Pd and Pd@PdO core–shell nanoparticles supported on Vulcan carbon XC-72R: comparison of electroactivity for methanol electro-oxidation reaction
Nanomaterials based on Pd nanoparticles supported on Vulcan carbon (XC-72R) were prepared by the organometallic approach in one-pot and mild conditions (3 bar hydrogen and room temperature) using Pd(dba) 2 (bis (dibenzylideneacetone) palladium (0)) as metal source and hexadecylamine (HDA) as stabili...
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| Veröffentlicht in: | Journal of materials science 2019-11, Vol.54 (21), p.13694-13714 |
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| creator | Guerrero-Ortega, L. P. A. Ramírez-Meneses, E. Cabrera-Sierra, R. Palacios-Romero, L. M. Philippot, K. Santiago-Ramírez, C. R. Lartundo-Rojas, L. Manzo-Robledo, A. |
| description | Nanomaterials based on Pd nanoparticles supported on Vulcan carbon (XC-72R) were prepared by the organometallic approach in one-pot and mild conditions (3 bar hydrogen and room temperature) using Pd(dba)
2
(bis (dibenzylideneacetone) palladium (0)) as metal source and hexadecylamine (HDA) as stabilizer. High-resolution transmission electron microscopy (HR-TEM) evidenced the presence of well-dispersed Pd nanoparticles of ca. 4.5 nm mean size onto the carbon support (Pd/HDA/C). Scanning and transmission electron microscopy with electron energy loss spectroscopy (STEM-EELS) allowed to determine the chemical composition of the nanomaterials. When the Pd/HDA/C nanomaterial was submitted to heating treatment (ht) at 400 °C under air (referred as Pd/HDA/C@air-ht), X-ray photoelectron spectroscopy (XPS) and HR-TEM/STEM-EELS analyses suggested the presence of interactions between PdO and Pd(0) as a result of the formation of Pd@PdO core–shell nanoparticles. The highest oxidation current magnitude during methanol oxidation reaction is ascribed to the heat-treated material, linked with a better electron and mass transfer processes at the electrode interface. This can be attributed to electronic interactions at the core–shell formed, which might promote different redox processes at the electrode interface during CH
3
OH deprotonation in the alkaline electrolyte. |
| doi_str_mv | 10.1007/s10853-019-03843-8 |
| format | Article |
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2
(bis (dibenzylideneacetone) palladium (0)) as metal source and hexadecylamine (HDA) as stabilizer. High-resolution transmission electron microscopy (HR-TEM) evidenced the presence of well-dispersed Pd nanoparticles of ca. 4.5 nm mean size onto the carbon support (Pd/HDA/C). Scanning and transmission electron microscopy with electron energy loss spectroscopy (STEM-EELS) allowed to determine the chemical composition of the nanomaterials. When the Pd/HDA/C nanomaterial was submitted to heating treatment (ht) at 400 °C under air (referred as Pd/HDA/C@air-ht), X-ray photoelectron spectroscopy (XPS) and HR-TEM/STEM-EELS analyses suggested the presence of interactions between PdO and Pd(0) as a result of the formation of Pd@PdO core–shell nanoparticles. The highest oxidation current magnitude during methanol oxidation reaction is ascribed to the heat-treated material, linked with a better electron and mass transfer processes at the electrode interface. This can be attributed to electronic interactions at the core–shell formed, which might promote different redox processes at the electrode interface during CH
3
OH deprotonation in the alkaline electrolyte.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-019-03843-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Carbon ; Characterization and Evaluation of Materials ; Chemical composition ; Chemical Sciences ; Chemistry and Materials Science ; Classical Mechanics ; Comparative analysis ; Coordination chemistry ; Core-shell particles ; Crystallography and Scattering Methods ; Electroactivity ; Electrodes ; Electron energy loss spectroscopy ; Energy dissipation ; Energy Materials ; Energy transmission ; Heat treatment ; Mass transfer ; Material chemistry ; Materials Science ; Methanol ; Nanomaterials ; Nanoparticles ; Organic chemistry ; Oxidation ; Oxidation-reduction reaction ; Palladium ; Photoelectrons ; Polymer Sciences ; Povidone ; Scanning electron microscopy ; Scanning transmission electron microscopy ; Solid Mechanics ; Spectrum analysis ; Transmission electron microscopy ; X ray photoelectron spectroscopy ; X-ray spectroscopy</subject><ispartof>Journal of materials science, 2019-11, Vol.54 (21), p.13694-13714</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2019). All Rights Reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c601t-a73414469d16b7b1623e4f8313be10fe62495125167ea62766d4844e2a91a76d3</citedby><cites>FETCH-LOGICAL-c601t-a73414469d16b7b1623e4f8313be10fe62495125167ea62766d4844e2a91a76d3</cites><orcidid>0000-0002-8570-4028 ; 0000-0003-0072-1281 ; 0000-0002-8965-825X ; 0000-0002-0003-6439 ; 0000-0002-6366-8791 ; 0000-0003-2456-3580 ; 0000-0002-7733-1671 ; 0000-0002-1367-6152</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-019-03843-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-019-03843-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,776,780,881,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02388801$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Guerrero-Ortega, L. P. A.</creatorcontrib><creatorcontrib>Ramírez-Meneses, E.</creatorcontrib><creatorcontrib>Cabrera-Sierra, R.</creatorcontrib><creatorcontrib>Palacios-Romero, L. M.</creatorcontrib><creatorcontrib>Philippot, K.</creatorcontrib><creatorcontrib>Santiago-Ramírez, C. R.</creatorcontrib><creatorcontrib>Lartundo-Rojas, L.</creatorcontrib><creatorcontrib>Manzo-Robledo, A.</creatorcontrib><title>Pd and Pd@PdO core–shell nanoparticles supported on Vulcan carbon XC-72R: comparison of electroactivity for methanol electro-oxidation reaction</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Nanomaterials based on Pd nanoparticles supported on Vulcan carbon (XC-72R) were prepared by the organometallic approach in one-pot and mild conditions (3 bar hydrogen and room temperature) using Pd(dba)
2
(bis (dibenzylideneacetone) palladium (0)) as metal source and hexadecylamine (HDA) as stabilizer. High-resolution transmission electron microscopy (HR-TEM) evidenced the presence of well-dispersed Pd nanoparticles of ca. 4.5 nm mean size onto the carbon support (Pd/HDA/C). Scanning and transmission electron microscopy with electron energy loss spectroscopy (STEM-EELS) allowed to determine the chemical composition of the nanomaterials. When the Pd/HDA/C nanomaterial was submitted to heating treatment (ht) at 400 °C under air (referred as Pd/HDA/C@air-ht), X-ray photoelectron spectroscopy (XPS) and HR-TEM/STEM-EELS analyses suggested the presence of interactions between PdO and Pd(0) as a result of the formation of Pd@PdO core–shell nanoparticles. The highest oxidation current magnitude during methanol oxidation reaction is ascribed to the heat-treated material, linked with a better electron and mass transfer processes at the electrode interface. This can be attributed to electronic interactions at the core–shell formed, which might promote different redox processes at the electrode interface during CH
3
OH deprotonation in the alkaline electrolyte.</description><subject>Carbon</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Chemical Sciences</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Comparative analysis</subject><subject>Coordination chemistry</subject><subject>Core-shell particles</subject><subject>Crystallography and Scattering Methods</subject><subject>Electroactivity</subject><subject>Electrodes</subject><subject>Electron energy loss spectroscopy</subject><subject>Energy dissipation</subject><subject>Energy Materials</subject><subject>Energy transmission</subject><subject>Heat treatment</subject><subject>Mass transfer</subject><subject>Material chemistry</subject><subject>Materials Science</subject><subject>Methanol</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Oxidation-reduction reaction</subject><subject>Palladium</subject><subject>Photoelectrons</subject><subject>Polymer Sciences</subject><subject>Povidone</subject><subject>Scanning electron microscopy</subject><subject>Scanning transmission electron microscopy</subject><subject>Solid Mechanics</subject><subject>Spectrum analysis</subject><subject>Transmission electron microscopy</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray spectroscopy</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9ksuKFDEUhgtRsB19AVcBV7OoMbdKpVzZNOoMNEwzXnAX0qlT3RmqkjJJDTM7X0F8Q5_EtKUODSJZhJx83-Ec-IviOcFnBOP6ZSRYVqzEpCkxk5yV8kGxIFXNSi4xe1gsMKa0pFyQx8WTGK8xxlVNyaL4tmmRdi3atK837SUyPsCPr9_jHvoeOe38qEOypoeI4jSOPiRokXfo09Qb7ZDRYZtfn1dlTa9eZXvIvI255DsEPZgUvDbJ3th0hzof0ABpn7v2fz5Lf2tbnWw2AhxI754WjzrdR3j2-z4pPr5982F1Xq4v312sluvSCExSqWvGCeeiaYnY1lsiKAPeSUbYFgjuQFDeVIRWRNSgBa2FaLnkHKhuiK5Fy06K07nvXvdqDHbQ4U55bdX5cq0ONUyZlBKTG5LZFzM7Bv9lgpjUtZ-Cy-MpSgWrGyZpc0_tdA_Kus6noM1go1HLqhGMC8l4ps7-QeXTwmCNd9DZXD8STo-EzCS4TTs9xagu3l8ds3RmTfAxBuj-bkawOiRFzUlROSnqV1KUzBKbpZhht4Nwv91_rJ_Hwr9A</recordid><startdate>20191101</startdate><enddate>20191101</enddate><creator>Guerrero-Ortega, L. 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P. A.</au><au>Ramírez-Meneses, E.</au><au>Cabrera-Sierra, R.</au><au>Palacios-Romero, L. M.</au><au>Philippot, K.</au><au>Santiago-Ramírez, C. R.</au><au>Lartundo-Rojas, L.</au><au>Manzo-Robledo, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pd and Pd@PdO core–shell nanoparticles supported on Vulcan carbon XC-72R: comparison of electroactivity for methanol electro-oxidation reaction</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2019-11-01</date><risdate>2019</risdate><volume>54</volume><issue>21</issue><spage>13694</spage><epage>13714</epage><pages>13694-13714</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Nanomaterials based on Pd nanoparticles supported on Vulcan carbon (XC-72R) were prepared by the organometallic approach in one-pot and mild conditions (3 bar hydrogen and room temperature) using Pd(dba)
2
(bis (dibenzylideneacetone) palladium (0)) as metal source and hexadecylamine (HDA) as stabilizer. High-resolution transmission electron microscopy (HR-TEM) evidenced the presence of well-dispersed Pd nanoparticles of ca. 4.5 nm mean size onto the carbon support (Pd/HDA/C). Scanning and transmission electron microscopy with electron energy loss spectroscopy (STEM-EELS) allowed to determine the chemical composition of the nanomaterials. When the Pd/HDA/C nanomaterial was submitted to heating treatment (ht) at 400 °C under air (referred as Pd/HDA/C@air-ht), X-ray photoelectron spectroscopy (XPS) and HR-TEM/STEM-EELS analyses suggested the presence of interactions between PdO and Pd(0) as a result of the formation of Pd@PdO core–shell nanoparticles. The highest oxidation current magnitude during methanol oxidation reaction is ascribed to the heat-treated material, linked with a better electron and mass transfer processes at the electrode interface. This can be attributed to electronic interactions at the core–shell formed, which might promote different redox processes at the electrode interface during CH
3
OH deprotonation in the alkaline electrolyte.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-019-03843-8</doi><tpages>21</tpages><orcidid>https://orcid.org/0000-0002-8570-4028</orcidid><orcidid>https://orcid.org/0000-0003-0072-1281</orcidid><orcidid>https://orcid.org/0000-0002-8965-825X</orcidid><orcidid>https://orcid.org/0000-0002-0003-6439</orcidid><orcidid>https://orcid.org/0000-0002-6366-8791</orcidid><orcidid>https://orcid.org/0000-0003-2456-3580</orcidid><orcidid>https://orcid.org/0000-0002-7733-1671</orcidid><orcidid>https://orcid.org/0000-0002-1367-6152</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Carbon Characterization and Evaluation of Materials Chemical composition Chemical Sciences Chemistry and Materials Science Classical Mechanics Comparative analysis Coordination chemistry Core-shell particles Crystallography and Scattering Methods Electroactivity Electrodes Electron energy loss spectroscopy Energy dissipation Energy Materials Energy transmission Heat treatment Mass transfer Material chemistry Materials Science Methanol Nanomaterials Nanoparticles Organic chemistry Oxidation Oxidation-reduction reaction Palladium Photoelectrons Polymer Sciences Povidone Scanning electron microscopy Scanning transmission electron microscopy Solid Mechanics Spectrum analysis Transmission electron microscopy X ray photoelectron spectroscopy X-ray spectroscopy |
| title | Pd and Pd@PdO core–shell nanoparticles supported on Vulcan carbon XC-72R: comparison of electroactivity for methanol electro-oxidation reaction |
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