhYtds6qWWIjR836xvHXjOSODhJR_57XGVUiAucLD193tP7-kXRa4LnBGP6Hooa5hSTBLNU0ifRjHBK4gRL_jSaYcl4LEWSnUQvuu4eYywFFs-jE8oFkYRns2h_1dhqMI02yFm0dM3e-K50DdpCb3wJFdo63-5c5e5GFOTzyujeO70zddn1fkQ3_VCUpkAPZb9D163x0BQOfYs_wYhuXe3uPLS7EQUVrUprPeg-xL-MnlmoOvPq8T2NPl-c3y7X8eb68mq52MSaJxmNrZapzXMBTFLBMMlEbjXk1EpeSACmGVgqJfDCFtQIW-SWZrgQwAUjORPsNHo35e6gUq0va_CjclCq9WKjDhqm4Scwo3sS2LOJbb37MZiuV-FEbaoKGuOGThGRpjK0SpL_QAVNQhOMA_r2L_TeDb4JRyuaEs5lQtIsUPOJ0t51nTf2WJZgdRhaHYZWx6GD4c1j7JDXpjjiv5cNgJyAh7Iy4z_i1GK1XfwZHk_eMLH5efSC_65EylKuvn64VOTjl5vVZnWh1uwXR-TELA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2715594178</pqid></control><display><type>article</type><title>Influence of Conversion Material Morphology on Electrochemistry Studied with Operando X-Ray Tomography and Diffraction</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Villevieille, Claire ; Ebner, Martin ; Gómez-Cámer, Juan Luis ; Marone, Federica ; Novák, Petr ; Wood, Vanessa</creator><creatorcontrib>Villevieille, Claire ; Ebner, Martin ; Gómez-Cámer, Juan Luis ; Marone, Federica ; Novák, Petr ; Wood, Vanessa</creatorcontrib><description>X‐ray diffraction and X‐ray tomography are performed on intermetallic particles undergoing lithiation in a porous electrode. Differences between ensemble phase evolution and that at a single‐particle level are explored. It is found that all particles evidence core–shell lithiation; however, particles with internal porosity are more mechanically robust and exhibit less fracture.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.201403792</identifier><identifier>PMID: 25619158</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Chemical Sciences ; Conversion ; conversion reactions ; Diffraction ; Electric power ; Electrochemistry ; Electrodes ; Engineering Sciences ; Evolution ; Fracture mechanics ; Li-ion batteries ; Material chemistry ; operando X-ray tomography and diffraction ; particles fractures ; Porosity ; Tomography ; X-rays</subject><ispartof>Advanced materials (Weinheim), 2015-03, Vol.27 (10), p.1676-1681</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5482-fc97fbb6a392630186bfcab2f95d9aa3c3af299a5dfd2e6fdbf280d6a5631b363</citedby><cites>FETCH-LOGICAL-c5482-fc97fbb6a392630186bfcab2f95d9aa3c3af299a5dfd2e6fdbf280d6a5631b363</cites><orcidid>0000-0001-8782-4800 ; 0000-0001-5789-5296 ; 0000-0002-3467-8763 ; 0000-0001-6435-0227</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.201403792$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.201403792$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,778,782,883,1414,27907,27908,45557,45558</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25619158$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02619032$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Villevieille, Claire</creatorcontrib><creatorcontrib>Ebner, Martin</creatorcontrib><creatorcontrib>Gómez-Cámer, Juan Luis</creatorcontrib><creatorcontrib>Marone, Federica</creatorcontrib><creatorcontrib>Novák, Petr</creatorcontrib><creatorcontrib>Wood, Vanessa</creatorcontrib><title>Influence of Conversion Material Morphology on Electrochemistry Studied with Operando X-Ray Tomography and Diffraction</title><title>Advanced materials (Weinheim)</title><addtitle>Adv. Mater</addtitle><description>X‐ray diffraction and X‐ray tomography are performed on intermetallic particles undergoing lithiation in a porous electrode. Differences between ensemble phase evolution and that at a single‐particle level are explored. It is found that all particles evidence core–shell lithiation; however, particles with internal porosity are more mechanically robust and exhibit less fracture.</description><subject>Chemical Sciences</subject><subject>Conversion</subject><subject>conversion reactions</subject><subject>Diffraction</subject><subject>Electric power</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Engineering Sciences</subject><subject>Evolution</subject><subject>Fracture mechanics</subject><subject>Li-ion batteries</subject><subject>Material chemistry</subject><subject>operando X-ray tomography and diffraction</subject><subject>particles fractures</subject><subject>Porosity</subject><subject>Tomography</subject><subject>X-rays</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkc9v0zAcxSMEYmVw5YgscRmHFP-InfhYtds6qWWIjR836xvHXjOSODhJR_57XGVUiAucLD193tP7-kXRa4LnBGP6Hooa5hSTBLNU0ifRjHBK4gRL_jSaYcl4LEWSnUQvuu4eYywFFs-jE8oFkYRns2h_1dhqMI02yFm0dM3e-K50DdpCb3wJFdo63-5c5e5GFOTzyujeO70zddn1fkQ3_VCUpkAPZb9D163x0BQOfYs_wYhuXe3uPLS7EQUVrUprPeg-xL-MnlmoOvPq8T2NPl-c3y7X8eb68mq52MSaJxmNrZapzXMBTFLBMMlEbjXk1EpeSACmGVgqJfDCFtQIW-SWZrgQwAUjORPsNHo35e6gUq0va_CjclCq9WKjDhqm4Scwo3sS2LOJbb37MZiuV-FEbaoKGuOGThGRpjK0SpL_QAVNQhOMA_r2L_TeDb4JRyuaEs5lQtIsUPOJ0t51nTf2WJZgdRhaHYZWx6GD4c1j7JDXpjjiv5cNgJyAh7Iy4z_i1GK1XfwZHk_eMLH5efSC_65EylKuvn64VOTjl5vVZnWh1uwXR-TELA</recordid><startdate>20150301</startdate><enddate>20150301</enddate><creator>Villevieille, Claire</creator><creator>Ebner, Martin</creator><creator>Gómez-Cámer, Juan Luis</creator><creator>Marone, Federica</creator><creator>Novák, Petr</creator><creator>Wood, Vanessa</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-8782-4800</orcidid><orcidid>https://orcid.org/0000-0001-5789-5296</orcidid><orcidid>https://orcid.org/0000-0002-3467-8763</orcidid><orcidid>https://orcid.org/0000-0001-6435-0227</orcidid></search><sort><creationdate>20150301</creationdate><title>Influence of Conversion Material Morphology on Electrochemistry Studied with Operando X-Ray Tomography and Diffraction</title><author>Villevieille, Claire ; Ebner, Martin ; Gómez-Cámer, Juan Luis ; Marone, Federica ; Novák, Petr ; Wood, Vanessa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5482-fc97fbb6a392630186bfcab2f95d9aa3c3af299a5dfd2e6fdbf280d6a5631b363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemical Sciences</topic><topic>Conversion</topic><topic>conversion reactions</topic><topic>Diffraction</topic><topic>Electric power</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Engineering Sciences</topic><topic>Evolution</topic><topic>Fracture mechanics</topic><topic>Li-ion batteries</topic><topic>Material chemistry</topic><topic>operando X-ray tomography and diffraction</topic><topic>particles fractures</topic><topic>Porosity</topic><topic>Tomography</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Villevieille, Claire</creatorcontrib><creatorcontrib>Ebner, Martin</creatorcontrib><creatorcontrib>Gómez-Cámer, Juan Luis</creatorcontrib><creatorcontrib>Marone, Federica</creatorcontrib><creatorcontrib>Novák, Petr</creatorcontrib><creatorcontrib>Wood, Vanessa</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Villevieille, Claire</au><au>Ebner, Martin</au><au>Gómez-Cámer, Juan Luis</au><au>Marone, Federica</au><au>Novák, Petr</au><au>Wood, Vanessa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of Conversion Material Morphology on Electrochemistry Studied with Operando X-Ray Tomography and Diffraction</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv. Mater</addtitle><date>2015-03-01</date><risdate>2015</risdate><volume>27</volume><issue>10</issue><spage>1676</spage><epage>1681</epage><pages>1676-1681</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>X‐ray diffraction and X‐ray tomography are performed on intermetallic particles undergoing lithiation in a porous electrode. Differences between ensemble phase evolution and that at a single‐particle level are explored. It is found that all particles evidence core–shell lithiation; however, particles with internal porosity are more mechanically robust and exhibit less fracture.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>25619158</pmid><doi>10.1002/adma.201403792</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-8782-4800</orcidid><orcidid>https://orcid.org/0000-0001-5789-5296</orcidid><orcidid>https://orcid.org/0000-0002-3467-8763</orcidid><orcidid>https://orcid.org/0000-0001-6435-0227</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0935-9648 |
| ispartof | Advanced materials (Weinheim), 2015-03, Vol.27 (10), p.1676-1681 |
| issn | 0935-9648 1521-4095 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_02619032v1 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemical Sciences Conversion conversion reactions Diffraction Electric power Electrochemistry Electrodes Engineering Sciences Evolution Fracture mechanics Li-ion batteries Material chemistry operando X-ray tomography and diffraction particles fractures Porosity Tomography X-rays |
| title | Influence of Conversion Material Morphology on Electrochemistry Studied with Operando X-Ray Tomography and Diffraction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T21%3A45%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Influence%20of%20Conversion%20Material%20Morphology%20on%20Electrochemistry%20Studied%20with%20Operando%20X-Ray%20Tomography%20and%20Diffraction&rft.jtitle=Advanced%20materials%20(Weinheim)&rft.au=Villevieille,%20Claire&rft.date=2015-03-01&rft.volume=27&rft.issue=10&rft.spage=1676&rft.epage=1681&rft.pages=1676-1681&rft.issn=0935-9648&rft.eissn=1521-4095&rft_id=info:doi/10.1002/adma.201403792&rft_dat=%3Cproquest_hal_p%3E1677948244%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2715594178&rft_id=info:pmid/25619158&rfr_iscdi=true |