Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling

Two cage copper(II)silsesquioxanes, namely, tricopper complex (PhSiO1.5)8(CuO)3(TMEDA)2*(MeCN)3Cu-1 and hexacopper complex (MeSiO1,5)12(CuO)6(Py)6*TMEDA Cu-2 were synthesized (in 30% and 16% yield, respectively) via TMEDA-assisted reactions (TMEDA = tetramethylethylenediamine). Structural features o...

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Veröffentlicht in:	Journal of organometallic chemistry 2020-01, Vol.906, p.121022, Article 121022
Hauptverfasser:	Astakhov, G.S., Levitsky, M.M., Bantreil, X., Lamaty, F., Khrustalev, V.N., Zubavichus, Y.V., Dorovatovskii, P.V., Shubina, E.S., Bilyachenko, A.N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chan-Evans-Lam coupling Chemical Sciences Coordination chemistry Copper complexes Metallasilsesquioxanes Organic chemistry X-ray
Online-Zugang:	Volltext
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