High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides

Two types of heterometallic (Fe(III),Na) silsesquioxanes-[Ph5Si5O10]2[Ph10Si10O21]Fe6(O2-)2Na7(H3O+)(MeOH)2(MeCN)4.5.1.25(MeCN), I, and [Ph5Si5O10]2[Ph4Si4O8]2Fe6Na6(O2-)3(MeCN)8.5(H2O)8.44, II-were obtained and characterized. X-ray studies established distinctive structures of both products, with p...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Catalysts 2017-04, Vol.7 (12), p.101
Hauptverfasser:	Yalymov, Alexey, Bilyachenko, Alexey, Levitsky, Mikhail, Korlyukov, Alexander, Khrustalev, Victor, Shul’pina, Lidia, Dorovatovskii, Pavel, Es’kova, Marina, Lamaty, Frédéric, Bantreil, Xavier, Villemejeanne, Benoît, Martinez, Jean, Shubina, Elena, Kozlov, Yuriy, Shul’pin, Georgiy
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Alcohols Alkanes Amides Amines Benzene Cages Catalysis Catalysts Catalytic activity Chemical reactions Chemical Sciences Coordination chemistry Cyclohexane Dimerization Hydrogen peroxide Hydroxyl radicals Iron Ketones Organic chemistry Oxidation Peroxides
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!