Supramolecular Arene-Ruthenium Metallacycle with Thermotropic Liquid-Crystalline Properties
Functionalization of 1,4-di(4-pyridinyl)benzene with poly(arylester) dendrimers bearing cyanobiphenyl end-groups gives a bidentate dendromesogenic ligand (L) that exhibits thermotropic liquid-crystalline properties. Combination of the diruthenium complex [Ru2(p-cymene)2(donq)][DDS]2 (M) with L,...
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| Veröffentlicht in: | Inorganic chemistry 2019-07, Vol.58 (14), p.9505-9512 |
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| container_title | Inorganic chemistry |
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| creator | Alvariño, Cristina Heinrich, Benoît Donnio, Bertrand Deschenaux, Robert Therrien, Bruno |
| description | Functionalization of 1,4-di(4-pyridinyl)benzene with poly(arylester) dendrimers bearing cyanobiphenyl end-groups gives a bidentate dendromesogenic ligand (L) that exhibits thermotropic liquid-crystalline properties. Combination of the diruthenium complex [Ru2(p-cymene)2(donq)][DDS]2 (M) with L, by coordination-driven self-assembly, affords the discrete and well-defined metallacycle M 2 L 2 . Like L, this supramolecular dendritic system displays mesomorphic properties above 50 °C. Both compounds L and M 2 L 2 show smectic phases, characterized by a multilayered organization of the multiple components. |
| doi_str_mv | 10.1021/acs.inorgchem.9b01532 |
| format | Article |
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| subjects | Chemical Sciences Coordination chemistry Cristallography Inorganic chemistry Organic chemistry |
| title | Supramolecular Arene-Ruthenium Metallacycle with Thermotropic Liquid-Crystalline Properties |
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