Toward a Rational Design of 3d-4f Heterometallic Coordination Polymers based on Mixed Valence Copper Centers

In the present work, we report two new CuI/CuII–GdIII mixed valence heterometallic coordination polymers (HCP), [Gd­(H2O)4­CuIICuI(IDC)2] (1) and [Gd2(H2O)2­(C2O4)2CuII(IDC)2­CuI 2(4,4′-bipy)]­·4.5H2O (2) obtained under solvothermal synthesis using 1H-imidazole-4,5-dicarboxylic acid (H3IDC) as a pri...

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Veröffentlicht in:	Crystal growth & design 2019-12, Vol.19 (12), p.7055-7066
Hauptverfasser:	Cruz, Carlos, Rubio, Francisco, Venegas-Yazigi, Diego, Audebrand, Nathalie, Calers, Christophe, Spodine, Evgenia, Paredes-García, Verónica
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences
Online-Zugang:	Volltext
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