On the interest of ambipolar materials for gas sensing

[Display omitted] •Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance. Based on the electrochemical properties of a series of metallophthalocyanines...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2018-04, Vol.258, p.657-664
Hauptverfasser: Wannebroucq, Amélie, Ouedraogo, Seydou, Meunier-Prest, Rita, Suisse, Jean-Moïse, Bayo, Mabinty, Bouvet, Marcel
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container_title Sensors and actuators. B, Chemical
container_volume 258
creator Wannebroucq, Amélie
Ouedraogo, Seydou
Meunier-Prest, Rita
Suisse, Jean-Moïse
Bayo, Mabinty
Bouvet, Marcel
description [Display omitted] •Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance. Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. We engaged three metallophthalocyanines, namely the octafluoro copper phthalocyanine, Cu(F8Pc), an octaester metallophthalocyanine and a phthalocyanine bearing four alkoxy groups and twelve fluorine atoms, Zn(T4F12Pc), in building original conductometric transducers that are Molecular Semiconductor – Doped Insulator heterojunctions (MSDIs) in association with the highly conductive lutetium bisphthalocyanine, LuPc2. Whereas the octaester derivative and Zn(T4F12Pc) exhibited a negative response to ammonia, as expected for p-type materials, Cu(F8Pc) exhibited a particular behavior. At low humidity levels, 30 and 10% rh, the current of the Cu(F8Pc)/LuPc2 MSDI decreases, similarly to p-type devices, but at higher relative humidity values, 70% rh, the current increases under ammonia, which is the signature of a n-type behavior. This ambipolar behavior is unique amongst semiconducting sensing materials. This work opens the way to the study of ambipolar materials as sensing materials for the development of a new type of conductometric gas sensors.
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Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. We engaged three metallophthalocyanines, namely the octafluoro copper phthalocyanine, Cu(F8Pc), an octaester metallophthalocyanine and a phthalocyanine bearing four alkoxy groups and twelve fluorine atoms, Zn(T4F12Pc), in building original conductometric transducers that are Molecular Semiconductor – Doped Insulator heterojunctions (MSDIs) in association with the highly conductive lutetium bisphthalocyanine, LuPc2. Whereas the octaester derivative and Zn(T4F12Pc) exhibited a negative response to ammonia, as expected for p-type materials, Cu(F8Pc) exhibited a particular behavior. At low humidity levels, 30 and 10% rh, the current of the Cu(F8Pc)/LuPc2 MSDI decreases, similarly to p-type devices, but at higher relative humidity values, 70% rh, the current increases under ammonia, which is the signature of a n-type behavior. This ambipolar behavior is unique amongst semiconducting sensing materials. 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B, Chemical</title><description>[Display omitted] •Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance. Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. 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subjects Ambipolar material
Ammonia
Biosensors
Chemical Sciences
Conductometric transducer
Copper
Detection
Electrochemical analysis
Fluorine
Gas sensor
Gas sensors
Gases
Heterojunctions
Humidity
Lutetium
Metal phthalocyanines
Molecular chains
Relative humidity
Transducers
title On the interest of ambipolar materials for gas sensing
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