Theoretical investigation of von Braun and von Braun‐like reactions

The von Braun reaction, discovered at the dawn of the past century, consists of the reaction between a tertiary amine and cyanogen bromide. It leads to the cleavage of a C─N bond with the formation of an N‐dialkylcyanamide and an alkyl bromide and has been extensively used in organic synthesis. A de...

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