Experimental Evidence of the Electrostatic Contribution to the Bending Rigidity of Charged Membranes

We address the issue of the origin of the bending rigidity of a charged membrane formed from amphiphilic molecules. Electrostatic effects are investigated by direct measurement of the force necessary to deform a catanionic membrane as function of the ionic strength of the medium by means of an atomi...

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Veröffentlicht in:The journal of physical chemistry. B 2007-03, Vol.111 (10), p.2503-2505
Hauptverfasser: Delorme, N, Bardeau, J.-F, Carrière, D, Dubois, M, Gourbil, A, Mohwald, H, Zemb, Th, Fery, A
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container_end_page 2505
container_issue 10
container_start_page 2503
container_title The journal of physical chemistry. B
container_volume 111
creator Delorme, N
Bardeau, J.-F
Carrière, D
Dubois, M
Gourbil, A
Mohwald, H
Zemb, Th
Fery, A
description We address the issue of the origin of the bending rigidity of a charged membrane formed from amphiphilic molecules. Electrostatic effects are investigated by direct measurement of the force necessary to deform a catanionic membrane as function of the ionic strength of the medium by means of an atomic force microscope (AFM). Using continuum mechanical modeling of membrane deformation, we derive the bending rigidity of the catanionic membranes and monitor for the first time its decrease in response to increasing salt concentration.
doi_str_mv 10.1021/jp068252v
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subjects Condensed Matter
Elasticity
Membrane Fluidity
Membranes, Artificial
Microscopy, Atomic Force
Physics
Salts - chemistry
Soft Condensed Matter
Static Electricity
title Experimental Evidence of the Electrostatic Contribution to the Bending Rigidity of Charged Membranes
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