Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination

Metal–Lewis acid cooperation provides new opportunities in catalysis. In this work, we report a new type of palladium–borane cooperation involving anionic Pd0 species. The air‐stable DPB palladium complex 1 (DPB=diphosphine‐borane) was prepared and reacted with KH to give the Pd0 borohydride 2, the...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-12, Vol.58 (52), p.18783-18787
Hauptverfasser:	Kameo, Hajime, Yamamoto, Jun, Asada, Ayaka, Nakazawa, Hiroshi, Matsuzaka, Hiroyuki, Bourissou, Didier
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds boranes Boron Catalysis Chemical Sciences Cooperation Dechlorination Dehalogenation Lewis acid Palladium
Online-Zugang:	Volltext
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