Cyclometalated N-heterocyclic carbene iridium(iii) complexes with naphthalimide chromophores: a novel class of phosphorescent heteroleptic compounds

A series of cyclometalated N-heterocyclic carbene complexes of the general formula [Ir(C^N) (C^C:)] has been prepared. Two sets of compounds were designed, those where (C^C:) represents a bidentate naphthalimide-substituted imidazolylidene ligand and (C^N) = ppy (3a), F2ppy (4a), bzq (5a) and those...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (10), p.3440-3451
Hauptverfasser:	Lanoë, Pierre-Henri, Chan, Jonny, Groué, Antoine, Gontard, Geoffrey, Jutand, Anny, Rager, Marie-Noelle, Armaroli, Nicola, Monti, Filippo, Barbieri, Andrea, Amouri, Hani
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Chromophores Coordination compounds Crystal structure Crystals Emission analysis Imidazole Infrared radiation Inorganic chemistry Iridium compounds Ligands NMR spectroscopy Phosphorescence Single crystals Substitutes
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