Gd5Si2B8: A Ternary Rare-Earth-Metal Silicide Boride Compound
Two compounds in one: The boron‐rich ternary compound Gd5Si2B8 represents a new structure type containing independent ordered boron and silicon substructures of compositions GdB4 and Gd3Si2, respectively, alternating along the c direction (see structure). The compound exhibits metallic character, wh...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2004-04, Vol.43 (15), p.1979-1983 |
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| container_end_page | 1983 |
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| container_issue | 15 |
| container_start_page | 1979 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 43 |
| creator | Babizhetskyy, Volodymyr Roger, Jérome Députier, Stéphanie Guérin, Roland Jardin, Régis Bauer, Josef Hiebl, Kurt Jardin, Christophe Saillard, Jean-Yves Halet, Jean-François |
| description | Two compounds in one: The boron‐rich ternary compound Gd5Si2B8 represents a new structure type containing independent ordered boron and silicon substructures of compositions GdB4 and Gd3Si2, respectively, alternating along the c direction (see structure). The compound exhibits metallic character, which is supported by theoretical investigations, and has a rather complex magnetic structure. |
| doi_str_mv | 10.1002/anie.200352468 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2004-04, Vol.43 (15), p.1979-1983 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_02335472v1 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | boron Chemical Sciences density functional theory gadolinium Inorganic chemistry magnetic properties silicon |
| title | Gd5Si2B8: A Ternary Rare-Earth-Metal Silicide Boride Compound |
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