Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction
The neutron powder diffraction technique has been used for structural studies of Rb 2 UBr 6 solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell...
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Veröffentlicht in: | Nukleonika 2020-03, Vol.65 (1), p.3-11 |
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description | The neutron powder diffraction technique has been used for structural studies of Rb
2
UBr
6
solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell in the P21/c space group. At 80 K and 853 K, the compound crystallizes in a tetragonal unit cell in the P4/mnc space group. At 300 K, the lattice constants are a = b = 7.745(1) and c = 11.064(1) Å. At the temperature range of 853–960 K, a trigonal phase is observed in the Pʒ̄ml space group. |
doi_str_mv | 10.2478/nuka-2020-0001 |
format | Article |
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2
UBr
6
solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell in the P21/c space group. At 80 K and 853 K, the compound crystallizes in a tetragonal unit cell in the P4/mnc space group. At 300 K, the lattice constants are a = b = 7.745(1) and c = 11.064(1) Å. At the temperature range of 853–960 K, a trigonal phase is observed in the Pʒ̄ml space group.</description><identifier>ISSN: 1508-5791</identifier><identifier>ISSN: 0029-5922</identifier><identifier>EISSN: 1508-5791</identifier><identifier>DOI: 10.2478/nuka-2020-0001</identifier><language>eng</language><subject>Condensed Matter ; Materials Science ; Physics</subject><ispartof>Nukleonika, 2020-03, Vol.65 (1), p.3-11</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c731-d7c9a2c126039fdda0f0cd4e7552d73f8c7f1ac2c474b4f95ad733251ffe3f713</cites><orcidid>0000-0003-2289-4706 ; 0000-0003-4642-8128 ; 0000-0002-5059-1481</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,315,781,785,865,886,27929,27930</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02490544$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Małetka, Krzysztof</creatorcontrib><creatorcontrib>Ressouche, Eric</creatorcontrib><creatorcontrib>Rundlof, Hakan</creatorcontrib><creatorcontrib>Tellgren, Rolland</creatorcontrib><creatorcontrib>Szczepaniak, Włodzimierz</creatorcontrib><creatorcontrib>Zabłocka-Malicka, Monika</creatorcontrib><title>Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction</title><title>Nukleonika</title><description>The neutron powder diffraction technique has been used for structural studies of Rb
2
UBr
6
solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell in the P21/c space group. At 80 K and 853 K, the compound crystallizes in a tetragonal unit cell in the P4/mnc space group. At 300 K, the lattice constants are a = b = 7.745(1) and c = 11.064(1) Å. At the temperature range of 853–960 K, a trigonal phase is observed in the Pʒ̄ml space group.</description><subject>Condensed Matter</subject><subject>Materials Science</subject><subject>Physics</subject><issn>1508-5791</issn><issn>0029-5922</issn><issn>1508-5791</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpNkE1Lw0AQhhdRsNRePe_VQ-rsVzc51qBWCAhSvS6b_cDFNCu7idB_b0KLeJrhneedw4PQLYE15bK878cvXVCgUAAAuUALIqAshKzI5b_9Gq1yDu1EyFIIIRfoo07HPOiuC73DeUijGcbkMo4ev7WY4veHhDc4xD4YbGJvp3tM2LrBpcNUsbg94t6NQ4o9tsH7pM0w0Tfoyusuu9V5LtH-6XFf74rm9fml3jaFkYwUVppKU0PoBljlrdXgwVjupBDUSuZLIz3Rhhouect9JfSUMiqI9455SdgS3Z3efupOfadw0Omoog5qt23UnAHlFQjOf2Z2fWJNijkn5_8KBNTsUM0O1exQzQ7ZL6CvZTw</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Małetka, Krzysztof</creator><creator>Ressouche, Eric</creator><creator>Rundlof, Hakan</creator><creator>Tellgren, Rolland</creator><creator>Szczepaniak, Włodzimierz</creator><creator>Zabłocka-Malicka, Monika</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-2289-4706</orcidid><orcidid>https://orcid.org/0000-0003-4642-8128</orcidid><orcidid>https://orcid.org/0000-0002-5059-1481</orcidid></search><sort><creationdate>20200301</creationdate><title>Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction</title><author>Małetka, Krzysztof ; Ressouche, Eric ; Rundlof, Hakan ; Tellgren, Rolland ; Szczepaniak, Włodzimierz ; Zabłocka-Malicka, Monika</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c731-d7c9a2c126039fdda0f0cd4e7552d73f8c7f1ac2c474b4f95ad733251ffe3f713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Condensed Matter</topic><topic>Materials Science</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Małetka, Krzysztof</creatorcontrib><creatorcontrib>Ressouche, Eric</creatorcontrib><creatorcontrib>Rundlof, Hakan</creatorcontrib><creatorcontrib>Tellgren, Rolland</creatorcontrib><creatorcontrib>Szczepaniak, Włodzimierz</creatorcontrib><creatorcontrib>Zabłocka-Malicka, Monika</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Nukleonika</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Małetka, Krzysztof</au><au>Ressouche, Eric</au><au>Rundlof, Hakan</au><au>Tellgren, Rolland</au><au>Szczepaniak, Włodzimierz</au><au>Zabłocka-Malicka, Monika</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction</atitle><jtitle>Nukleonika</jtitle><date>2020-03-01</date><risdate>2020</risdate><volume>65</volume><issue>1</issue><spage>3</spage><epage>11</epage><pages>3-11</pages><issn>1508-5791</issn><issn>0029-5922</issn><eissn>1508-5791</eissn><abstract>The neutron powder diffraction technique has been used for structural studies of Rb
2
UBr
6
solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell in the P21/c space group. At 80 K and 853 K, the compound crystallizes in a tetragonal unit cell in the P4/mnc space group. At 300 K, the lattice constants are a = b = 7.745(1) and c = 11.064(1) Å. At the temperature range of 853–960 K, a trigonal phase is observed in the Pʒ̄ml space group.</abstract><doi>10.2478/nuka-2020-0001</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-2289-4706</orcidid><orcidid>https://orcid.org/0000-0003-4642-8128</orcidid><orcidid>https://orcid.org/0000-0002-5059-1481</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Condensed Matter Materials Science Physics |
title | Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction |
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