Kinetic and selectivity control of TEMPO electro-mediated oxidation of alcohols
TEMPO electro-mediated oxidation of alcohols has been investigated in aqueous and hydro-organic media. Mono- and poly-saccharides, aryl alcohols and heterocyclic alcohols were converted into the corresponding carbonyls in good chemical and Faradaic yields. In both solvents, the electrochemically gen...
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| Veröffentlicht in: | Electrochemistry communications 2005-03, Vol.7 (3), p.312-316 |
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| container_title | Electrochemistry communications |
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| creator | Liaigre, Denis Breton, Tony Belgsir, El Mustapha |
| description | TEMPO electro-mediated oxidation of alcohols has been investigated in aqueous and hydro-organic media. Mono- and poly-saccharides, aryl alcohols and heterocyclic alcohols were converted into the corresponding carbonyls in good chemical and Faradaic yields. In both solvents, the electrochemically generated TEMPO
+ was used in catalytic amount and the kinetics was found to be controlled by the diffusion step. |
| doi_str_mv | 10.1016/j.elecom.2005.01.002 |
| format | Article |
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| ispartof | Electrochemistry communications, 2005-03, Vol.7 (3), p.312-316 |
| issn | 1388-2481 1873-1902 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_02533776v1 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Alcohols Carbohydrates Chemical Sciences Chemistry Electrochemistry Electrosynthesis Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions or physical chemistry Oxidation TEMPO Theoretical and |
| title | Kinetic and selectivity control of TEMPO electro-mediated oxidation of alcohols |
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