Synthesis and structural characterization of a liquid polyisoprene bearing amidoxime end groups
Azo-bis(isobutyroamidoxime) was synthesized and used as functionalized initiator to prepare a liquid isoprene bearing amidoxime end groups via radical polymerization. The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular, the structure of the polymer was invest...
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| Veröffentlicht in: | Journal of polymer research 2011-11, Vol.18 (6), p.2265-2273 |
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| container_title | Journal of polymer research |
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| creator | Burel, Fabrice Oulyadi, Hassan Bunel, Claude Grishchenko, Vladimir Busko, Natalya Barantsova, Antonina Boiko, Vitaly |
| description | Azo-bis(isobutyroamidoxime) was synthesized and used as functionalized initiator to prepare a liquid isoprene bearing amidoxime end groups via radical polymerization. The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular, the structure of the polymer was investigated using 1D and 2D NMR techniques. The distribution of the different isoprene units (1,4-trans, 1,4-cis, 1,2 and 3,4), as well as the structure of the amidoxime end-groups was determined. It was found that the structure of the end groups was governed by the steric hindrance of the initiator. Only 1,4 and 4,1 functionalized end units were evidenced, with a majority of 4,1 end units. |
| doi_str_mv | 10.1007/s10965-011-9640-4 |
| format | Article |
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The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular, the structure of the polymer was investigated using 1D and 2D NMR techniques. The distribution of the different isoprene units (1,4-trans, 1,4-cis, 1,2 and 3,4), as well as the structure of the amidoxime end-groups was determined. It was found that the structure of the end groups was governed by the steric hindrance of the initiator. 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| subjects | Analytical chemistry Bearing Characterization and Evaluation of Materials Chemical Sciences Chemistry Chemistry and Materials Science Gel permeation chromatography Industrial Chemistry/Chemical Engineering Initiators Isoprene Liquids Nuclear magnetic resonance Original Paper Polymer Sciences Polymers Radicals Two dimensional |
| title | Synthesis and structural characterization of a liquid polyisoprene bearing amidoxime end groups |
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