Role of the Main and Auxiliary Ligands in the Nuclearity of Cu‐Ln Complexes

Trianionic ligands with an inner N2O2, an outer O2O2 or O2O coordination site and an oxygen atom coming from an amide function not involved in these sites yield dinuclear Cu‐Ln complexes that self‐assemble into tetranuclear species with an alternate arrangement of Cu and Ln ions. This alternate Cu‐G...

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Veröffentlicht in:	European journal of inorganic chemistry 2020-01, Vol.2020 (4), p.382-393
Hauptverfasser:	Costes, Jean‐Pierre, Rodriguez Douton, Maria‐Jesus, Shova, Sergiu, Vendier, Laure
Format:	Artikel
Sprache:	eng
Schlagworte:	Antiferromagnetism Bridges Chelation Chemical Sciences Coordination chemistry Coordination compounds Copper Ferromagnetism Gadolinium Inorganic chemistry Lanthanides Ligand design Ligands Magnetic properties Structure elucidation
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