On the interest of ambipolar materials for gas sensing
[Display omitted] •Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance. Based on the electrochemical properties of a series of metallophthalocyanines...
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Veröffentlicht in: | Sensors and actuators. B, Chemical Chemical, 2018-04, Vol.258, p.657-664 |
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container_title | Sensors and actuators. B, Chemical |
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creator | Wannebroucq, Amélie Ouedraogo, Seydou Meunier-Prest, Rita Suisse, Jean-Moïse Bayo, Mabinty Bouvet, Marcel |
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•Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance.
Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. We engaged three metallophthalocyanines, namely the octafluoro copper phthalocyanine, Cu(F8Pc), an octaester metallophthalocyanine and a phthalocyanine bearing four alkoxy groups and twelve fluorine atoms, Zn(T4F12Pc), in building original conductometric transducers that are Molecular Semiconductor – Doped Insulator heterojunctions (MSDIs) in association with the highly conductive lutetium bisphthalocyanine, LuPc2. Whereas the octaester derivative and Zn(T4F12Pc) exhibited a negative response to ammonia, as expected for p-type materials, Cu(F8Pc) exhibited a particular behavior. At low humidity levels, 30 and 10% rh, the current of the Cu(F8Pc)/LuPc2 MSDI decreases, similarly to p-type devices, but at higher relative humidity values, 70% rh, the current increases under ammonia, which is the signature of a n-type behavior. This ambipolar behavior is unique amongst semiconducting sensing materials. This work opens the way to the study of ambipolar materials as sensing materials for the development of a new type of conductometric gas sensors. |
doi_str_mv | 10.1016/j.snb.2017.11.146 |
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•Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance.
Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. We engaged three metallophthalocyanines, namely the octafluoro copper phthalocyanine, Cu(F8Pc), an octaester metallophthalocyanine and a phthalocyanine bearing four alkoxy groups and twelve fluorine atoms, Zn(T4F12Pc), in building original conductometric transducers that are Molecular Semiconductor – Doped Insulator heterojunctions (MSDIs) in association with the highly conductive lutetium bisphthalocyanine, LuPc2. Whereas the octaester derivative and Zn(T4F12Pc) exhibited a negative response to ammonia, as expected for p-type materials, Cu(F8Pc) exhibited a particular behavior. At low humidity levels, 30 and 10% rh, the current of the Cu(F8Pc)/LuPc2 MSDI decreases, similarly to p-type devices, but at higher relative humidity values, 70% rh, the current increases under ammonia, which is the signature of a n-type behavior. This ambipolar behavior is unique amongst semiconducting sensing materials. This work opens the way to the study of ambipolar materials as sensing materials for the development of a new type of conductometric gas sensors.</description><identifier>ISSN: 0925-4005</identifier><identifier>EISSN: 1873-3077</identifier><identifier>DOI: 10.1016/j.snb.2017.11.146</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Ambipolar material ; Ammonia ; Biosensors ; Chemical Sciences ; Conductometric transducer ; Copper ; Detection ; Electrochemical analysis ; Fluorine ; Gas sensor ; Gas sensors ; Gases ; Heterojunctions ; Humidity ; Lutetium ; Metal phthalocyanines ; Molecular chains ; Relative humidity ; Transducers</subject><ispartof>Sensors and actuators. B, Chemical, 2018-04, Vol.258, p.657-664</ispartof><rights>2017 Elsevier B.V.</rights><rights>Copyright Elsevier Science Ltd. Apr 2018</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c402t-c86e272169fe78b3d3c06faf4b08cb70a46b58ebb88e1cdf3ec099ea6ee486bf3</citedby><cites>FETCH-LOGICAL-c402t-c86e272169fe78b3d3c06faf4b08cb70a46b58ebb88e1cdf3ec099ea6ee486bf3</cites><orcidid>0000-0002-2272-6633 ; 0000-0001-5597-3879</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.snb.2017.11.146$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,315,781,785,886,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02295846$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Wannebroucq, Amélie</creatorcontrib><creatorcontrib>Ouedraogo, Seydou</creatorcontrib><creatorcontrib>Meunier-Prest, Rita</creatorcontrib><creatorcontrib>Suisse, Jean-Moïse</creatorcontrib><creatorcontrib>Bayo, Mabinty</creatorcontrib><creatorcontrib>Bouvet, Marcel</creatorcontrib><title>On the interest of ambipolar materials for gas sensing</title><title>Sensors and actuators. B, Chemical</title><description>[Display omitted]
•Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance.
Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. We engaged three metallophthalocyanines, namely the octafluoro copper phthalocyanine, Cu(F8Pc), an octaester metallophthalocyanine and a phthalocyanine bearing four alkoxy groups and twelve fluorine atoms, Zn(T4F12Pc), in building original conductometric transducers that are Molecular Semiconductor – Doped Insulator heterojunctions (MSDIs) in association with the highly conductive lutetium bisphthalocyanine, LuPc2. Whereas the octaester derivative and Zn(T4F12Pc) exhibited a negative response to ammonia, as expected for p-type materials, Cu(F8Pc) exhibited a particular behavior. At low humidity levels, 30 and 10% rh, the current of the Cu(F8Pc)/LuPc2 MSDI decreases, similarly to p-type devices, but at higher relative humidity values, 70% rh, the current increases under ammonia, which is the signature of a n-type behavior. This ambipolar behavior is unique amongst semiconducting sensing materials. This work opens the way to the study of ambipolar materials as sensing materials for the development of a new type of conductometric gas sensors.</description><subject>Ambipolar material</subject><subject>Ammonia</subject><subject>Biosensors</subject><subject>Chemical Sciences</subject><subject>Conductometric transducer</subject><subject>Copper</subject><subject>Detection</subject><subject>Electrochemical analysis</subject><subject>Fluorine</subject><subject>Gas sensor</subject><subject>Gas sensors</subject><subject>Gases</subject><subject>Heterojunctions</subject><subject>Humidity</subject><subject>Lutetium</subject><subject>Metal phthalocyanines</subject><subject>Molecular chains</subject><subject>Relative humidity</subject><subject>Transducers</subject><issn>0925-4005</issn><issn>1873-3077</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LAzEUxIMoWKsfwNuCJw-7vvxpksVTKWqFghc9hyR9sSntbk1WwW9vyopHTw-GmeHNj5BrCg0FKu-2Te5cw4CqhtKGCnlCJlQrXnNQ6pRMoGWzWgDMzslFzlsAEFzChMiXrho2WMVuwIR5qPpQ2b2Lh35nU7W3RY12l6vQp-rd5ipjl2P3fknOQpHx6vdOydvjw-tiWa9enp4X81XtBbCh9loiU4zKNqDSjq-5BxlsEA60dwqskG6m0Tmtkfp14OihbdFKRKGlC3xKbsfejd2ZQ4p7m75Nb6NZzlfmqAFj7UwL-UWL92b0HlL_8Vm2mG3_mbrynmEgFZeMC1VcdHT51OecMPzVUjBHlGZrCkpzRGkoNQVlydyPGSxTvyImk33EzuM6JvSDWffxn_QPDIJ61A</recordid><startdate>20180401</startdate><enddate>20180401</enddate><creator>Wannebroucq, Amélie</creator><creator>Ouedraogo, Seydou</creator><creator>Meunier-Prest, Rita</creator><creator>Suisse, Jean-Moïse</creator><creator>Bayo, Mabinty</creator><creator>Bouvet, Marcel</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-2272-6633</orcidid><orcidid>https://orcid.org/0000-0001-5597-3879</orcidid></search><sort><creationdate>20180401</creationdate><title>On the interest of ambipolar materials for gas sensing</title><author>Wannebroucq, Amélie ; Ouedraogo, Seydou ; Meunier-Prest, Rita ; Suisse, Jean-Moïse ; Bayo, Mabinty ; Bouvet, Marcel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c402t-c86e272169fe78b3d3c06faf4b08cb70a46b58ebb88e1cdf3ec099ea6ee486bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Ambipolar material</topic><topic>Ammonia</topic><topic>Biosensors</topic><topic>Chemical Sciences</topic><topic>Conductometric transducer</topic><topic>Copper</topic><topic>Detection</topic><topic>Electrochemical analysis</topic><topic>Fluorine</topic><topic>Gas sensor</topic><topic>Gas sensors</topic><topic>Gases</topic><topic>Heterojunctions</topic><topic>Humidity</topic><topic>Lutetium</topic><topic>Metal phthalocyanines</topic><topic>Molecular chains</topic><topic>Relative humidity</topic><topic>Transducers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wannebroucq, Amélie</creatorcontrib><creatorcontrib>Ouedraogo, Seydou</creatorcontrib><creatorcontrib>Meunier-Prest, Rita</creatorcontrib><creatorcontrib>Suisse, Jean-Moïse</creatorcontrib><creatorcontrib>Bayo, Mabinty</creatorcontrib><creatorcontrib>Bouvet, Marcel</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Sensors and actuators. B, Chemical</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wannebroucq, Amélie</au><au>Ouedraogo, Seydou</au><au>Meunier-Prest, Rita</au><au>Suisse, Jean-Moïse</au><au>Bayo, Mabinty</au><au>Bouvet, Marcel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the interest of ambipolar materials for gas sensing</atitle><jtitle>Sensors and actuators. B, Chemical</jtitle><date>2018-04-01</date><risdate>2018</risdate><volume>258</volume><spage>657</spage><epage>664</epage><pages>657-664</pages><issn>0925-4005</issn><eissn>1873-3077</eissn><abstract>[Display omitted]
•Ambipolar materials exhibit a unique feature in chemosensing.•Humidity can act as a trigger between p and n-type behaviors.•The tuning of the electronic properties of sensing materials is of importance.
Based on the electrochemical properties of a series of metallophthalocyanines this article shows that the phthalocyanine bearing four alkoxy groups and twelve fluorine atoms behaves approximately as those with eight fluorine atoms. This indicates that the electron-donating effect of one alkoxy group balances the electro-withdrawing effect of one fluorine atom. We engaged three metallophthalocyanines, namely the octafluoro copper phthalocyanine, Cu(F8Pc), an octaester metallophthalocyanine and a phthalocyanine bearing four alkoxy groups and twelve fluorine atoms, Zn(T4F12Pc), in building original conductometric transducers that are Molecular Semiconductor – Doped Insulator heterojunctions (MSDIs) in association with the highly conductive lutetium bisphthalocyanine, LuPc2. Whereas the octaester derivative and Zn(T4F12Pc) exhibited a negative response to ammonia, as expected for p-type materials, Cu(F8Pc) exhibited a particular behavior. At low humidity levels, 30 and 10% rh, the current of the Cu(F8Pc)/LuPc2 MSDI decreases, similarly to p-type devices, but at higher relative humidity values, 70% rh, the current increases under ammonia, which is the signature of a n-type behavior. This ambipolar behavior is unique amongst semiconducting sensing materials. This work opens the way to the study of ambipolar materials as sensing materials for the development of a new type of conductometric gas sensors.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.snb.2017.11.146</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-2272-6633</orcidid><orcidid>https://orcid.org/0000-0001-5597-3879</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Ambipolar material Ammonia Biosensors Chemical Sciences Conductometric transducer Copper Detection Electrochemical analysis Fluorine Gas sensor Gas sensors Gases Heterojunctions Humidity Lutetium Metal phthalocyanines Molecular chains Relative humidity Transducers |
title | On the interest of ambipolar materials for gas sensing |
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