Multivalent Metallosupramolecular Assemblies as Effective DNA Binding Agents

We report the implementation of coordination chemistry onto the generation of new types of metallosupramolecular complexes with laterally appended cationic moieties for DNA binding in buffered aqueous media. Utilization of an N,N,O‐type coordination pocket along with an octahedral zinc(II) metal ion...

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Veröffentlicht in:	Chemistry : a European journal 2018-07, Vol.24 (42), p.10802-10811
Hauptverfasser:	Drożdż, Wojciech, Walczak, Anna, Bessin, Yannick, Gervais, Virginie, Cao, Xiao‐Yu, Lehn, Jean‐Marie, Ulrich, Sébastien, Stefankiewicz, Artur R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Assemblies Binding Buffers (chemistry) Calorimetry Cations Chemical Sciences Chemistry coordination chemistry Coordination compounds Deoxyribonucleic acid DNA DNA recognition Electrophoresis Electrostatic properties Gel electrophoresis Magnetic resonance spectroscopy Metal ions multivalency NMR spectroscopy Organic chemistry self-assembly Titration Titration calorimetry X-ray diffraction Zinc
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