Solid‐state synthesis of cyclo LD‐diphenylalanine: A chiral phase built from achiral subunits

The solid‐state structure of LL/DD or LD/DL diphenylalanine diluted in KBr pellets is studied by infrared (IR) absorption and vibrational circular dichroism (VCD) spectroscopy. The structure depends on the absolute configuration of the residues. The natural LL diphenylalanine exists as a mixture of...

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Veröffentlicht in:	Chirality (New York, N.Y.) N.Y.), 2020-05, Vol.32 (5), p.693-703
Hauptverfasser:	Pérez‐Mellor, Ariel, Le Barbu‐Debus, Katia, Zehnacker, Anne
Format:	Artikel
Sprache:	eng
Schlagworte:	Absolute configuration Chemical Physics Chemical Sciences Chemistry Techniques, Synthetic Chirality chirality synchronization Circular dichroism Dichroism diketopiperazine (DKP) Enantiomers Models, Molecular Molecular Conformation Monomers Optical activity or physical chemistry peptides Phenylalanine - analogs & derivatives Phenylalanine - chemical synthesis Phenylalanine - chemistry Physics Reagents Spectroscopy Spectrum analysis Stereoisomerism Synchronism Synchronization Temperature Theoretical and vibrational circular dichroism (VCD) vibrational spectroscopy Zwitterions
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