Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction

The neutron powder diffraction technique has been used for structural studies of Rb 2 UBr 6 solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell...

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Veröffentlicht in:Nukleonika 2020-03, Vol.65 (1), p.3-11
Hauptverfasser: Małetka, Krzysztof, Ressouche, Eric, Rundlof, Hakan, Tellgren, Rolland, Szczepaniak, Włodzimierz, Zabłocka-Malicka, Monika
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container_issue 1
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container_title Nukleonika
container_volume 65
creator Małetka, Krzysztof
Ressouche, Eric
Rundlof, Hakan
Tellgren, Rolland
Szczepaniak, Włodzimierz
Zabłocka-Malicka, Monika
description The neutron powder diffraction technique has been used for structural studies of Rb 2 UBr 6 solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell in the P21/c space group. At 80 K and 853 K, the compound crystallizes in a tetragonal unit cell in the P4/mnc space group. At 300 K, the lattice constants are a = b = 7.745(1) and c = 11.064(1) Å. At the temperature range of 853–960 K, a trigonal phase is observed in the Pʒ̄ml space group.
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subjects Condensed Matter
Materials Science
Physics
title Crystalline structures of Rb 2 UBr 6 ionic conductor determined by neutron diffraction
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